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1. 发明授权

US08507741B2 Methods for co-production of alkylbenzene and biofuel from natural oils using hydrocracking 有权
标题翻译：使用加氢裂化从天然油共生产烷基苯和生物燃料的方法
公开(公告)号：US08507741B2
公开(公告)日：2013-08-13
申请号：US13242825
申请日：2011-09-23
申请人： Amarendra Anumakonda , Srikantiah Raghuram , Joao Jorge da Silva Ferreira Alves , Andrea G. Bozzano
发明人： Amarendra Anumakonda , Srikantiah Raghuram , Joao Jorge da Silva Ferreira Alves , Andrea G. Bozzano
IPC分类号： C07C1/207 , C07C2/64 , C07C5/22
CPC分类号： C07C2/68 , C07C2/70 , C07C5/333 , C07C7/163 , C07C2527/1206 , C07C2527/126 , C10G3/00 , C10G69/00 , C10G69/123 , C10G69/14 , C10G2300/1014 , C10G2400/30 , Y02P30/20 , C07C15/107 , C07C11/02
摘要： Embodiments of methods for co-production of linear alkylbenzene and biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form paraffins. A first portion of the paraffins is hydrocracked to form a first stream of normal and lightly branched paraffins in the C9 to C14 range and a second stream of isoparaffins. The first stream is dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. A second portion of the paraffins and the isoparaffins are processed to form biofuel.
摘要翻译：提供了从天然油共生产直链烷基苯和生物燃料的方法的实施方案。一种方法包括使天然油脱氧以形成链烷烃的步骤。将第一部分石蜡加氢裂化以形成C9至C14范围内的第一流和正链和轻度支化的烷烃，第二股异链烷烃流。将第一流脱氢以提供单烯烃。然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。此后，分离烷基苯以提供烷基苯产物。石蜡和异链烷烃的第二部分被处理以形成生物燃料。

2. 发明申请

US20130079570A1 METHODS FOR CO-PRODUCTION OF ALKYLBENZENE AND BIOFUEL FROM NATURAL OILS USING HYDROCRACKING 有权
标题翻译：使用水解法从天然油中生产烷基苯酚和生物油的方法
公开(公告)号：US20130079570A1
公开(公告)日：2013-03-28
申请号：US13242825
申请日：2011-09-23
申请人： Amarendra Anumakonda , Srikantiah Raghuram , Joao Jorge da Silva Ferreira Alves , Andrea G. Bozzano
发明人： Amarendra Anumakonda , Srikantiah Raghuram , Joao Jorge da Silva Ferreira Alves , Andrea G. Bozzano
IPC分类号： C07C1/207
CPC分类号： C07C2/68 , C07C2/70 , C07C5/333 , C07C7/163 , C07C2527/1206 , C07C2527/126 , C10G3/00 , C10G69/00 , C10G69/123 , C10G69/14 , C10G2300/1014 , C10G2400/30 , Y02P30/20 , C07C15/107 , C07C11/02
摘要： Embodiments of methods for co-production of linear alkylbenzene and biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form paraffins. A first portion of the paraffins is hydrocracked to form a first stream of normal and lightly branched paraffins in the C9 to C14 range and a second stream of isoparaffins. The first stream is dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. A second portion of the paraffins and the isoparaffins are processed to form biofuel.
摘要翻译：提供了从天然油共生产直链烷基苯和生物燃料的方法的实施方案。一种方法包括使天然油脱氧以形成链烷烃的步骤。将第一部分石蜡加氢裂化以形成C9至C14范围内的第一流和正链和轻度支化的烷烃，第二股异链烷烃流。将第一流脱氢以提供单烯烃。然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。此后，分离烷基苯以提供烷基苯产物。石蜡和异链烷烃的第二部分被处理以形成生物燃料。

3. 发明授权

US08546629B2 Methods for co-production of alkylbenzene and biofuel from natural oils 有权
标题翻译：从天然油共生产烷基苯和生物燃料的方法
公开(公告)号：US08546629B2
公开(公告)日：2013-10-01
申请号：US13242833
申请日：2011-09-23
申请人： Andrea G. Bozzano , Matthew James Griffiths , Amarendra Anumakonda
发明人： Andrea G. Bozzano , Matthew James Griffiths , Amarendra Anumakonda
IPC分类号： C07C2/64 , C07C5/22
CPC分类号： C07C2/66 , C01B3/26 , C10G3/00 , C10G3/50 , C10G9/00 , C10G29/205 , C10G45/32 , C10G57/005 , C10G69/00 , C10G69/123 , C10G69/126 , C10G69/14 , C10G2300/1014 , C10G2400/04 , C10G2400/08 , C10L1/08 , Y02E50/13 , Y02P30/20 , C07C15/107
摘要： Embodiments of methods for co-production of linear alkylbenzene and biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. A first portion of the paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. A second portion of the paraffins is processed to form biofuel.
摘要翻译：提供了从天然油共生产直链烷基苯和生物燃料的方法的实施方案。一种方法包括使天然油脱氧以形成包含石蜡的物流的步骤。将第一部分链烷烃脱氢以提供单烯烃。然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。此后，分离烷基苯以提供烷基苯产物。处理第二部分石蜡以形成生物燃料。

4. 发明申请

US20130079573A1 METHODS FOR CO-PRODUCTION OF ALKYLBENZENE AND BIOFUEL FROM NATURAL OILS 有权
标题翻译：从天然油中生产烷基苯酚和生物油的方法
公开(公告)号：US20130079573A1
公开(公告)日：2013-03-28
申请号：US13242833
申请日：2011-09-23
申请人： Andrea G. Bozzano , Matthew James Griffiths , Amarendra Anumakonda
发明人： Andrea G. Bozzano , Matthew James Griffiths , Amarendra Anumakonda
IPC分类号： C07C1/207
CPC分类号： C07C2/66 , C01B3/26 , C10G3/00 , C10G3/50 , C10G9/00 , C10G29/205 , C10G45/32 , C10G57/005 , C10G69/00 , C10G69/123 , C10G69/126 , C10G69/14 , C10G2300/1014 , C10G2400/04 , C10G2400/08 , C10L1/08 , Y02E50/13 , Y02P30/20 , C07C15/107
摘要： Embodiments of methods for co-production of linear alkylbenzene and biofuel from a natural oil are provided. A method comprises the step of deoxygenating the natural oils to form a stream comprising paraffins. A first portion of the paraffins are dehydrogenated to provide mono-olefins. Then, benzene is alkylated with the mono-olefins under alkylation conditions to provide an alkylation effluent comprising alkylbenzenes and benzene. Thereafter, the alkylbenzenes are isolated to provide the alkylbenzene product. A second portion of the paraffins is processed to form biofuel.
摘要翻译：提供了从天然油共生产直链烷基苯和生物燃料的方法的实施方案。一种方法包括使天然油脱氧以形成包含石蜡的流的步骤。将第一部分链烷烃脱氢以提供单烯烃。然后，在烷基化条件下用单烯烃烷基化苯以提供包含烷基苯和苯的烷基化流出物。此后，分离烷基苯以提供烷基苯产物。处理第二部分石蜡以形成生物燃料。

5. 发明申请

US20050081444A1 CATALYTIC PARTIAL OXIDATION PROCESSOR WITH HEAT EXCHANGER FOR CONVERTING HYDROCARBON FUELS TO SYNGAS FOR USE IN FUEL CELLS AND METHOD 审中-公开
标题翻译：具有换热器的催化部分氧化处理器用于将燃料转化为燃料中的燃料和方法
公开(公告)号：US20050081444A1
公开(公告)日：2005-04-21
申请号：US10605688
申请日：2003-10-17
申请人： Amarendra Anumakonda , Robin Wang
发明人： Amarendra Anumakonda , Robin Wang
IPC分类号： B01J8/06 , B01J12/00 , B01J19/24 , C01B3/38 , H01M8/06 , H01M8/12 , C01B3/26
CPC分类号： C01B3/386 , B01J8/067 , B01J12/007 , B01J19/2485 , B01J2208/00212 , B01J2208/00495 , B01J2208/025 , B01J2219/00159 , B01J2219/00243 , C01B2203/0261 , C01B2203/066 , C01B2203/0883 , C01B2203/1247 , H01M8/0612 , H01M2008/1293 , Y02P20/124
摘要： A catalytic partial oxidation processor comprising at least one catalytic partial oxidation reactor disposed in a shell having an inlet and outlet such that heat from partial oxidation in the reactor transfers from the reactor to heat exchange fluid in the shell. The heat transfer serves to keep the precatalyst zone of the partial oxidation reactor cool and the post catalyst section of the partial oxidation reactor hot while also providing an efficient heat recovery system. A system for producing electric power comprises such a catalytic partial oxidation processor and a fuel cell disposed for receiving the exit gas stream and consuming the hydrogen to produce electric power. Corresponding methods are also disclosed.
摘要翻译：一种催化部分氧化处理器，包括设置在具有入口和出口的外壳中的至少一个催化部分氧化反应器，使得反应器中部分氧化的热量从反应器转移到壳中的热交换流体。传热用于使部分氧化反应器的预催化剂区域保持冷却，并且部分氧化反应器的后催化剂部分处于热状态，同时还提供有效的热回收系统。一种用于生产电力的系统包括这种催化部分氧化处理器和设置用于接收出口气流并消耗氢气以产生电力的燃料电池。还公开了相应的方法。

6. 发明申请

US20090287029A1 Controlling Production of Transportation Fuels from Renewable Feedstocks 有权
标题翻译：控制可再生原料运输燃料的生产
公开(公告)号：US20090287029A1
公开(公告)日：2009-11-19
申请号：US12402873
申请日：2009-03-12
申请人： Amarendra Anumakonda , Michael J. McCall , Timothy A. Brandvold , Joseph A. Kocal
发明人： Amarendra Anumakonda , Michael J. McCall , Timothy A. Brandvold , Joseph A. Kocal
IPC分类号： C10G3/00
CPC分类号： C10G45/58 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C10G3/42 , C10G3/50 , C10G3/52 , C10G45/64 , C10G45/72 , C10G47/00 , C10G47/36 , C10G65/12 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/04 , C10G2400/08 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： A process for controlling the concurrent production of both diesel range hydrocarbons and aviation range hydrocarbons from renewable feedstocks such as plant oils and animal oils. The process involves determining the required specification of the desired products and the desired relative yields of the product that still meet the required specifications. The necessary isomerization and selective hydrocracking zone conditions are determined in order to create a mixture of paraffins which meet the required product specifications and yields. The necessary fractionation zone conditions are determined to separate the desired products. A renewable feedstock is treated by hydrogenating and deoxygenating to provide an effluent comprising paraffins, isomerizing and selectively hydrogenating at least a portion of the paraffins at the predetermined conditions, and separating by fractionation at the predetermined fractionation conditions to generate a diesel range hydrocarbon product and an aviation range hydrocarbon product.
摘要翻译：控制从可再生原料如植物油和动物油同时生产柴油范围碳氢化合物和航空范围烃的过程。该过程包括确定所需产品的所需规格以及仍符合要求规格的产品所需的相对产量。确定所需的异构化和选择性加氢裂化区条件以产生满足所需产物规格和产率的石蜡混合物。确定所需的分馏区条件以分离所需的产物。通过氢化和脱氧来处理可再生原料以提供包含链烷烃的流出物，在预定条件下异构化和选择性氢化至少一部分链烷烃，并通过在预定分馏条件下分级分离以产生柴油范围烃产物和航空范围烃产品。

7. 发明申请

US20050089465A1 Thermally Managed Catalytic Partial Oxidation Of Hydrocarbon Fuels To Form Syngas For Use In Fuel Cells 审中-公开
标题翻译：碳氢燃料的热管理催化部分氧化形成用于燃料电池的合成气
公开(公告)号：US20050089465A1
公开(公告)日：2005-04-28
申请号：US10605737
申请日：2003-10-22
申请人： Amarendra Anumakonda , Robin Wang , Mariola Proszowski , Jean Yamanis
发明人： Amarendra Anumakonda , Robin Wang , Mariola Proszowski , Jean Yamanis
IPC分类号： B01J12/00 , B01J19/00 , B01J19/24 , C01B3/38 , C01B31/18 , C01B3/02 , C01B31/24
CPC分类号： B01J19/0013 , B01J12/007 , B01J19/0026 , B01J19/0053 , B01J19/2415 , B01J2208/00707 , B01J2208/025 , B01J2219/00087 , B01J2219/00159 , C01B3/382 , C01B3/384 , C01B3/386 , C01B2203/0244 , C01B2203/066 , C01B2203/0816 , C01B2203/0844 , C01B2203/0872 , C01B2203/0883 , C01B2203/1005 , C01B2203/1247 , C01B2203/1276 , C01B2203/142 , C01B2203/82
摘要： Method and equipment for converting hydrocarbon fuel to a mixture of hydrogen and carbon monoxide through catalytic partial oxidation. Thermal management of the process in the pre-reaction and post reaction zones of the reactor enhance yields and reduces carbon deposition.
摘要翻译：通过催化部分氧化将烃类燃料转化为氢气和一氧化碳的混合物的方法和设备。反应器和反应后反应区中的方法的热管理提高了产率并减少了碳沉积。

8. 发明授权

US06221280B1 Catalytic partial oxidation of hydrocarbon fuels to hydrogen and carbon monoxide 失效
标题翻译：烃燃料催化部分氧化成氢和一氧化碳
公开(公告)号：US06221280B1
公开(公告)日：2001-04-24
申请号：US09175125
申请日：1998-10-19
申请人： Amarendra Anumakonda , Jean Yamanis , Joe Ferrall
发明人： Amarendra Anumakonda , Jean Yamanis , Joe Ferrall
IPC分类号： C07C102
CPC分类号： H01M8/0612 , C01B3/386 , C01B2203/0261 , C01B2203/066 , C01B2203/0811 , C01B2203/1023 , C01B2203/1064 , C01B2203/1082 , C01B2203/1247 , C01B2203/1276 , C01B2203/1288 , C01B2203/169
摘要： A method of processing sulfur-containing heavy hydrocarbon fuels in the substantial absence of steam through catalytic partial oxidation is described. The process comprises the steps of vaporizing a heavy hydrocarbon fuel and bringing the vaporized fuel and oxidizer mixture in contact with a noble metal catalyst supported on an open channel structure. The hydrocarbon fuel is considered to be a liquid hydrocarbon having at least six carbon atoms and a sulfur content of at least 50 ppm. The feed, containing only the vaporized fuel and oxygen in the oxidizer mixture, is subsequently routed through a reactor containing a noble metal catalyst (typically Rh/Alumina) at contact times of not more than about 500 milliseconds and a LHSV of not less than about 0.5 h−1. The feed is partially oxidized by a catalytic reaction occurring at a temperature of no less than about 1050° C., with the catalytic partial oxidation process producing essentially complete conversion of hydrocarbons present in the feed to hydrogen and carbon monoxide. The sulfur compounds in the feed are predominantly converted into hydrogen sulfide. The product gas consisting mainly of carbon monoxide and hydrogen can then be recovered or, alternatively, directed to a solid oxide fuel cell system.
摘要翻译：描述了通过催化部分氧化在基本上不存在蒸汽的情况下处理含硫重烃燃料的方法。该方法包括蒸发重质烃燃料并使蒸发的燃料和氧化剂混合物与负载在开放通道结构上的贵金属催化剂接触的步骤。烃燃料被认为是具有至少6个碳原子并且硫含量至少为50ppm的液态烃。在氧化剂混合物中仅含有蒸发的燃料和氧气的进料随后在不大于约500毫秒的接触时间通过包含贵金属催化剂（通常为Rh /氧化铝）的反应器，并且LHSV不小于约 0.5 h-1。进料通过在不低于约1050℃的温度下发生的催化反应被部分氧化，催化部分氧化过程产生进料中存在的烃基本上完全转化为氢气和一氧化碳。进料中的硫化合物主要转化为硫化氢。然后可以回收主要由一氧化碳和氢气组成的产物气体，或者替代地指向固体氧化物燃料电池系统。

9. 发明授权

US08058492B2 Controlling production of transportation fuels from renewable feedstocks 有权
标题翻译：控制可再生原料运输燃料的生产
公开(公告)号：US08058492B2
公开(公告)日：2011-11-15
申请号：US12402873
申请日：2009-03-12
申请人： Amarendra Anumakonda , Michael J. McCall , Timothy A. Brandvold , Joseph A. Kocal
发明人： Amarendra Anumakonda , Michael J. McCall , Timothy A. Brandvold , Joseph A. Kocal
IPC分类号： C10M171/00 , C07C4/00 , C10G1/00
CPC分类号： C10G45/58 , C01B2203/0233 , C01B2203/0244 , C01B2203/062 , C10G3/42 , C10G3/50 , C10G3/52 , C10G45/64 , C10G45/72 , C10G47/00 , C10G47/36 , C10G65/12 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/04 , C10G2400/08 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： A process for controlling the concurrent production of both diesel range hydrocarbons and aviation range hydrocarbons from renewable feedstocks such as plant oils and animal oils. The process involves determining the required specification of the desired products and the desired relative yields of the product that still meet the required specifications. The necessary isomerization and selective hydrocracking zone conditions are determined in order to create a mixture of paraffins which meet the required product specifications and yields. The necessary fractionation zone conditions are determined to separate the desired products. A renewable feedstock is treated by hydrogenating and deoxygenating to provide an effluent comprising paraffins, isomerizing and selectively hydrogenating at least a portion of the paraffins at the predetermined conditions, and separating by fractionation at the predetermined fractionation conditions to generate a diesel range hydrocarbon product and an aviation range hydrocarbon product.
摘要翻译：控制从可再生原料如植物油和动物油同时生产柴油范围碳氢化合物和航空范围烃的过程。该过程包括确定所需产品的所需规格以及仍符合要求规格的产品所需的相对产量。确定所需的异构化和选择性加氢裂化区条件以产生满足所需产物规格和产率的石蜡混合物。确定所需的分馏区条件以分离所需的产物。通过氢化和脱氧来处理可再生原料以提供包含链烷烃的流出物，在预定条件下异构化和选择性氢化至少一部分链烷烃，并通过在预定分馏条件下分级分离以产生柴油范围烃产物和航空范围烃产品。

10. 发明申请

US20050089464A1 Production Of Syngas For Fuel Cells Using Multiple Catalyst Configuration 审中-公开
标题翻译：使用多种催化剂配置生产燃料电池合成气
公开(公告)号：US20050089464A1
公开(公告)日：2005-04-28
申请号：US10605736
申请日：2003-10-22
申请人： Robin Wang , Peter Pappas , Amarendra Anumakonda , Mariola Proszowski , Jean Yamanis
发明人： Robin Wang , Peter Pappas , Amarendra Anumakonda , Mariola Proszowski , Jean Yamanis
IPC分类号： B01J12/00 , B01J19/24 , C01B3/38 , C01B32/40 , C01B6/24 , C01B31/18 , C01B31/24 , C01B3/02
CPC分类号： C01B3/386 , B01J12/007 , B01J19/2485 , B01J2208/025 , B01J2219/00087 , B01J2219/00155 , B01J2219/00157 , B01J2219/00159 , C01B32/40 , C01B2203/0244 , C01B2203/0261 , C01B2203/066 , C01B2203/0844 , C01B2203/1023 , C01B2203/1247 , C01B2203/1258 , C01B2203/142 , C01B2203/82
摘要： Method and equipment for converting hydrocarbon fuel to a mixture of hydrogen and carbon monoxide through catalytic partial oxidation. The catalysts can include a combination of both an oxidation catalyst and a steam reforming catalyst, though no water is used in the process and catalyst contact time is short. Thermal management of the process in the pre-reaction and post reaction zones of the reactor enhance yields and reduce carbon deposition.
摘要翻译：通过催化部分氧化将烃类燃料转化为氢气和一氧化碳的混合物的方法和设备。催化剂可以包括氧化催化剂和蒸汽重整催化剂的组合，尽管在该方法中不使用水，催化剂接触时间短。反应器和反应后反应区中的方法的热管理提高了产率并减少了碳沉积。

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