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1. 发明授权

US4912264A Method for producing hydroxy-containing alkylated aromatic compounds 失效
标题翻译：制备含羟基烷基化芳族化合物的方法
公开(公告)号：US4912264A
公开(公告)日：1990-03-27
申请号：US059119
申请日：1987-06-03
申请人： Akira Takeshita , Shinzaburo Masaki , Takeo Fujii , Tooru Tokumaru , Akira Murakami
发明人： Akira Takeshita , Shinzaburo Masaki , Takeo Fujii , Tooru Tokumaru , Akira Murakami
IPC分类号： B01J23/24 , B01J27/188 , C07B31/00 , C07B37/02 , C07B61/00 , C07C27/00 , C07C37/14 , C07C39/06 , C07C39/14 , C07C67/00
CPC分类号： C07C37/14 , C07C37/16 , C07C2101/14
摘要： Process for producing hydroxy-containing alkylated aromatic compounds by the liquid phase reaction of an aromatic compound having at least one hydroxyl group with an alkylating agent in the presence of a heteropoly acid and water.
摘要翻译：通过具有至少一个羟基的芳族化合物与烷基化剂的液相反应在杂多酸和水的存在下制备含羟基的烷基化芳族化合物的方法。

2. 再颁专利

USRE34076E Method for producing hydroxy-containing alkylated aromatic compounds 失效
公开(公告)号：USRE34076E
公开(公告)日：1992-09-22
申请号：US730116
申请日：1991-07-15
申请人： Akira Takeshita , Shinzaburo Masaki , Takeo Fujii , Tooru Tokumaru , Akira Murakami
发明人： Akira Takeshita , Shinzaburo Masaki , Takeo Fujii , Tooru Tokumaru , Akira Murakami
IPC分类号： B01J23/24 , B01J27/188 , C07B31/00 , C07B37/02 , C07B61/00 , C07C27/00 , C07C37/14 , C07C39/06 , C07C39/14 , C07C67/00
CPC分类号： C07C37/14 , C07C37/16 , C07C2101/14
摘要： Process for producing hydroxy-containing alkylated aromatic compounds by the liquid phase reaction of an aromatic compound having at least one hydroxyl group with an alkylating agent in the presence of a heteropoly acid and water.

3. 发明授权

US5399791A Process for production of cresols 失效
标题翻译：甲酚生产工艺
公开(公告)号：US5399791A
公开(公告)日：1995-03-21
申请号：US202160
申请日：1994-02-25
申请人： Kiyoshi Ikimi , Yoichi Ikeda , Akira Murakami , Kazushige Okamoto , Tooru Tokumaru , Motoo Hazama
发明人： Kiyoshi Ikimi , Yoichi Ikeda , Akira Murakami , Kazushige Okamoto , Tooru Tokumaru , Motoo Hazama
IPC分类号： C07C39/07 , C07C37/08 , C07C37/06
CPC分类号： C07C39/07
摘要： There is disclosed a process for the production of cresols, including the steps of: (a) conducting oxygenation of cymene with oxygen gas or an oxygen-containing gas without any addition of an alkali, thereby obtaining a solution of oxygenation products containing tertiary and primary hydroperoxides of cymene; (b) washing the solution of oxygenation products obtained in step (a) with an aqueous alkali solution at a temperature in the range of from 10.degree. to 95.degree. C.; (c) subjecting the solution of oxygenation products obtained in step (b) to hydrogenation at a temperature in the range of from 60.degree. to 100.degree. C. to decrease the content of primary hydroperoxide in such a manner that the weight ratio of primary hydroperoxide to tertiary hydroperoxide is not greater than 1/25 (w/w); (d) subjecting the solution treated in step (c) to decomposition in the presence of a catalyst; and (e) subjecting the solution treated in step (d) to hydrogenation to obtain cresols.
摘要翻译：公开了一种生产甲酚的方法，包括以下步骤：（a）在不加碱的条件下，用氧气或含氧气体进行甲基异丙基苯的氧化反应，从而得到含有叔，伞形氢过氧化物; （b）在10℃至95℃的温度范围内用碱水溶液洗涤步骤（a）中获得的氧合产物的溶液; （c）将步骤（b）中获得的氧合产物溶液在60℃至100℃的温度范围内进行氢化，以降低初级氢过氧化物的含量，使得初级氢过氧化物的重量比叔氢过氧化物不大于1/25（w / w）; （d）使在步骤（c）中处理的溶液在催化剂存在下进行分解; 和（e）使步骤（d）中处理的溶液进行氢化以获得甲酚。

4. 发明授权

US5600026A Process for production of cresols 失效
标题翻译：甲酚生产工艺
公开(公告)号：US5600026A
公开(公告)日：1997-02-04
申请号：US393031
申请日：1995-02-23
申请人： Kiyoshi Ikimi , Yoichi Ikeda , Akira Murakami , Kazushige Okamoto , Tooru Tokumaru , Motoo Hazama
发明人： Kiyoshi Ikimi , Yoichi Ikeda , Akira Murakami , Kazushige Okamoto , Tooru Tokumaru , Motoo Hazama
IPC分类号： C07C39/07 , C07C409/08 , C07C37/08 , C07C37/06 , C07C37/68
CPC分类号： C07C39/07 , C07C407/00 , C07C409/08
摘要： There is disclosed a process for the production of cresols, including the steps of: (a) conducting oxygenation of cymene with oxygen gas or an oxygen-containing gas, thereby obtaining a solution of oxygenation products containing tertiary and primary hydroperoxides of cymene; (b) reacting the solution of oxygenation products obtained in the step (a) with an organic quaternary ammonium salt and an alkali, or with an organic quaternary ammonium hydroxide, thereby decreasing the content of primary hydroperoxide; (c) subjecting the reaction mixture in the step (b) to decomposition in the presence of a catalyst; and (d) subjecting the decomposition mixture in the step (c) to hydrogenation, thereby obtaining the desired cresols.
摘要翻译：公开了一种生产甲酚的方法，包括以下步骤：（a）用氧气或含氧气体进行甲基异丙基苯的氧化反应，从而得到含有甲基异丙苯的叔级和过氧化氢过氧化氢的氧化产物溶液; （b）使步骤（a）中得到的氧合产物的溶液与有机季铵盐和碱或与有机季铵氢氧化物反应，从而降低初级氢过氧化物的含量; （c）使步骤（b）中的反应混合物在催化剂存在下分解; 和（d）使步骤（c）中的分解混合物进行氢化，从而得到所需的甲酚。

5. 发明授权

US5442114A Process for producing aromatic amide compounds 失效
标题翻译：芳香族酰胺化合物的制备方法
公开(公告)号：US5442114A
公开(公告)日：1995-08-15
申请号：US182460
申请日：1994-01-18
申请人： Kan Takamine , Michio Yamato , Akira Murakami , Tooru Tokumaru , Yoshinori Nakayama , Motoo Hazama
发明人： Kan Takamine , Michio Yamato , Akira Murakami , Tooru Tokumaru , Yoshinori Nakayama , Motoo Hazama
IPC分类号： C07C231/02 , C07C235/24
CPC分类号： C07C231/02 , C07C235/24
摘要： There is disclosed a process for producing an aromatic amide compound of the general formula (4), including the steps of subjecting an o-nitrophenol compound of the general formula (1) to catalytic reduction in acetone or an aromatic hydrocarbon solvent under the presence of a nickel catalyst to give an o-aminophenol compound of the general formula (2); and (b) subjecting the o-aminophenol compound of the general formula (2) to condensation with an acid chloride compound having a sulfur content of 0.5% or less, based on the weight of the acid chloride compound, of the general formula (3) in acetone or an aromatic hydrocarbon solvent under an atmosphere of an inert gas having an oxygen concentration of 1% or less. The acid chloride compound having a sulfur content of 0.5% or less, based on the weight of the acid chloride compound, of the general formula (3) may be obtained by allowing a carboxylic acid compound of the general formula (5) to react with thionyl chloride and by concentrating the reaction mixture. Also disclosed is another process for producing an aromatic amide compound of the general formula (4), including the step of subjecting an o-aminophenol hydrochloride salt of the general formula (6) to condensation with an acid chloride compound having a sulfur content of 0.8% or less, based on the weight of the acid chloride compound, of the general formula (3) in an inert solvent.
摘要翻译：公开了通式（4）的芳香族酰胺化合物的制造方法，包括以下步骤：将通式（1）的邻硝基苯酚化合物在丙酮或芳族烃溶剂中进行催化还原，镍催化剂，得到通式（2）的邻氨基苯酚化合物; 和（b）将通式（2）的邻氨基苯酚化合物与基于酰基氯化合物的重量的硫含量为0.5％以下的酰基氯化合物进行缩合，通式（3））在丙酮或芳烃溶剂中，在氧浓度为1％以下的惰性气体气氛下进行。通式（3）的酰基氯化合物的硫含量为0.5％以下的酰氯化合物可以通过使通式（5）的羧酸化合物与亚硫酰氯，并浓缩反应混合物。还公开了制备通式（4）的芳族酰胺化合物的另一种方法，包括使通式（6）的邻氨基苯酚盐酸盐与硫含量为0.8的酰氯化合物缩合的步骤％以下，基于酰基氯化合物的重量，在惰性溶剂中。

6. 发明授权

US3980662A Process for preparing acid amides 失效
标题翻译：酰胺的制备方法
公开(公告)号：US3980662A
公开(公告)日：1976-09-14
申请号：US478613
申请日：1974-06-12
申请人： Yoshihiro Watanabe , Takeshi Yamahara , Shun Inokuma , Tooru Tokumaru
发明人： Yoshihiro Watanabe , Takeshi Yamahara , Shun Inokuma , Tooru Tokumaru
IPC分类号： B01J31/16 , B01J31/18 , C07D213/81 , C07D213/82 , C07C102/08
CPC分类号： C07D213/82 , B01J31/1658 , B01J31/1805 , B01J31/181 , C07D213/81 , B01J2531/16
摘要： The acid amides are produced by a process comprising hydrating a nitrile compound in the presence of a copper-containing polymer having basic nitrogenous groups in the polymer chain or linked with the polymer chain as a catalyst.
摘要翻译：酸酰胺通过包括在聚合物链中具有碱性含氮基团的含铜聚合物或作为催化剂与聚合物链连接的腈化聚合物存在下使腈化合物水合的方法来制备。

7. 发明授权

US4769494A Process for producing O,O-di-lower-alkylchlorothiophosphate 失效
标题翻译： O，O-二低级烷基氯代硫代磷酸酯的制备方法
公开(公告)号：US4769494A
公开(公告)日：1988-09-06
申请号：US11009
申请日：1987-02-05
申请人： Motomasa Ohsu , Koichi Kamemoto , Manabu Yahata , Tooru Tokumaru , Takeshi Hioki , Hiroshi Ueda
发明人： Motomasa Ohsu , Koichi Kamemoto , Manabu Yahata , Tooru Tokumaru , Takeshi Hioki , Hiroshi Ueda
IPC分类号： C07F9/20 , C07F9/02
CPC分类号： C07F9/20
摘要： A continuous process for producing O,O-di-lower alkylchlorothiophosphate very important as an intermediate for organo-phosphate series agricultural chemicals which comprises continuously reacting phosphorus sulfochloride with a lower alcohol in the presence of caustic soda according to a multi-stage reaction form comprising from 3 to 8 stages in which the following conditions are satisfied:(1) The amounts of caustic soda and a lower alcohol used shall be from 2 to 2.2 moles and 10 moles or more, respectively, based on 1 mole of phosphorus sulfochloride.(2) Caustic soda, water and the lower alcohol shall be used as a caustic soda/water/lower alcohol solution, and besides the caustic soda concentration of the aqueous caustic soda in said solution shall be from 30.0 to 99.5 wt.%.(3) To the 1st reaction stage shall be continuously supplied the whole amount of phosphorus sulfochloride required and from 45 to 85 wt.% each of the amounts of caustic soda and the lower alcohol required; and to the 2nd and subsequent reaction stages shall be continuously supplied the residual caustic soda and lower alcohol in divided portions so that the substantial amounts supplied become successively small toward the final reaction stage.(4) The temperature of the reaction system shall be -5.degree. C. or lower.(5) The residence time in the reaction system shall be within 4 hours.
摘要翻译：一种用于生产作为有机磷酸酯系农药的中间体非常重要的O，O-二低级烷基氯硫代磷酸酯的连续方法，其包括在苛性钠存在下，根据多阶段反应形式连续地使磷酰氯与低级醇反应，包括从3到8个阶段，其中满足以下条件：（1）基于1摩尔磷酰氯，苛性钠和低级醇的用量分别为2至2.2摩尔和10摩尔或更多。（2）苛性钠，水和低级醇应用作苛性钠/水/低级醇溶液，除了所述溶液中的苛性钠水溶液的苛性钠浓度外还应为30.0至99.5重量％。（3）向第一反应阶段连续供应所需的全部硫磺磷酸盐和每一种苛性钠和所需的低级醇的45至85重量％; 并且连续向第二和随后的反应阶段连续地供应残留的苛性钠和低级醇，使得所供应的实质量向着最终反应阶段依次小。（4）反应体系的温度应在-5℃以下。（5）反应体系中的停留时间应在4小时内。

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