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1. 发明授权

US4100337A Olefin polymerization process and catalyst therefor 失效
公开(公告)号：US4100337A
公开(公告)日：1978-07-11
申请号：US823749
申请日：1977-08-11
申请人： Allen Noshay , Frederick John Karol
发明人： Allen Noshay , Frederick John Karol
IPC分类号： C08F4/00 , C08F4/06 , C08F4/42 , C08F4/60 , C08F4/78 , C08F10/02 , C08F10/00
CPC分类号： C08F10/02
摘要： Catalysts for the polymerization of ethylene and the copolymerization of ethylene with other olefins have been prepared by depositing an organo-chromium compound on a silica support which has been fluorided at low temperatures.

2. 发明授权

US4077904A Olefin polymerization process and catalyst therefor 失效
标题翻译：烯烃聚合方法及其催化剂
公开(公告)号：US4077904A
公开(公告)日：1978-03-07
申请号：US700843
申请日：1976-06-29
申请人： Allen Noshay , Frederick John Karol
发明人： Allen Noshay , Frederick John Karol
IPC分类号： C08F4/00 , C08F4/06 , C08F4/42 , C08F4/60 , C08F4/78 , C08F10/02 , C08F4/02
CPC分类号： C08F10/02
摘要： Catalysts for the polymerization of ethylene and the copolymerization of ethylene with other olefins have been prepared by depositing an organo-chromium compound on a silica support which has been fluorided at low temperatures.
摘要翻译：用于聚合乙烯的催化剂和乙烯与其它烯烃的共聚已经通过在低温下氟化的二氧化硅载体上沉积有机铬化合物来制备。

3. 发明授权

US06562750B2 Catalyst for the production of olefin polymers 失效
公开(公告)号：US06562750B2
公开(公告)日：2003-05-13
申请号：US10042797
申请日：2002-01-09
申请人： Walter Thomas Reichle , Frederick John Karol
发明人： Walter Thomas Reichle , Frederick John Karol
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C07F7/003 , C08F210/16 , Y10S526/901 , C08F4/64189 , C08F4/6028 , C08F4/64048 , C08F210/14
摘要： A catalyst composition for the polymerization of olefins is provided, comprising a bis(hydroxy aromatic nitrogen ligand) transition metal catalyst precursor and an activating cocatalyst.

4. 发明授权

US6066703A Process for the production of olefin polymers 失效
标题翻译：生产烯烃聚合物的方法
公开(公告)号：US6066703A
公开(公告)日：2000-05-23
申请号：US977583
申请日：1997-11-25
申请人： Walter Thomas Reichle , Xinmin Yang , Frederick John Karol
发明人： Walter Thomas Reichle , Xinmin Yang , Frederick John Karol
IPC分类号： B01J31/22 , C08F4/64 , C08F4/642 , C08F4/649 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/65912 , C08F4/6592 , Y10S526/901 , Y10S526/943
摘要： A process for the polymerization of an olefin which employs as the catalyst composition the reaction product of a) a monocycloalkadienyl catalyst precursor; b) an activity enhancing cycloalkadiene; and c) an activating cocatalyst is disclosed.
摘要翻译：烯烃的聚合方法，其用作催化剂组合物a）单环烷二烯基催化剂前体的反应产物; b）增强环二烯的活性; 和c）活化助催化剂。

5. 发明授权

US5852146A Catalyst for the production of olefin polymers 失效
公开(公告)号：US5852146A
公开(公告)日：1998-12-22
申请号：US670507
申请日：1996-06-27
申请人： Walter Thomas Reichle , Frederick John Karol
发明人： Walter Thomas Reichle , Frederick John Karol
IPC分类号： C07F7/00 , C07F7/28 , C08F4/60 , C08F4/602 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , C07F7/006 , C08F210/16 , Y10S526/901
摘要： A catalyst composition for the polymerization of olefins is provided, comprising a bis(hydroxy aromatic nitrogen ligand) transition metal catalyst precursor and an activating cocatalyst.

6. 发明授权

US5756416A Catalyst composition having improved comonomer reactivity 失效
标题翻译：催化剂组合物具有改善的共聚单体反应性
公开(公告)号：US5756416A
公开(公告)日：1998-05-26
申请号：US563702
申请日：1995-11-28
申请人： Eric Paul Wasserman , Sun Chueh Kao , Frederick John Karol
发明人： Eric Paul Wasserman , Sun Chueh Kao , Frederick John Karol
IPC分类号： C08F4/44 , C08F4/602 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/6192 , Y10S526/901 , Y10S526/943
摘要： A catalyst composition comprising A) an aluminoxane-impregnated support prepared by contacting an aluminoxane with an inert carrier material and heating to a temperature of at least about 80.degree. C.; B) a metallocene of the formula: (L).sub.y (L')MY.sub.(x-y-1) wherein M is a metal from groups IIIB to VIII of the Periodic Table; each L and L' is independently a cycloalkadienyl group bonded to M; each Y is independently hydrogen, an aryl, alkyl, alkenyl, alkylaryl, or arylalkyl radical having 1-20 carbon atoms, a hydrocarboxy radical having from 1-20 carbon atoms, a halogen, RCO.sub.2 --, or R.sub.2 N--, wherein R is a hydrocarbyl group containing 1 to about 20 carbon atoms; n and m are each 0, 1, 2, 3, or 4; y is 0, 1, or 2; x is 1, 2, 3, or 4; and x-y.gtoreq.1; C) a bulky aluminum alkyl of the formula: AlR.sup.1.sub.x R.sup.2.sub.(3-x) wherein R.sup.1 is a hydrocarbyl group having 1 to 12 carbon atoms; x is an integer from 0 to 2; R.sup.2 is a hydrocarbyl group of the formula --(CH.sub.2).sub.y -- R.sup.3, wherein y is an integer from 1 to 8; and R.sup.3 is a saturated or unsaturated hydrocarbyl group having 3 to 12 carbon atoms containing at least one ring, and D) methylaluminoxane is provided. The catalyst composition may be used to prepare olefin polymers having increased short chain branching frequency.
摘要翻译：一种催化剂组合物，其包含A）通过使铝氧烷与惰性载体材料接触并加热到至少约80℃的温度而制备的铝氧烷浸渍的载体; B）下式的茂金属：（L）y（L'）MY（x-y-1）其中M是元素周期表IIIB至VIII族的金属; 每个L和L'独立地是与M键合的环二烯基; 每个Y独立地是氢，具有1-20个碳原子的芳基，烷基，烯基，烷基芳基或芳基烷基，具有1-20个碳原子的烃基，卤素，RCO2-或R2N-，其中R是含有1至约20个碳原子的烃基; n和m各自为0,1,2,3或4; y为0,1或2; x是1，2，3或4; 和x-y> / = 1; C）下式的大体积的烷基铝：AlR 1 R 2（3-x）其中R 1是具有1至12个碳原子的烃基; x是0到2的整数; R 2是式 - （CH 2）y -R 3的烃基，其中y是1至8的整数; R3为含有至少一个环的碳原子数为3〜12的饱和或不饱和烃基，提供D）甲基铝氧烷。催化剂组合物可用于制备具有增加的短链支化频率的烯烃聚合物。

7. 发明授权

US06380390B1 Catalyst for the production of olefin polymers 失效
标题翻译：用于生产烯烃聚合物的催化剂
公开(公告)号：US06380390B1
公开(公告)日：2002-04-30
申请号：US09482795
申请日：2000-01-13
申请人： Walter Thomas Reichle , Frederick John Karol
发明人： Walter Thomas Reichle , Frederick John Karol
IPC分类号： C07D21516
CPC分类号： C08F10/00 , C07F7/003 , C08F210/16 , Y10S526/901 , C08F4/64189 , C08F4/6028 , C08F4/64048 , C08F210/14
摘要： A catalyst composition for the polymerization of olefins is provided, comprising a bis(hydroxy aromatic nitrogen ligand) transition metal catalyst precursor and an activating cocatalyst.
摘要翻译：提供了一种用于烯烃聚合的催化剂组合物，其包含双（羟基芳族氮配体）过渡金属催化剂前体和活化助催化剂。

8. 发明授权

US6069109A Process for the production of half-sandwich transition metal based catalyst precursors 失效
标题翻译：制备半夹心过渡金属基催化剂前体的方法
公开(公告)号：US6069109A
公开(公告)日：2000-05-30
申请号：US108824
申请日：1998-07-01
申请人： Sun-Chueh Kao , Frederick John Karol
发明人： Sun-Chueh Kao , Frederick John Karol
IPC分类号： B01J31/22 , C07F17/00 , C08F4/64 , C08F4/6592 , C08F10/00 , B01J31/00 , C07F7/00 , C07F7/28
CPC分类号： B01J31/1805 , B01J31/2204 , B01J31/223 , B01J31/2295 , C07F17/00 , C08F10/00 , B01J2531/30 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/60 , B01J2531/70 , B01J2531/80
摘要： A process for the production of a catalyst precursor comprising reacting (a) a metallocene dihalide; (b) a compound of the formula: ##STR1## wherein each Q is the same or different and is independently selected from the group consisting of O, NR, CR.sub.2, and S; E is either C or S; Z is selected from the group consisting of --OR, --NR.sub.2, --CR.sub.3, --SR, --SiR.sub.3, --PR.sub.2, --H, and a substituted or unsubstituted aryl group; and each R is independently a group containing carbon, silicon, nitrogen, oxygen, and/or phosphorus; and (c) a trialkylamine.
摘要翻译：一种制备催化剂前体的方法，包括使（a）金属茂二卤化物（b）下式的化合物：其中每个Q相同或不同并且独立地选自O，NR，CR 2和S; E是C或S; Z选自-OR，-NR2，-CR3，-SR，-SiR3，-PR2，-H和取代或未取代的芳基; 并且每个R独立地是含有碳，硅，氮，氧和/或磷的基团; 和（c）三烷基胺。

9. 发明授权

US5852143A Production of polyethylene using stereoisomeric metallocenes 失效
标题翻译：使用立体异构金属茂生产聚乙烯
公开(公告)号：US5852143A
公开(公告)日：1998-12-22
申请号：US838182
申请日：1997-04-16
申请人： Purna Chand Sishta , Eric Paul Wasserman , Frederick John Karol
发明人： Purna Chand Sishta , Eric Paul Wasserman , Frederick John Karol
IPC分类号： C08F2/34 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/16
CPC分类号： C08F10/00 , C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/901 , Y10S526/943
摘要： Polyethylene having a broad molecular weight distribution, a narrow comonomer distribution and excellent processability is easily and cost effectively made using stereoisomeric mixtures of bridged metallocene catalysts containing cycloalkadienyl ligands with facial chirality.
摘要翻译：具有宽分子量分布，窄共聚单体分布和优异加工性能的聚乙烯使用含有环链二烯基配体的桥连金属茂催化剂与面部手性的立体异构体混合物容易且经济地进行。

10. 发明授权

US5644023A Process for the manufacture of copolymers of ethylene and carbon monoxide 失效
标题翻译：制备乙烯和一氧化碳共聚物的方法
公开(公告)号：US5644023A
公开(公告)日：1997-07-01
申请号：US871652
申请日：1992-04-21
申请人： Nicholas Joseph Conti , Frederick John Karol , George Norris Foster
发明人： Nicholas Joseph Conti , Frederick John Karol , George Norris Foster
IPC分类号： B01J31/16 , B01J31/18 , B01J31/24 , C08G67/02
CPC分类号： B01J31/1616 , B01J31/18 , B01J31/2409 , C08G67/02 , B01J2531/822 , B01J2531/824 , B01J2531/847
摘要： A process comprising:(a) introducing a mixture comprising one or more alpha-olefins, carbon monoxide, and, optionally, one or more dienes into a reaction zone under polymerization conditions;(b) contacting the mixture with a catalyst prepared by a process comprising:(i) providing a transition metal in the zero valence state adsorbed on a support;(ii) reacting the supported metal with an oxidant to form a supported compound wherein the metal has a positive valence;(iii) ligating the supported compound with a ligand; and(c) introducing a reoxidant into the reaction zone to maintain the positive valence of the metal.
摘要翻译：一种方法，包括：（a）在聚合条件下将包含一种或多种α-烯烃，一氧化碳和任选的一种或多种二烯的混合物引入反应区; （b）使所述混合物与通过以下方法制备的催化剂接触：所述方法包括：（i）提供吸附在载体上的零价态的过渡金属; （ii）使负载的金属与氧化剂反应以形成其中金属具有正价的负载化合物; （iii）将负载的化合物与配体连接; 和（c）将再氧化物引入反应区以维持金属的正价。

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