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1. 发明授权

US5352763A Biodegradable optically active polymers and intermediate oligomers thereof, and process for producing them 失效
标题翻译：可生物降解的光学活性聚合物及其中间体低聚物及其生产方法
公开(公告)号：US5352763A
公开(公告)日：1994-10-04
申请号：US5081
申请日：1993-01-15
申请人： Akio Yamaguchi , Yoji Hori , Takashi Imai , Motoki Suzuki , Susumu Akutagawa
发明人： Akio Yamaguchi , Yoji Hori , Takashi Imai , Motoki Suzuki , Susumu Akutagawa
IPC分类号： C07C69/675 , C07C235/10 , C08G18/32 , C08G18/42 , C08G18/73 , C08G63/06 , C08G63/60 , C08G63/64 , C08G63/685 , C08G63/695 , C08L101/16
CPC分类号： C08G18/4283 , C07C235/10 , C07C69/675 , C08G18/3221 , C08G63/60 , C08G63/695 , C08G2230/00
摘要： An optically active oligomer obtained by polycondensation of an (R)-3-hydroxyalkanoic acid alkyl ester and at least one of a diol, a diamine and an amino alcohol and an optically active polymer obtained by copolymerization of said oligomer and a monomer selected from diisocyanic acid esters, dicarboxylic acid derivatives, and dichlorosilanes are disclosed. Novel functional polymers with biodegradability and hydrolyzability are produced with industrial advantage.
摘要翻译：通过（R）-3-羟基链烷酸酯和二醇，二胺和氨基醇中的至少一种和通过所述低聚物和选自二异氰酸酯的单体共聚得到的光学活性聚合物缩聚得到的光学活性低聚物酸酯，二羧酸衍生物和二氯硅烷。具有生物降解性和水解性的新型功能聚合物具有工业优势。

2. 发明授权

US5221755A Optically active ether lactone, optically active polymer thereof, and process for producing the polymer 失效
标题翻译：光学活性醚内酯，其光学活性聚合物，以及聚合物的制造方法
公开(公告)号：US5221755A
公开(公告)日：1993-06-22
申请号：US866519
申请日：1992-04-10
申请人： Akio Yamaguchi , Yoji Hori , Susumu Akutagawa
发明人： Akio Yamaguchi , Yoji Hori , Susumu Akutagawa
IPC分类号： C07B61/00 , C07D321/08 , C08G63/08 , C08G63/664 , C08G63/78
CPC分类号： C07D321/08
摘要： An optically active 7-substituted-1,4-dioxepan-5-one derivative represented by the general formula (I): ##STR1## wherein R represents an alkyl group having from 1 to 5 carbon atoms; and * means an asymmetric carbon atom, is disclosed. An optically active polymer represented by formula (II): ##STR2## wherein R and * are as defined above; and n is an integer of 25 or more, obtained by ring opening polymerization of the optically active 7-substituted-1,4-dioxepan-5-one derivative represented by formula (I) is also disclosed. A process for producing the optically active polymer represented by formula (II) is further disclosed, comprising subjecting an optically active 7-substituted-1,4-dioxepan-5-one derivative represented by formula (I) to ring opening polymerization in the presence of at least one catalyst selected from the group consisting of (i) an organotin compound, (ii) an organoaluminum compound and water, and (iii) an organozinc compound and water.
摘要翻译：由通式（I）表示的光学活性的7-取代-1,4-二氧杂环庚烯-5-酮衍生物：其中R表示具有1至5个碳原子的烷基; 和*表示不对称碳原子。由式（II）表示的光学活性聚合物：其中R和*如上所定义; 还公开了通过式（I）表示的光学活性7-取代-1,4-二氧杂环庚烷-5-酮衍生物的开环聚合得到的n为25以上的整数。进一步公开了制备由式（II）表示的光学活性聚合物的方法，包括使式（I）表示的光学活性7-取代-1,4-二氧杂环庚烷-5-酮衍生物在存在下开环聚合选自（i）有机锡化合物，（ii）有机铝化合物和水，和（iii）有机锌化合物和水的至少一种催化剂。

3. 发明授权

US5264547A Optically active ether lactone, optically active polymer thereof, and process for producing the polymer 失效
公开(公告)号：US5264547A
公开(公告)日：1993-11-23
申请号：US25059
申请日：1993-03-02
申请人： Akio Yamaguchi , Yoji Hori , Susumu Akutagawa
发明人： Akio Yamaguchi , Yoji Hori , Susumu Akutagawa
IPC分类号： C07D321/08 , C08G63/08
CPC分类号： C07D321/08
摘要： An optically active 7-substituted-1,4-dioxepan-5-one derivative represented by the general formula (I): ##STR1## wherein R represents an alkyl group having from 1 to 5 carbon atoms; and * means an asymmetric carbon atom, is disclosed. An optically active polymer represented by formula (II): ##STR2## wherein R and * are as defined above; and n is an integer of 25 or more, obtained by ring opening polymerization of the optically active 7-substituted-1,4-dioxepan-5-one derivative represented by formula (I) is also disclosed. A process for producing the optically active polymer represented by formula (II) is further disclosed, comprising subjecting an optically active 7-substituted-1,4-dioxepan-5-one derivative represented by formula (I) to ring opening polymerization in the presence of at least one catalyst selected from the group consisting of (i) an organotin compound, (ii) an organoaluminum compound and water, and (iii) an organozinc compound and water.

4. 发明授权

US4886623A Ferroelectric smectic liquid crystal compound and composition containing the same 失效
标题翻译：铁电晶界液晶化合物和含有它们的组合物
公开(公告)号：US4886623A
公开(公告)日：1989-12-12
申请号：US137281
申请日：1987-12-23
申请人： Shigeru Mitsuhashi , Hitoshi Kondo , Tetsuharu Okazaki , Shinji Endoh , Hiroko Kudo , Akio Yamaguchi , Haruki Tsuruta , Susumu Akutagawa
发明人： Shigeru Mitsuhashi , Hitoshi Kondo , Tetsuharu Okazaki , Shinji Endoh , Hiroko Kudo , Akio Yamaguchi , Haruki Tsuruta , Susumu Akutagawa
IPC分类号： C07C69/92 , C07C69/773 , C07C69/94 , C09K19/20 , C09K19/22 , C09K19/46
CPC分类号： C09K19/2021
摘要： A liquid crystal compound represented by formula: ##STR1## wherein R.sub.1 represents a straight chain alkyl group having from 4 to 18 carbon atoms; R.sub.2 represents a straight chain alkyl group having from 2 to 6 carbon atoms or a branched alkyl group having from 3 to 6 atoms and having a methyl group as a side chain; and m and n each represents 1 or 2, is disclosed.The liquid crystal compound of formula (I) is optically and electrically stable and exhibits fast electro-optical switching in image display.
摘要翻译：由下式表示的液晶化合物：其中R 1表示具有4至18个碳原子的直链烷基; R2表示具有2-6个碳原子的直链烷基或具有3至6个原子并具有甲基作为侧链的支链烷基; 并且m和n各自表示1或2。式（I）的液晶化合物在光学和电学上是稳定的，并且在图像显示中表现出快速的电光切换。

5. 发明授权

US5049308A Ferroelectric smectic liquid crystal compound and composition containing the same 失效
标题翻译：铁电晶界液晶化合物和含有它们的组合物
公开(公告)号：US5049308A
公开(公告)日：1991-09-17
申请号：US372582
申请日：1989-06-27
申请人： Shigeru Mitsuhashi , Hitoshi Kondo , Tetsuharu Okazaki , Shinji Endoh , Hiroko Kudo , Akio Yamaguchi , Haruki Tsuruta , Susumu Akutagawa
发明人： Shigeru Mitsuhashi , Hitoshi Kondo , Tetsuharu Okazaki , Shinji Endoh , Hiroko Kudo , Akio Yamaguchi , Haruki Tsuruta , Susumu Akutagawa
IPC分类号： C07C69/92 , C07C69/773 , C07C69/94 , C09K19/20 , C09K19/22 , C09K19/46
CPC分类号： C09K19/2021
摘要： A liquid crystal compound represented by formula: ##STR1## wherein R.sub.1 represents a straight chain alkyl group having from 4 to 18 carbon atoms; R.sub.2 represents a straight chain alkyl group having from 2 to 6 carbon atoms or a branched alkyl group having from 3 to 6 atoms and having a methyl group as a side chain; and m and n each represents 1 or 2, is disclosed.The liquid crystal compound of formula (I) is optically and electrically stable and exhibits fast electro-optical switching in image display.

6. 发明授权

US4962242A Process for producing optically active alcohols 失效
标题翻译：光学活性醇的制造方法
公开(公告)号：US4962242A
公开(公告)日：1990-10-09
申请号：US66164
申请日：1987-06-25
申请人： Nobuo Yamada , Toshiyuki Takezawa , Noboru Sayo , Misao Yagi , Hidenori Kumobayashi , Susumu Akutagawa , Hidemasa Takaya , Shinichi Inoue , Ryoji Noyori
发明人： Nobuo Yamada , Toshiyuki Takezawa , Noboru Sayo , Misao Yagi , Hidenori Kumobayashi , Susumu Akutagawa , Hidemasa Takaya , Shinichi Inoue , Ryoji Noyori
IPC分类号： C07C29/17
CPC分类号： C07C29/172 , C07B2200/07
摘要： A process for producing an optically active alcohol represented by formula (I): ##STR1## wherein R.sub.1 is an alkyl group having from 2 to 11 carbon atoms, an alkenyl group having from 3 to 11 carbon atoms, an alkadienyl group having from 6 to 11 carbon atoms, a cyclohexyl group, an cyclohexylmethyl group, or a cyclohexylethyl group, provided that the olefin in the alkenyl group or alkadienyl group is not conjugated to the olefin at the 2-position thereof; and * means an asymmetric carbon atom,is disclosed, comprising subjecting an olefinic alcohol represented by formula (II): ##STR2## wherein R.sub.1 is the same as defined above to asymmetric hydrogenation in the presence of, as a catalyst, a ruthenium-optically active phosphine complex.According to the process of the invention, the desired optically active alcohols which are useful not only as intermediates for the manufacture of perfumes and vitamin E but also as liquid crystal materials can be produced with high optical purities.
摘要翻译：一种制备由式（I）表示的光学活性醇的方法：其中R1是具有2至11个碳原子的烷基，具有3至11个碳原子的链烯基，具有环己基，环己基甲基或环己基乙基，条件是烯基或链二烯基中的烯烃在2-位没有与烯烃共轭; 和*表示不对称碳原子，包括使式（II）表示的烯属醇：其中R 1与上述定义相同，在作为催化剂的存在下进行不对称氢化钌 - 光学活性膦配合物。根据本发明的方法，不仅可用于制造香料和维生素E，而且用作液晶材料的中间体所需的光学活性醇可以以高光学纯度生产。

7. 发明授权

US4764629A Ruthenium-phosphine complex 失效
标题翻译：钌膦络合物
公开(公告)号：US4764629A
公开(公告)日：1988-08-16
申请号：US125280
申请日：1987-11-25
申请人： Noboru Sayo , Takanao Taketomi , Hidenori Kumobayashi , Susumu Akutagawa
发明人： Noboru Sayo , Takanao Taketomi , Hidenori Kumobayashi , Susumu Akutagawa
IPC分类号： B01J31/24 , B01J31/00 , C07B61/00 , C07F15/00
CPC分类号： C07F15/0053
摘要： A ruthenium-phosphine complex represented by formula (I): ##STR1## wherein R represents a hydrogen atom, a methyl group, or a methoxy group; S represents a tertiary amine; when y is 0, then x is 2, z is 4, and p is 1; and when y is 1, then x is 1, z is 1, and p is 0. The complex is inexpensive and exhibits excellent performance as a catalyst for various organic syntheses, and particularly asymmetric hydrogenation.
摘要翻译：由式（I）表示的钌膦络合物：其中R表示氢原子，甲基或甲氧基; S表示叔胺; 当y为0时，x为2，z为4，p为1; 当y为1时，x为1，z为1，p为0.该复合物价格便宜，作为各种有机合成催化剂，特别是不对称氢化，表现出优异的性能。

8. 发明授权

US3984355A 1,2,6-Trimethyltricyclo[5,3,2,0.sup.2,7 ]dodeca-5-one perfume composition 失效
标题翻译： 1,2,6-三甲基三环{8,5,3,2,0 {hu 2,7 {b {9 dodeca-5-one perfume composition
公开(公告)号：US3984355A
公开(公告)日：1976-10-05
申请号：US631543
申请日：1975-11-13
申请人： Akira Nagakura , Susumu Akutagawa , Haruki Kurihara
发明人： Akira Nagakura , Susumu Akutagawa , Haruki Kurihara
IPC分类号： C07C49/453 , C11B9/00
CPC分类号： C07C49/453 , C11B9/0042
摘要： 1,2,6-Trimethyltricyclo[5,3,2,0.sup.2,7 ]dodeca-5-one having the formula (I) ##SPC1##and a process for producing this compound. This compound is useful as a perfume.
摘要翻译：具有式（I）的1,2,6-三甲基三环[5,3,2,02,7]十二碳-5-酮及其制备方法。该化合物可用作香料。

9. 发明授权

US3963782A 5-Acetyl-1,2,6-trimethyltricyclo[5,3,2,0.sup.2,7 ]dodeca-5-ene 失效
标题翻译： 5-乙酰基-1,2,6-三甲基三环{8,5,3,2,0 {hu 2,7 {b {9 dodeca-5-ene
公开(公告)号：US3963782A
公开(公告)日：1976-06-15
申请号：US537002
申请日：1974-12-27
申请人： Akira Nagakura , Susumu Akutagawa , Haruki Kurihara
发明人： Akira Nagakura , Susumu Akutagawa , Haruki Kurihara
IPC分类号： A61K8/35 , A61Q13/00 , C07C5/31 , C07C45/00 , C07C49/553 , C07C67/00 , C11B9/00 , C07C49/61
CPC分类号： C11B9/0042 , C07C49/553 , C07C5/31
摘要： 5-Acetyl-1,2,6-trimethyltricyclo[5,3,2,0.sup.2,7 ]dodeca-5-ene having the formula (I) v,2/14And a process for producing this compound. This compound is useful as a perfume.
摘要翻译：具有式（I）v，2/14的5-乙酰基-1,2,6-三甲基三环[5,3,2,02,7]十二碳-5-烯和其制备本化合物的方法。该化合物可用作香料。

10. 发明授权

US3962340A 1,2,6-Trimethyltricyclo[5,3,2,0.sup.2,7 ]dodeca-5-one 失效
标题翻译： 1,2,6-三甲基三环{8,5,3,2,0 {hu 2,7 {b {9 dodeca-5-one
公开(公告)号：US3962340A
公开(公告)日：1976-06-08
申请号：US537005
申请日：1974-12-27
申请人： Akira Nagakura , Susumu Akutagawa , Haruki Kurihara
发明人： Akira Nagakura , Susumu Akutagawa , Haruki Kurihara
IPC分类号： A61K8/35 , A61Q13/00 , C07C5/31 , C07C45/00 , C07C49/453 , C07C67/00 , C11B9/00 , C07C49/36
CPC分类号： C11B9/0042 , C07C49/453 , C07C5/31
摘要： 1,2,6-Trimethyltricyclo[5,3,2,0.sup.2,7 ]dodeca-5-one having the formula (I) ##SPC1##and a process for producing this compound. This compound is useful as a perfume.
摘要翻译：具有式（I）的1,2,6-三甲基三环[5,3,2,02,7]十二碳-5-酮及其制备方法。该化合物可用作香料。

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