专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US06231828B1 Process for producing sodium percarbonate 有权
标题翻译：生产过碳酸钠的方法
公开(公告)号：US06231828B1
公开(公告)日：2001-05-15
申请号：US09142940
申请日：1998-12-23
申请人： Alun P. James , Graham R. Horne , Richard Roesler , Lido Signorini , Robert Owen , Soraya Parvaneh , Romano Pardini , Stefano Bigini , Manfred Mathes , Uwe Droste , Pier-Luigi Deli
发明人： Alun P. James , Graham R. Horne , Richard Roesler , Lido Signorini , Robert Owen , Soraya Parvaneh , Romano Pardini , Stefano Bigini , Manfred Mathes , Uwe Droste , Pier-Luigi Deli
IPC分类号： C01B1510
CPC分类号： C11D3/3942 , C01B15/103 , C11D3/128
摘要： Sodium percarbonate is traditionally made in a crystallization process from aqueous hydrogen peroxide and sodium carbonate with recycle of mother liquor in the presence of a substantial concentration of a salting-out agent, conventionally sodium chloride. The invention provides a process intended to be conducted without addition of chloride salting-out agent in which the dissolution step (1) is controlled to restrict the sodium carbonate concentration to below 95%; preferably 60 to 90% of its saturated concentration at a temperature preferably controlled to at most 35° C. and the mole ratio of hydrogen peroxide: sodium carbonate in the reaction vessel is controlled to between 0.7 to 1.2:1, and preferably about 1:1. In some embodiments at least a fraction of the mother liquor introduced into the dissolution tank (1) is obtained by extraction from the reaction vessel (6) and in other embodiments a fraction of the sodium percarbonate (2) is introduced in solution in the mother liquor (4) and a fraction is introduced in particulate form (8) directly into the reaction vessel (6). Large particle sodium percarbonate is provided which has a 7 day aged heat emission at 40° C. of not more than 3 &mgr;W/g measured in a microcalorimeter over 16 hours that is lower than the heat emission from conventionally produced sodium percarbonate employing a chloride salting-out agent.
摘要翻译：传统上，过碳酸钠通过过氧化氢和碳酸钠水溶液的结晶过程在母液中，在大量浓度的盐析剂，常规氯化钠存在下进行。本发明提供了一种在不加入氯化物盐析剂的情况下进行的方法，其中控制溶解步骤（1）以将碳酸钠浓度限制在95％以下; 优选其饱和浓度的60至90％，优选控制在至多35℃，反应容器中过氧化氢：碳酸钠的摩尔比控制在0.7至1.2:1之间，优选约1： 1。在一些实施方案中，通过从反应容器（6）中提取，获得引入溶解槽（1）的至少一部分母液，在其它实施方案中，将过量碳酸钠（2）的一部分引入母体溶液中液体（4）和一部分颗粒形式（8）直接引入反应容器（6）。提供大颗粒过碳酸钠，其在40℃下具有7天以上的热释放度，其在微量热计中在16小时内测量的不超过3μW/ g，低于常规制备的过碳酸钠使用氯化物盐析 -out代理。

2. 发明授权

US06482385B2 Sodium percarbonate and process for producing sodium percarbonate 失效
标题翻译：过碳酸钠和生产过碳酸钠的方法
公开(公告)号：US06482385B2
公开(公告)日：2002-11-19
申请号：US09794122
申请日：2001-02-28
申请人： Alun P. James , Graham R. Horne , Richard Roesler , Lido Signorini , Robert Owen , Soraya Parvaneh , Romano Pardini , Stefano Bigini , Manfred Mathes , Uwe Droste , Pier-Luigi Deli
发明人： Alun P. James , Graham R. Horne , Richard Roesler , Lido Signorini , Robert Owen , Soraya Parvaneh , Romano Pardini , Stefano Bigini , Manfred Mathes , Uwe Droste , Pier-Luigi Deli
IPC分类号： C01B1510
CPC分类号： C11D3/3942 , C01B15/103 , C11D3/128
摘要： Sodium percarbonate is traditionally made in a crystallization process from aqueous hydrogen peroxide and sodium carbonate with recycle of mother liquor in the presence of a substantial concentration of a salting out agent, conventionally sodium chloride. The invention provides a process intended to be conducted without addition of chloride salting-out agent in which the dissolution step is controlled to restrict the sodium carbonate concentration to below 95%, preferably 60 to 90% of its saturated concentration at a temperature preferably controlled to at most 35C. and the mole ratio of hydrogen peroxide:sodium carbonate in the reaction vessel is controlled to between 0.7 to 1.2:1, and preferably about 1:1. In some embodiments at least a fraction of the mother liquor introduced into the dissolution tank is obtained by extraction from the reaction vessel and in other embodiments a fraction of the sodium percarbonate is introduced in solution in the mother liquor and a fraction is introduced in particulate form directly into the reaction vessel. Large particle sodium percarbonate is provided which has a 7 day aged heat emission at 40C. of not more than 3 &mgr;W/g measured in a microcalorimeter over 16 hours that is lower than the heat emission from conventionally produced sodium percarbonate employing a chloride salting-out agent.
摘要翻译：传统上，过碳酸钠通过过氧化氢水溶液和碳酸钠的结晶过程进行，在过量的盐析剂（常规氯化钠）存在下，再循环母液。本发明提供一种在不加入氯化物盐析剂的情况下进行的方法，其中控制溶解步骤以将碳酸钠浓度限制在其饱和浓度的95％以下，优选60％至90％，优选控制在最多35℃。并且将反应容器中过氧化氢：碳酸钠的摩尔比控制在0.7至1.2:1之间，优选约1:1。在一些实施方案中，通过从反应容器中萃取而获得引入溶解槽的至少一部分母液，在其它实施方案中，将过碳酸钠的一部分引入母液中的溶液中，并将一部分以颗粒形式直接进入反应容器。提供了大颗粒过碳酸钠，其在40℃下具有7天的发热。在微量热计中在16小时内测量的，不超过3微瓦/克，低于使用氯化物盐析剂的常规生产的过碳酸钠的散热。

3. 发明授权

US06306811B1 Compositions containing sodium percarbonate 失效
标题翻译：含有过碳酸钠的组合物
公开(公告)号：US06306811B1
公开(公告)日：2001-10-23
申请号：US09142941
申请日：1999-03-30
申请人： Alun P. James , Graham R. Horne , Richard Roesler , Soraya Parvaneh , Romano Pardini , Pier-Luigi Deli
发明人： Alun P. James , Graham R. Horne , Richard Roesler , Soraya Parvaneh , Romano Pardini , Pier-Luigi Deli
IPC分类号： C11D300
CPC分类号： C11D3/128 , C01B15/103 , C11D3/3942
摘要： Sodium percarbonate exhibits a tendency to decompose in built compositions and particularly detergent compositions built with zeolites. The tendency can be ameliorated by selecting sodium percarbonate which intrinsically has a mean particle size of from 500 to 1000 microns and not more than 20% by weight of below 350 microns and has a moisture pick-up when measured in a test at 80% relative humidity and 32° C. after 24 hours of not greater than 30 g/1000 g sample. A suitable sodium percarbonate can be made most conveniently by crystallisation from a bulk saturated solution of sodium percarbonate in a crystalliser/classifier that does not employ a conventional chloride salting-out agent.
摘要翻译：过碳酸钠表现出在内置组合物中分解的倾向，特别是用沸石构成的洗涤剂组合物。通过选择过碳酸钠，其本质上具有500至1000微米且不大于20重量％低于350微米的平均粒度可以改善倾向，并且在80％相对的测试中测量时具有吸湿性湿度为32℃，24小时后不大于30g / 1000g样品。通过在不使用常规氯化物盐析剂的结晶器/分选机中从过饱碳酸钠的大量饱和溶液中结晶，可以最方便地制备合适的过碳酸钠。

4. 发明授权

US06413927B1 Process for stabilizing particulate alkali metal percarbonate 失效
标题翻译：稳定颗粒状碱金属过碳酸盐的方法
公开(公告)号：US06413927B1
公开(公告)日：2002-07-02
申请号：US09463769
申请日：2000-03-30
申请人： Graham R. Horne , Alun P. James , Daniel R. Baker
发明人： Graham R. Horne , Alun P. James , Daniel R. Baker
IPC分类号： C11D1700
CPC分类号： C11D3/221 , C01B15/106 , C11D3/3942 , C11D17/0039
摘要： A process for stabilising particulate alkali metal percarbonate involves coating it with an aqueous solution, preferably concentrated, of a non-reducing oligomeric saccharide, preferably sucrose and especially together with an inorganic salt co-coating agent. The preferred co-coating agents are alkali metal silicate, sulphate, carbonate and carbonate chloride. Coated percarbonate is provided having an excellent combination of solubility, and stability, even with low amounts of coating agent.
摘要翻译：用于稳定颗粒状碱金属过碳酸盐的方法包括用非还原性低聚糖，优选蔗糖的水溶液，优选浓缩，特别是与无机盐共包衣剂一起包衣。优选的共包衣剂是碱金属硅酸盐，硫酸盐，碳酸盐和碳酸氢盐。提供了涂覆的过碳酸盐，即使用少量的涂覆剂也具有优异的溶解性和稳定性的组合。

5. 发明授权

US06521583B1 Coated sodium percarbonate particles, process for their preparation, their use in detergent compositions and detergent compositions containing them 失效
标题翻译：涂覆的过碳酸钠颗粒，其制备方法，它们在洗涤剂组合物中的应用和含有它们的洗涤剂组合物
公开(公告)号：US06521583B1
公开(公告)日：2003-02-18
申请号：US09701780
申请日：2001-04-16
申请人： Alun P. James , Graham R. Horne , Tom Candy , Richard Rösler , Manfred Mathes
发明人： Alun P. James , Graham R. Horne , Tom Candy , Richard Rösler , Manfred Mathes
IPC分类号： C11D1700
CPC分类号： C11D3/10 , C01B15/106 , C11D3/08 , C11D3/3942 , C11D17/0039
摘要： Coated sodium percarbonate particles are provided which contain a sodium percarbonate core, and a coating layer substantially free from sulate, borate and magnesium compounds, having at least 30 and at most 75% w/w of an alkali metal carbonate and at least 25 and at most 70% w/w of an alkali metal silicate. The alkali metal carbonate and silicate being uniformly dispersed in the coating layer. Also provided is a process for the preparation of the coated sodium percarbonate particles and their use in detergent compositions.
摘要翻译：提供涂覆的过碳酸钠颗粒，其含有过碳酸钠芯和基本上不含硫酸钡，硼酸盐和镁化合物的涂层，其具有至少30和至多75％w / w的碱金属碳酸盐和至少25和在大约70％w / w的碱金属硅酸盐。碱金属碳酸盐和硅酸盐均匀分散在涂层中。还提供了制备涂覆的过碳酸钠颗粒的方法及其在洗涤剂组合物中的用途。

6. 发明授权

US5556834A Percarbonate particles stabilized by coating with an aqueous solution containing a silicate and a boric acid 失效
标题翻译：通过用含有硅酸盐和硼酸的水溶液进行包衣来稳定的过碳酸盐颗粒
公开(公告)号：US5556834A
公开(公告)日：1996-09-17
申请号：US464745
申请日：1995-06-21
申请人： Alun P. James , Graham R. Horne
发明人： Alun P. James , Graham R. Horne
IPC分类号： C01B15/10 , C11D3/39 , C11D3/395 , C11D7/18 , C11D7/54 , C11D17/00 , C11D7/04 , C11D7/14
CPC分类号： C01B15/106 , C11D17/0039 , C11D3/3937
摘要： A process for stabilizing percarbonate by coating by means of a coating agent according to which the percarbonate particles are treated with a concentrated aqueous solution containing at least one boron compound selected from meta and ortho boric acids and at least one silicate, following by removal of water to provide coated percarbonate particles. The solution is prepared by adding the boron compound to a solution of the silicate. The coated particles are useful in washing and bleaching compositions.
摘要翻译： PCT No.PCT / GB93 / 02551 Sec。 371日期：1995年6月21日 102（e）日期1995年6月21日PCT 1993年12月15日PCT公布。公开号WO94 / 14701 日期1994年7月7日一种通过涂覆剂使过碳酸盐稳定的方法，根据该方法，用含有至少一种选自偏硼酸和原硼酸的硼化合物和至少一种硅酸盐的浓缩水溶液处理过碳酸盐颗粒，随后通过除去水以提供涂覆的过碳酸盐颗粒。通过将硼化合物加入到硅酸盐溶液中来制备溶液。涂覆的颗粒可用于洗涤和漂白组合物。

7. 发明授权

US07371717B2 Process for preparing coated alkali metal percarbonate, coated alkali metal percarbonate obtainable by this process, its use in detergent compositions, and detergent compositions containing it 失效
标题翻译：用于制备包覆的碱金属过碳酸盐的方法，通过该方法获得的包覆的碱金属过碳酸盐，其在洗涤剂组合物中的用途和含有它的洗涤剂组合物
公开(公告)号：US07371717B2
公开(公告)日：2008-05-13
申请号：US10203624
申请日：2001-02-14
申请人： Graham R. Horne , Alun P. James , Juan-Teva Carlier , Manfred Mathes
发明人： Graham R. Horne , Alun P. James , Juan-Teva Carlier , Manfred Mathes
IPC分类号： C11D7/08 , C11D7/18 , C11D7/54
CPC分类号： C01B15/106 , C11D3/3942 , C11D17/0039
摘要： A process for preparing coated particulate alkali metal percarbonate in which coating is carried out by mixing percarbonate with a solid particulate coating and agent and optionally with an aqueous liquid, so that the amount of water present during mixing does not exceed 12% of the total weight of the mixture. Coated alkali metal percarbonate obtainable by this process and its use as active bleach in detergent compositions is also disclosed.
摘要翻译：一种制备涂覆的颗粒状碱金属过碳酸盐的方法，其中通过将过碳酸盐与固体颗粒涂料和试剂以及任选的含水液体混合来进行涂层，使得混合期间存在的水的量不超过总重量的12％的混合物。还公开了通过该方法获得的涂覆的碱金属过碳酸盐及其作为洗涤剂组合物中的活性漂白剂的用途。

8. 发明授权

US5463112A Peroxycompounds 失效
标题翻译：过氧化合物
公开(公告)号：US5463112A
公开(公告)日：1995-10-31
申请号：US976997
申请日：1993-02-02
申请人： John P. Sankey , William Sanderson , Graham R. Horne
发明人： John P. Sankey , William Sanderson , Graham R. Horne
IPC分类号： A01N41/04 , C07C409/42 , C11D3/39 , C07C409/08 , C01B15/06
CPC分类号： C07C409/42 , A01N41/04 , C11D3/3945
摘要： This invention concerns novel sulphoperoxyacids having the following generic formula ##STR1## wherein the R', R", and M are as defined in the specification. Bleach compositions and methods of bleaching using such novel sulphoperoxyacids are also taught.
摘要翻译： PCT No.PCT / GB91 / 00921 Sec。 371日期：1993年2月2日 102（e）日期1993年2月2日PCT提交1991年6月7日PCT公布。 WO91 / 18876BC出版物日本1991年12月12日。本发明涉及具有以下通式（IMAGE）的新型磺基过氧酸，其中R'，R“和M如说明书中所定义。还教导了漂白组合物和使用这种新型磺基过氧酸的漂白方法。

9. 发明授权

US5356606A Peroxidic compositions 失效
标题翻译：过氧化合物
公开(公告)号：US5356606A
公开(公告)日：1994-10-18
申请号：US050159
申请日：1993-04-27
申请人： Graham R. Horne , Nicholas A. Troughton
发明人： Graham R. Horne , Nicholas A. Troughton
IPC分类号： C01B15/12 , C11D3/39 , C01B35/12
CPC分类号： C01B15/123 , C11D3/394 , C11D3/3947
摘要： A composition having improved physical stability comprising an aqueous peroxidic solution of an alkali metal oxyboron compound containing alkali metal to boron in a substoichiometric mole ratio into which there has been introduced an effective stabilizing amount of cyclohexane -1,2-diaminotetra (methylene phosphonic acid) or a water soluble salt thereof. Also a process for enhancing the physical stability of an aqueous peroxidic solution of an alkali metal oxyboron compound containing alkali metal to boron in a substoichiometric mole ratio which is characterized by introducing into the solution an effective stabilizing amount of cyclohexane -1,2-diaminotetra (methylene phosphonic acid) or a water soluble salt thereof.
摘要翻译： PCT No.PCT / GB91 / 01589 Sec。 371日期：1993年4月27日 102（e）日期1993年4月27日PCT 1991年9月17日PCT公布。出版物WO92 / 06036 日期：1992年4月16日。具有改进的物理稳定性的组合物，其包含以化学计量摩尔比计含有碱金属与硼的碱金属氧硼化合物的过氧化物水溶液，其中引入有效稳定量的环己烷-1,2 - 二氨基四（亚甲基膦酸）或其水溶性盐。还提供了一种以亚化学计量摩尔比提高含有碱金属与硼的碱金属氧硼化合物的过氧化氢水溶液的物理稳定性的方法，其特征在于将有效稳定量的环己烷-1,2-二氨基四（亚甲基膦酸）或其水溶性盐。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式