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    • 7. 发明授权
    • Emissive polymeric materials for optoelectronic devices
    • 用于光电器件的发射聚合材料
    • US07973126B2
    • 2011-07-05
    • US11957579
    • 2007-12-17
    • Joseph John ShiangKelly Scott ChichakJames Anthony CellaLarry Neil LewisKevin Henry Janora
    • Joseph John ShiangKelly Scott ChichakJames Anthony CellaLarry Neil LewisKevin Henry Janora
    • C08G79/00H01L51/54C09K11/06
    • C08G61/12C08G2261/142C08G2261/1526C08G2261/3142C08G2261/3162H01L51/0039H01L51/5012Y10S428/917
    • Polymers including at least one structural unit derived from a compound of formula I or including at least one pendant group of formula II may be used in optoelectronic devices wherein R1, R3, R4 and R6 are independently hydrogen, alkyl, alkoxy, oxaalkyl, alkylaryl, aryl, arylalkyl, heteroaryl, substituted alkyl; substituted alkoxy, substituted oxaalkyl, substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted heteroaryl; R1a is hydrogen or alkyl; R2 is alkylene, substituted alkylene, oxaalkylene, CO, or CO2; R2a is alkylene; R5 is independently at each occurrence hydrogen, alkyl, alkylaryl, aryl, arylalkyl, alkoxy, carboxy, substituted alkyl; substituted alkylaryl, substituted aryl, substituted arylalkyl, or substituted alkoxy, X is halo, triflate, —B(OR1a)2, or  located at the 2, 5- or 2, 7-positions; and L is derived from phenylpyridine, tolylpyridine, benzothienylpyridine, phenylisoquinoline, dibenzoquinozaline, fluorenylpyridine, ketopyrrole, 2-(1-naphthyl)benzoxazole)), 2-phenylbenzoxazole, 2-phenylbenzothiazole, coumarin, thienylpyridine, phenylpyridine, benzothienylpyridine, 3-methoxy-2-phenylpyridine, thienylpyridine, phenylimine, vinylpyridine, pyridylnaphthalene, pyridylpyrrole, pyridylimidazole, phenylindole, derivatives thereof or combinations thereof.
    • 包括至少一种衍生自式I化合物或包含至少一个式II侧基的结构单元的聚合物可用于其中R 1,R 3,R 4和R 6独立地为氢,烷基,烷氧基,氧杂烷基,烷芳基, 芳基,芳基烷基,杂芳基,取代的烷基; 取代的烷氧基,取代的氧杂烷基,取代的烷基芳基,取代的芳基,取代的芳基烷基或取代的杂芳基; R1a是氢或烷基; R2是亚烷基,取代的亚烷基,氧杂亚烷基,CO或CO 2; R2a是亚烷基; R5各自独立地为氢,烷基,烷基芳基,芳基,芳基烷基,烷氧基,羧基,取代的烷基; 取代的烷基芳基,取代的芳基,取代的芳基烷基或取代的烷氧基,X是卤素,三氟甲磺酸酯,-B(OR1a)2,或位于2,5-或2,7-位; 苯基吡啶,苯并噻吩并吡啶,二苯并喹嗪,芴基吡啶,酮吡咯,2-(1-萘基)苯并恶唑)),2-苯基苯并恶唑,2-苯基苯并噻唑,香豆素,噻吩基吡啶,苯基吡啶,苯并噻吩基吡啶,3-甲氧基 - 2-苯基吡啶,噻吩基吡啶,苯基亚胺,乙烯基吡啶,吡啶基萘,吡啶基吡咯,吡啶基咪唑,苯基吲哚,其衍生物或其组合。
    • 9. 发明授权
    • Optoelectronic devices with multilayered structures
    • 具有多层结构的光电器件
    • US07830081B2
    • 2010-11-09
    • US11748195
    • 2007-05-14
    • Larry Neil LewisKelly Scott ChichakJames Anthony CellaJoseph John Shiang
    • Larry Neil LewisKelly Scott ChichakJames Anthony CellaJoseph John Shiang
    • C08G77/398H01J1/62
    • C08G77/58G02B1/043C08L83/04
    • Optoelectronic devices include polysiloxanes derived from hydrosilation of an organometallic compound of formula L2MZ,wherein L and Z are independently bidentate ligands; at least one of L and Z comprises alkenyl, alkenylaryl, alkenyloxy, alkenyloxyaryl, alkynyl, alkynylaryl, alkynyloxy, alkynyloxyaryl, substituted alkenyl, substituted alkenylaryl, substituted alkenyloxy, substituted alkenyloxyaryl, substituted alkynyl, substituted alkynylaryl, substituted alkynyloxy, substituted alkynyloxyaryl, acrylate, methacrylate, or a combination thereof; and M is Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Os, Ir, Pt, Au, Hg, Ga, Ge, In, Sn, Sb, Tl, Pd, Bi, Po, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, or Lu.
    • 光电器件包括衍生自式L2MZ的有机金属化合物的氢化硅石的聚硅氧烷,其中L和Z独立地是二齿配体; L和Z中的至少一个包括烯基,烯基芳基,烯氧基,烯基氧基芳基,炔基,炔基芳基,炔氧基,炔氧基芳基,取代的烯基,取代的烯基芳基,取代的烯氧基,取代的烯基氧基芳基,取代的炔基,取代的炔基芳基,取代的炔氧基,取代的炔氧基芳基,丙烯酸酯, 甲基丙烯酸酯或其组合; 并且M是Zr,Nb,Mo,Tc,Ru,Rh,Pd,Ag,Cd,Hf,Ta,W,Re,Os,Ir,Pt,Au,Hg,Ga,Ge,In,Sn,Sb, ,Pd,Bi,Po,La,Ce,Pr,Nd,Pm,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb或Lu。