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1. 发明授权

US4147664A Catalyst of polymerization, copolymerization and oligomerization of olefins and drolefins 失效
标题翻译：烯烃和烯烃的聚合，共聚和低聚催化剂
公开(公告)号：US4147664A
公开(公告)日：1979-04-03
申请号：US796480
申请日：1977-05-12
申请人： Anatoly D. Pomogailo , Alla P. Lisitskaya , Viktor S. Oskin , Fridrikh S. Dyachkovsky , Ardalion N. Ponomarev , Nina S. Gorkova
发明人： Anatoly D. Pomogailo , Alla P. Lisitskaya , Viktor S. Oskin , Fridrikh S. Dyachkovsky , Ardalion N. Ponomarev , Nina S. Gorkova
IPC分类号： C07C2/30 , C07C2/34 , C07C2/40 , C08F4/62 , C08F10/00 , C08F36/04 , C08F4/02
CPC分类号： C08F36/04 , C07C2/30 , C07C2/34 , C07C2/406 , C08F10/00 , C08F255/02 , C08F257/00 , C08F257/02 , C07C2531/06 , C07C2531/12 , C07C2531/22
摘要： A catalyst for polymerization, copolymerization and oligomerization of olefins and diolefins is described, which is a compound having the general formula MX.sub.n wherein M is a metal belonging to IVA -- VIA groups of the Periodic System or a cobalt, X is a halogen, hydrogen, cyclopentadienyl, alkoxy-, aryloxy-, or amido group, and n is an integer denoting the valency of M; a compound having the general formula M'R.sub.p Z.sub.k-p wherein M' is a metal of I--III groups of the Periodic System, R is a hydrocarbon radical, Z is a halogen, hydrogen, alkoxy-, aryloxy- or amido group, k is an integer denoting the valency of M', 1.ltoreq.p.ltoreq.k; or compound having the general formula MR.sub.m X.sub.n-m, wherein 2.ltoreq.m.ltoreq.n, said component being chemically bonded with the surface of a carbon-chain polymer carrier through the fragment ##STR1## WHEREIN R' = H, CH.sub.3, C.sub.2 H.sub.5, CH.sub.2 = CH.sub.2, C.sub.6 H.sub.5 ;R" = h, or CH.sub.3 ;R"' = h, or CH.sub.3 ;y = OH, NHR', SR; COCH.sub.3, CH.sub.2 OH ##STR2## CH.sub.2 NHR', COOH, OCOCH.sub.3, CH.sub.2 SH, COOCH.sub.3, C .tbd. N, N(R').sub.2, SO.sub.2 R', SOR', --CH.sub.2 --S--CH.sub.2 --CH.dbd.CH.sub.2,--CH.sub.2 --NH--CH.sub.2 --CH.dbd.CH.sub.2,--CH.sub.2 --SO.sub.2 --CH.sub.2 --CH.dbd.CH.sub.2, wherein R' is defined above,T is the degree of polymerization equal to 4 - 5000.In the case where use is made of compound MX.sub.n applied to a carbon-chain polymer carrier, it is activated with compound M'R.sub.p Z.sub.k-p, while in the case of use being made of compound M'R.sub.p Z.sub.k-p applied to a carbon-chain polymer carrier, it is activated with compound MX.sub.n.Said catalyst is several times (5 to 100) more active than prior art catalysts and provides for a high yield of the product, which may be as high as 1000 kg/g of a transition metal.
摘要翻译：描述了用于烯烃和二烯烃的聚合，共聚和低聚的催化剂，其是具有通式MXn的化合物，其中M是属于周期系统的IVA-VIA基团的金属或钴，X是卤素，氢，环戊二烯基，烷氧基 - ，芳氧基 - 或酰胺基，n是表示M的化合价的整数; 具有通式M'RpZk-p的化合物，其中M'是周期系的I-III族金属，R是烃基，Z是卤素，氢，烷氧基 - ，芳氧基或酰氨基，k 是表示M'的价数的整数，1 = p = k; 或具有通式MRmXn-m的化合物，其中2≤n，所述组分与碳链聚合物载体的表面通过片段“R”= H，CH 3化学键合， C 2 H 5，CH 2 = CH 2，C 6 H 5; R“= H或CH 3; R“'= H或CH 3; y = OH，NHR'，SR; COCH 3，CH 2 OH，CH 2 NHR'，COOH，OCOCH 3，CH 2 SH，COOCH 3，C 3BOND N，N（R'）2，SO 2 R'，SOR'，-CH 2 -S-CH 2 -CH = CH 2，-CH 2 -NH- CH2-CH = CH2，-CH2-SO2-CH2-CH = CH2，其中R'定义如上，T是聚合度等于4-5000。

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