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1. 发明申请

US20050084742A1 Control of polymer surface distribution on diffusion media for improved fuel cell performance 有权
标题翻译：控制扩散介质上聚合物表面分布，提高燃料电池性能
公开(公告)号：US20050084742A1
公开(公告)日：2005-04-21
申请号：US10924317
申请日：2004-08-23
申请人： Anastasios Angelopoulos , Chunxin Ji , Mark Mathias
发明人： Anastasios Angelopoulos , Chunxin Ji , Mark Mathias
IPC分类号： B05D5/12 , B32B9/00 , H01M4/88 , H01M4/94 , H01M4/96 , H01M8/02 , H01M8/10
CPC分类号： H01M8/0202 , H01M8/0234 , H01M8/0239 , H01M8/0245 , H01M2008/1095 , Y02P70/56 , Y10T428/30
摘要： Favorable performance of diffusion media in fuel cells has found to be correlated to a parameter (the C/F ratio) that relates to a spatial and thickness distribution of the hydrophobic fluoropolymer on the carbon fiber substrate structure of the medium. Suitable diffusion media may be chosen from among commercially coated diffusion media by measuring the C/F ratio by means of energy dispersive spectroscopy, and choosing the diffusion media if the value of the C/F ratio is within the preferred range. Alternatively, the diffusion media may be manufactured with an improved process that consistently yields values of C/F ratio in the desired range.
摘要翻译：发现燃料电池中扩散介质的有利性能与涉及介质的碳纤维衬底结构上的疏水性含氟聚合物的空间和厚度分布的参数（C / F比）相关。合适的扩散介质可以通过用能量色散光谱法测量C / F比例从市售的扩散介质中选择，如果C / F比值在优选的范围内，则选择扩散介质。或者，扩散介质可以用改进的方法制造，其一致地产生所需范围内C / F比的值。

2. 发明申请

US20090211522A1 Use of Variable Frequency Microwaves to Control the Teflon Profile of Gas Diffusion Media 审中-公开
标题翻译：使用变频微波控制气体扩散介质的特氟龙轮廓
公开(公告)号：US20090211522A1
公开(公告)日：2009-08-27
申请号：US12035307
申请日：2008-02-21
申请人： Stephen Perl , Anastasios Angelopoulos
发明人： Stephen Perl , Anastasios Angelopoulos
IPC分类号： B05C3/02 , H05B6/64
CPC分类号： H01M8/0234
摘要： A method for fabricating diffusion media for a fuel cell that includes using variable frequency microwaves for heating the diffusion media after it has been coated with a solvent including fluorocarbon particles to provide broader control over the distribution of the fluorocarbon on the diffusion media. In one embodiment, a carbon fiber substrate is dipped in a solution including the fluorocarbon particles and a surfactant. The wet and coated substrate is then dried using the microwave radiation, where the frequency of the microwave radiation is varied to increase or control the dispersion of the fluorocarbon particles and the hydrophobicity of the diffusion media. In one embodiment, the microwave radiation is varied in frequency between 500 MHz and 1000 GHZ.
摘要翻译：一种用于制造用于燃料电池的扩散介质的方法，其包括使用可变频率微波加热所述扩散介质，所述可变频率微波已经涂覆有包含碳氟化合物颗粒的溶剂，以提供对所述扩散介质上碳氟化合物分布的更广泛的控制。在一个实施方案中，将碳纤维基材浸渍在包含碳氟化合物颗粒和表面活性剂的溶液中。然后使用微波辐射将湿的和涂覆的基底干燥，其中改变微波辐射的频率以增加或控制碳氟化合物颗粒的分散和扩散介质的疏水性。在一个实施例中，微波辐射在500MHz和1000GHz之间的频率上变化。

3. 发明授权

US08227076B2 Multifunctional nanocoatings and process for fabricating same 有权
标题翻译：多功能纳米涂料及其制造方法
公开(公告)号：US08227076B2
公开(公告)日：2012-07-24
申请号：US12025923
申请日：2008-02-05
申请人： Anastasios Angelopoulos
发明人： Anastasios Angelopoulos
IPC分类号： B32B27/32 , B32B5/16 , B32B9/04 , B32B15/04 , B32B27/34
CPC分类号： B82Y30/00 , B05D1/18 , B05D1/185 , B05D7/56 , B32B2255/20 , B32B2255/205 , B32B2377/00 , B32B2457/18 , H01M8/0228 , H01M8/1016 , H01M2008/1095 , Y10T428/24975 , Y10T428/25 , Y10T428/259 , Y10T428/26 , Y10T428/265 , Y10T428/269 , Y10T428/31504 , Y10T428/31678 , Y10T428/31725
摘要： Embodiments of a coated substrate comprise a substrate (100) and a multi-layer multi-functional nanoparticle coating (105) having a thickness of up to about 500 nm thereon. The nanoparticle coating (105) comprises an ionic polyelectrolyte layer (110), and an ionic multi-colloid layer disposed over the polyelectrolyte layer (110). The multi-colloid layer comprises hydrophilic colloid ions (130) disposed over and coupled to the polyelectrolyte layer (110), conductive colloid ions (120) disposed over and coupled to the polyelectrolyte layer (110). The conductive colloid ions (120) are separated from the hydrophilic colloid ions (130) by repulsive forces therebetween.
摘要翻译：涂覆的基底的实施方案包括其上具有至多约500nm厚度的基底（100）和多层多功能纳米颗粒涂层（105）。纳米颗粒涂层（105）包括离子聚电解质层（110）和设置在聚电解质层（110）上的离子多胶体层。所述多胶体层包括设置在所述聚电解质层（110）上并耦合到所述聚电解质层（110）的亲水胶体离子（130），设置在所述聚电解质层（110）上并耦合到所述聚电解质层（110）的导电胶体离子（120）。导电胶体离子（120）通过它们之间的排斥力与亲水胶体离子（130）分离。

4. 发明授权

US07892596B2 Nanoparticle coating process for fuel cell components 有权
标题翻译：燃料电池组件的纳米颗粒涂层工艺
公开(公告)号：US07892596B2
公开(公告)日：2011-02-22
申请号：US11608415
申请日：2006-12-08
申请人： Anastasios Angelopoulos , Scott L. Peters
发明人： Anastasios Angelopoulos , Scott L. Peters
IPC分类号： B05C1/00
CPC分类号： H01M8/0228 , H01M8/0204 , H01M8/0206 , H01M8/0221 , H01M8/0226
摘要： A process including coating a fuel cell component using a coating solution including nanoparticles.
摘要翻译：一种包括使用包括纳米颗粒的涂布溶液涂覆燃料电池组件的方法。

5. 发明申请

US20170244112A1 High Activity Pt-Bi Catalyst for Dimethyl Ether Electro-Oxidation 审中-公开
公开(公告)号：US20170244112A1
公开(公告)日：2017-08-24
申请号：US15381811
申请日：2016-12-16
申请人： Anastasios Angelopoulos
发明人： Anastasios Angelopoulos
IPC分类号： H01M4/92 , C22C12/00 , B22F1/02 , B22F1/00 , H01M4/86 , B22F9/24
CPC分类号： H01M4/926 , B22F1/0044 , B22F1/02 , B22F9/24 , B22F2009/245 , B22F2301/30 , B22F2998/10 , C22C12/00 , H01M4/8657 , H01M4/8663 , H01M4/921 , H01M2250/20 , Y02T90/32
摘要： Provided are processes for preparing a thermodynamically stable PtBi2 alloy nanoparticle. In certain aspects, the process comprises preparing an aqueous mixture, with the aqueous mixture comprising: an inorganic compound comprising SnCl2; an inorganic compound comprising Bi; and HCl. The process further comprises adding PtCl4 to the mixture. The process results in the spontaneous reduction of Bi and Pt. Excess SnCl2 is adsorbed as a ligand at the surface of the PtB2 alloy nanoparticle, which serves to stabilize the nanoparticle. Another aspect provides a thermodynamically stable PtBi2 nanoparticle. The nanoparticle comprises a core comprising a PtBi2 alloy. The nanoparticle further comprises a shell at least partially encapsulating the core, with the shell comprising stannous chloride. The thermodynamically stable PtB2 nanoparticle has a negative charge.

6. 发明申请

US20120135211A1 MULTIFUNCTIONAL NANOCOATINGS WITH MIXED NANOPARTICLES AND PROCESS FOR FABRICATING SAME 有权
标题翻译：具有混合纳米颗粒的多功能纳米微粒及其制备方法
公开(公告)号：US20120135211A1
公开(公告)日：2012-05-31
申请号：US12025920
申请日：2008-02-05
申请人： Anastasios Angelopoulos
发明人： Anastasios Angelopoulos
IPC分类号： B32B7/02 , B05D5/00 , B05D1/18 , B32B3/00 , B05D5/12 , B82Y30/00
CPC分类号： B82Y30/00 , B05D1/18 , B05D1/185 , B05D7/56 , H01M8/0228 , H01M8/1016 , H01M2008/1095 , Y10T428/2495 , Y10T428/265
摘要： Embodiments of a coated substrate comprise a substrate (100) with a multi-functional multi-layer nanoparticle coating (105) having a thickness of up to about 500 nm thereon. The nanoparticle coating (105) comprises an ionic polyelectrolyte layer (110), and a mixed colloid layer disposed over the polyelectrolyte layer (110). The mixed colloid layer comprises hydrophilic colloid ions (130) and conductive colloid ions (120) which is coupled through electrostatic or non-electrostatic forces, and the conductive colloid ions (120), the hydrophilic colloid ions (130), or both are coupled to the polyelectrolyte layer (110).
摘要翻译：涂覆基材的实施方案包括具有其上具有高达约500nm厚度的多功能多层纳米颗粒涂层（105）的基底（100）。纳米颗粒涂层（105）包括离子聚电解质层（110）和设置在聚电解质层（110）上方的混合胶体层。混合胶体层包括通过静电或非静电力耦合的亲水胶体离子（130）和导电胶体离子（120），并且导电胶体离子（120），亲水胶体离子（130）或两者耦合到聚电解质层（110）。

7. 发明申请

US20070141238A1 NANOPARTICLE COATING PROCESS FOR FUEL CELL COMPONENTS 有权
标题翻译：燃料电池组件的纳米涂层工艺
公开(公告)号：US20070141238A1
公开(公告)日：2007-06-21
申请号：US11608415
申请日：2006-12-08
申请人： Anastasios Angelopoulos , Scott Peters
发明人： Anastasios Angelopoulos , Scott Peters
IPC分类号： B05D5/12 , B05D1/18 , B05D7/00
CPC分类号： H01M8/0228 , H01M8/0204 , H01M8/0206 , H01M8/0221 , H01M8/0226
摘要： A process including coating a fuel cell component using a coating solution including nanoparticles.
摘要翻译：一种包括使用包括纳米颗粒的涂布溶液涂覆燃料电池组件的方法。

8. 发明授权

US08628819B2 Method of depositing a nanoparticle coating on a bipolar plate and removing the nanoparticle coating from the lands of the bipolar plate 有权
标题翻译：在双极板上沉积纳米颗粒涂层并从双极板的焊盘上去除纳米颗粒涂层的方法
公开(公告)号：US08628819B2
公开(公告)日：2014-01-14
申请号：US11669465
申请日：2007-01-31
申请人： Scott L. Peters , Anastasios Angelopoulos
发明人： Scott L. Peters , Anastasios Angelopoulos
IPC分类号： B05D5/12 , B05D1/18
CPC分类号： H01M8/0228 , H01M8/0258
摘要： A process comprising: submerging a fuel cell bipolar plate in a bath comprising nanoparticles and a liquid phase comprising a nanoparticles dispersion agent and wherein the bipolar plate includes an upper surface having a plurality of lands and channels formed therein; removing the fuel cell bipolar plate from the bath so that a coating comprising nanoparticles adheres to the fuel cell bipolar plate; while the coating is wet and before the coating is dried and solidified, removing the coating comprising nanoparticles from the lands of the bipolar plate, leaving coating comprising nanoparticle in the channels; and drying the coating in the channels.
摘要翻译：一种方法，包括：将燃料电池双极板浸没在包含纳米颗粒的液体浴和包含纳米颗粒分散剂的液相中，并且其中双极板包括其上形成有多个焊盘和通道的上表面; 从浴中去除燃料电池双极板，使得包含纳米颗粒的涂层粘附到燃料电池双极板; 当涂层是湿的并且在涂层被干燥和固化之前，从双极板的焊盘上去除包含纳米颗粒的涂层，将包含纳米颗粒的涂层留在通道中; 并干燥通道中的涂层。

9. 发明授权

US08435627B2 Multifunctional nanocoatings with mixed nanoparticles and process for fabricating same 有权
标题翻译：具有混合纳米颗粒的多功能纳米涂层及其制造方法
公开(公告)号：US08435627B2
公开(公告)日：2013-05-07
申请号：US12025920
申请日：2008-02-05
申请人： Anastasios Angelopoulos
发明人： Anastasios Angelopoulos
IPC分类号： B32B7/02
CPC分类号： B82Y30/00 , B05D1/18 , B05D1/185 , B05D7/56 , H01M8/0228 , H01M8/1016 , H01M2008/1095 , Y10T428/2495 , Y10T428/265
摘要： Embodiments of a coated substrate comprise a substrate (100) with a multi-functional multi-layer nanoparticle coating (105) having a thickness of up to about 500 nm thereon. The nanoparticle coating (105) comprises an ionic polyelectrolyte layer (110), and a mixed colloid layer disposed over the polyelectrolyte layer (110). The mixed colloid layer comprises hydrophilic colloid ions (130) and conductive colloid ions (120) which is coupled through electrostatic or non-electrostatic forces, and the conductive colloid ions (120), the hydrophilic colloid ions (130), or both are coupled to the polyelectrolyte layer (110).
摘要翻译：涂覆基材的实施方案包括具有其上具有高达约500nm厚度的多功能多层纳米颗粒涂层（105）的基底（100）。纳米颗粒涂层（105）包括离子聚电解质层（110）和设置在聚电解质层（110）上方的混合胶体层。混合胶体层包括通过静电或非静电力耦合的亲水胶体离子（130）和导电胶体离子（120），并且导电胶体离子（120），亲水胶体离子（130）或两者耦合到聚电解质层（110）。

10. 发明申请

US20100003764A1 OPTICAL SENSOR 审中-公开
标题翻译：光传感器
公开(公告)号：US20100003764A1
公开(公告)日：2010-01-07
申请号：US12497143
申请日：2009-07-02
申请人： Anastasios Angelopoulos , Subasri M Ayyadurai , Jonathan A. Berstein , Daniel Kanter
发明人： Anastasios Angelopoulos , Subasri M Ayyadurai , Jonathan A. Berstein , Daniel Kanter
IPC分类号： G01N21/78 , B05D1/18
摘要： An optical sensor for monitoring an environmental condition, the optical sensor comprising a perfluorosulfonate ionomer membrane comprising a solution, wherein the solution comprises a transition metal-free dye component, wherein exposure of the optical sensor to a specific environmental condition produces a color shift on the optical sensor.
摘要翻译：一种用于监测环境条件的光学传感器，所述光学传感器包括包含溶液的全氟磺酸盐离聚物膜，其中所述溶液包含无过渡金属的染料组分，其中所述光学传感器暴露于特定环境条件会在光学传感器。

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