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    • 4. 发明申请
    • Method for enhanced synthesis of carbon nanostructures
    • 碳纳米结构增强合成方法
    • US20090136413A1
    • 2009-05-28
    • US12286571
    • 2008-10-01
    • Zhongrui LiYang XuAlexandru S. Biris
    • Zhongrui LiYang XuAlexandru S. Biris
    • D01F9/127B82B3/00
    • D01F9/127B01J21/10B01J23/75B01J23/78B01J23/881B01J23/8872B01J27/232B82Y30/00B82Y40/00C01B32/162C01B2202/02C01B2202/04C01B2202/06C01P2004/133
    • A method of significantly improving carbon nanotube or carbon nanofiber yield from catalytic chemical vapor deposition of a carbon-containing gas comprising at least one hydrocarbon with the assistance of a proper amount of carbon dioxide (CO2). The catalytic particles preferably contain at least one metal from Group VIII (Fe, Co, Ni or the like) or/and one metal from Group VIb, including Mo, W, and Cr. The catalytic particles are preferably supported on oxide powders such as MgO, Al2O3, SiO, CaO, TiO, and ZrO, or a flat substrate such as, but not limited to, a Si wafer. The carbon nanotube or nanofiber product is preferably formed by exposing the catalyst to a mixture of a carbon-containing gas comprising at least one hydrocarbon with a proper amount of CO2 at a sufficiently high temperature. In an alternative embodiment, other oxygen-containing gases, such as alcohols, may be included in the mixture in addition to carbon dioxide.
    • 在适当量的二氧化碳(CO 2)的帮助下,通过催化化学气相沉积包含至少一种烃的含碳气体显着改善碳纳米管或碳​​纳米纤维的方法。 催化剂颗粒优选含有至少一种来自VIII族(Fe,Co,Ni等)的金属或/和VIb族的一种金属,包括Mo,W和Cr。 催化剂颗粒优选负载在诸如MgO,Al 2 O 3,SiO,CaO,TiO和ZrO的氧化物粉末上,或者诸如但不限于Si晶片的平坦基板。 碳纳米管或纳米纤维产品优选通过在足够高的温度下将催化剂暴露于包含至少一种烃的含碳气体与适量CO 2的混合物来形成。 在另一个实施方案中,除了二氧化碳之外,其它含氧气体,例如醇,可以包括在混合物中。