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    • 6. 发明授权
    • Shelf-stable catalyst component for RTV silicone composition
    • 用于RTV硅酮组合物的稳定的催化剂组分
    • US4448928A
    • 1984-05-15
    • US476174
    • 1983-03-17
    • Steven H. KleinAlfred H. Smith, Jr.
    • Steven H. KleinAlfred H. Smith, Jr.
    • C08J3/24C08K13/02C08L83/06
    • C08J3/24C08K13/02C08J2383/04
    • A process for producing a shelf-stable catalyst component for a room temperature vulcanizable silicone rubber composition comprising (a) mixing a organopolysiloxane fluid with first from 1 to 15 percent by weight of the total amounts of the following ingredients (1) an alkyl silicate cross-linking agent (2) a catalytic promoter which is a tin salt and (3) a self-bonding additive which is nitrogen-functional self-bonding additive until there is a uniform mixture; (b) adding to the mixture from 10 to 250 parts of filler and mixing the ingredients to a uniform mixture wherein the mixture is heated at a temperature of at least 100.degree. C. for at least 1 hour so as to drive off moisture and form a stable base mixture and then adding to the stable base mixture the rest of the cross-linking agent, the catalytic promoter and the shelf-bonding additive to form a self-stable uniform mixture.
    • 一种制备用于室温可硫化硅橡胶组合物的储存稳定的催化剂组分的方法,包括(a)将有机聚硅氧烷流体与以下成分(1)的总量的1至15重量% 连接剂(2)作为锡盐的催化促进剂和(3)自粘结添加剂,直到有均匀的混合物为氮功能性自粘结添加剂; (b)将混合物从10至250份添加到填料中并将成分混合到均匀的混合物中,其中将混合物在至少100℃的温度下加热至少1小时,以便除去水分并形成 稳定的碱性混合物,然后向稳定的碱混合物中加入其余的交联剂,催化促进剂和搁板添加剂以形成自稳定的均匀混合物。
    • 7. 发明授权
    • Shelf-stable catalyst component for RTV silicone composition
    • 用于RTV硅酮组合物的稳定的催化剂组分
    • US4388433A
    • 1983-06-14
    • US238333
    • 1981-02-26
    • Steven H. KleinAlfred H. Smith, Jr.
    • Steven H. KleinAlfred H. Smith, Jr.
    • C08J3/24C08K13/02C08L83/06
    • C08J3/24C08K13/02C08J2383/04Y10S524/906
    • A process for producing a shelf-stable catalyst component for a room temperature vulcanizable silicone rubber composition comprising (a) mixing a organopolysiloxane fluid with first from 1 to 15 percent by weight of the total amounts of the following ingredients (1) an alkyl silicate cross-linking agent (2) a catalytic promoter which is a tin salt and (3) a self-bonding additive which is nitrogen-functional self-bonding additive until there is a uniform mixture; (b) adding to the mixture from 10 to 250 parts of filler and mixing the ingredients to a uniform mixture wherein the mixture is heated at a temperature of at least 100.degree. C. for at least 1 hour so as to drive off moisture and form a stable base mixture and then adding to the stable base mixture the rest of the cross-linking agent, the catalytic promoter and the shelf-bonding additive to form a self-stable uniform mixture.
    • 一种制备用于室温可硫化硅橡胶组合物的储存稳定的催化剂组分的方法,包括(a)将有机聚硅氧烷流体与以下成分(1)的总量的1至15重量% 连接剂(2)作为锡盐的催化促进剂和(3)自粘结添加剂,直到有均匀的混合物为氮功能性自粘结添加剂; (b)将混合物从10至250份添加到填料中并将成分混合到均匀的混合物中,其中将混合物在至少100℃的温度下加热至少1小时,以便除去水分并形成 稳定的碱性混合物,然后向稳定的碱混合物中加入其余的交联剂,催化促进剂和搁板添加剂以形成自稳定的均匀混合物。
    • 9. 发明授权
    • Low vapor transmission rate silicone composition
    • 低蒸气透过率硅胶组成
    • US4131588A
    • 1978-12-26
    • US750061
    • 1976-12-13
    • Alfred H. Smith, Jr.
    • Alfred H. Smith, Jr.
    • C08L83/00C08K3/34C08K5/09C08K5/5419C08K5/544C08K13/02C08L83/04
    • C08K3/34Y10S528/901
    • A low moisture vapor transmission rate room temperature vulcanizable silicone composition comprising a silanol end-stopped diorganopolysiloxane with optionally a reinforcing or extending filler, an alkyl silicate crosslinking agent or in the alternative a co-polymer composed of monofunctional and tetrafunctional units and a catalyst which is the metal salt of carboxylic acid such as dibutyl tin dilaurate where the improvement comprises having in such a composition from 75 to 150 parts by weight of a vapor barrier filler which is mica with optionally up to 30% by weight of said vapor barrier filler being talc, wherein the above concentration of filler is based upon 100 parts of the silanol end-stopped diorganopolysiloxane polymer. Also in the present invention there is envisioned as SiH Olefin platinum catalyzed composition which has the foregoing mica as a vapor barrier filler.
    • 低水分蒸气透过率室温可硫化硅氧烷组合物,其包含硅烷醇末端停止的二有机聚硅氧烷,任选地是增强或延伸填料,烷基硅酸盐交联剂或替代性的由单官能和四官能单元组成的共聚物和催化剂, 羧酸的金属盐,例如二月桂酸二丁基锡,其中改进包括具有75至150重量份的蒸气阻隔填料,其为云母,任选地至多30重量%的所述蒸气阻隔填料为滑石 ,其中上述填料浓度基于100份硅烷醇封端的二有机聚硅氧烷聚合物。 在本发明中,也可以想象出作为阻气性填料的上述云母的SiH烯烃铂催化组合物。