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1. 发明申请

US20080306306A1 Method for Producing 2-Adamantanol and 2-Adamantanone 审中-公开
标题翻译：生产2-金刚烷醇和2-金刚烷酮的方法
公开(公告)号：US20080306306A1
公开(公告)日：2008-12-11
申请号：US11571800
申请日：2005-06-30
申请人： Akio Kojima , Hideki Yamane , Kenji Okamoto
发明人： Akio Kojima , Hideki Yamane , Kenji Okamoto
IPC分类号： C07C45/27
CPC分类号： C07C49/453 , C07C29/56 , C07C2603/74 , C07C35/37
摘要： The present invention is a process for producing 2-adamantanol and 2-adamantanone from 1-adamantanol, by using as a catalyst a substance comprising at least one kind of acid catalyst selected from Lewis acid(s) and solid acid(s) that coexist with at least one kind selected from the group consisting of carboxylic acids, sulfonic acids, and phosphoric acids, and provides a process suitable for mass production of 2-adamantanol and 2-adamantanone selectively with high efficiency without using sulfuric acid as a catalyst, thereby enabling laborsaving in waste acid treatment step and drastic reduction of the reaction time.
摘要翻译：本发明是一种由1-金刚烷生产2-金刚烷醇和2-金刚烷酮的方法，其通过使用选自共存的至少一种选自路易斯酸和固体酸的至少一种酸催化剂作为催化剂，具有选自羧酸，磺酸和磷酸的至少一种，并且提供了适合于高效率地选择性地大规模生产2-金刚烷酮和2-金刚烷酮的方法，而不用硫酸作催化剂。在废酸处理步骤中实现劳动，并大大减少反应时间。

2. 发明申请

US20100056663A1 ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, AND RESIN COMPOSITION CONTAINING ADAMANTANE DERIVATIVE 有权
标题翻译：亚胺衍生物，其制备方法和含有衍生物的树脂组合物
公开(公告)号：US20100056663A1
公开(公告)日：2010-03-04
申请号：US12516102
申请日：2007-11-21
申请人： Katsuki Ito , Yasunari Okada , Hideki Yamane , Akio Kojima
发明人： Katsuki Ito , Yasunari Okada , Hideki Yamane , Akio Kojima
IPC分类号： C08F2/46 , C07C39/04 , C07D303/02 , C08G65/08 , C07C69/52
CPC分类号： C08F20/30 , C07C39/17 , C07C67/26 , C07C2603/74 , C07D303/30 , C08G59/3218 , H05K3/287 , C07C69/54
摘要： The present invention is an adamantane derivative which provides optical characteristics such as transparency, (long term) light resistance and the like, long term heat resistance, electric characteristics such as dielectric constant and the like, and good mechanical properties; a production method thereof; and a resin composition containing the above-mentioned adamantane derivative that is an adamantane derivative represented by general formulae (I) to (III); for example, a production method of an adamantane derivative represented by the general formula (III) by reacting an adamantane derivative represented by the general formula (II) with acrylates, a resin composition containing an adamantane derivative represented by the general formula (II) and an epoxy resin curing agent, and a resin composition containing an adamantane derivative represented by the general formula (III) and a thermopolymerization initiator or a photopolymerization initiator.In the formula, R1 represents CnH2n+1 (n is an integer of 1 to 10); R2 represents H, CH3, F or CF3; j is an integer of 1 to 4; k is an integer of 0 to 3; m is an integer of 2 to 5; and j+k+m≦6.
摘要翻译：本发明是提供透明性，长期耐光性等长期耐热性，介电常数等电特性等良好的机械特性的光学特性的金刚烷衍生物。其制造方法; 和含有上述通式（I）〜（III）所示的金刚烷衍生物的金刚烷衍生物的树脂组合物; 例如通过使通式（II）表示的金刚烷衍生物与丙烯酸酯反应的通式（III）表示的金刚烷衍生物的制造方法，含有通式（II）表示的金刚烷衍生物的树脂组合物和环氧树脂固化剂和含有由通式（III）表示的金刚烷衍生物和热聚合引发剂或光聚合引发剂的树脂组合物。在该式中，R 1表示C n H 2n + 1（n为1〜10的整数）。 R2代表H，CH3，F或CF3; j为1〜4的整数， k为0〜3的整数， m为2〜5的整数，和j + k + m＆nlE; 6。

3. 发明授权

US08110614B2 Adamantane derivative, method for producing the same, and resin composition containing adamantane derivative 有权
标题翻译：金刚烷衍生物，其制造方法和含有金刚烷衍生物的树脂组合物
公开(公告)号：US08110614B2
公开(公告)日：2012-02-07
申请号：US12516102
申请日：2007-11-21
申请人： Katsuki Ito , Yasunari Okada , Hideki Yamane , Akio Kojima
发明人： Katsuki Ito , Yasunari Okada , Hideki Yamane , Akio Kojima
IPC分类号： C08F2/46 , C08F20/10 , C07C39/04 , C07C69/52 , C07D303/00 , C07D301/27 , C08G65/08
CPC分类号： C08F20/30 , C07C39/17 , C07C67/26 , C07C2603/74 , C07D303/30 , C08G59/3218 , H05K3/287 , C07C69/54
摘要： Adamantane derivatives are provided including a phenolic hydroxyl group-containing adamantane derivative, a glycidyloxy group-containing adamantane derivative, and an adamantyl group-containing epoxy modified acrylate, which exhibit excellent transparency, light resistance, and heat resistance properties. Also provided are resin compositions containing the adamantane derivatives. Further provided are corresponding methods for producing the adamantane derivatives, as well as the resin compositions containing the same.
摘要翻译：提供了金刚烷衍生物，其包括含有酚羟基的金刚烷衍生物，含缩水甘油氧基的金刚烷衍生物和含金刚烷基的环氧改性丙烯酸酯，其表现出优异的透明性，耐光性和耐热性。还提供含有金刚烷衍生物的树脂组合物。还提供了用于制备金刚烷衍生物的相应方法，以及含有该金刚烷衍生物的树脂组合物。

4. 发明授权

US08163849B2 Process of producing polylactic acid 失效
标题翻译：生产聚乳酸的方法
公开(公告)号：US08163849B2
公开(公告)日：2012-04-24
申请号：US12526456
申请日：2008-02-06
申请人： Kiyotsuna Toyohara , Midori Ikegame , Hideki Yamane , Yoshiharu Kimura , Daisuke Masaki , Shin To
发明人： Kiyotsuna Toyohara , Midori Ikegame , Hideki Yamane , Yoshiharu Kimura , Daisuke Masaki , Shin To
IPC分类号： C08G63/91
CPC分类号： D01F6/625 , C08G63/08 , C08G63/88 , C08G63/912 , C08J3/005 , C08J2367/04 , D01F6/92
摘要： It is an object of the present invention to produce a polylactic acid having a high molecular weight such as a weight average molecular weight (Mw) of more than 100,000 from which only a stereocomplex crystal is grown even by repeating melting and crystallization. The present invention is a process of producing a polylactic acid, including the steps of: (i) obtaining a solid by kneading together poly(L-lactic acid) and poly(D-lactic acid) at a temperature of 160 to 225° C. and crystallizing the kneaded product; and (ii) melt kneading the obtained solid.
摘要翻译：本发明的目的是制备具有高分子量的重均分子量（Mw）超过100,000的聚乳酸，即使通过重复熔融和结晶也仅生长立体络合物晶体。本发明是一种制备聚乳酸的方法，包括以下步骤：（i）通过在160-225℃的温度下将聚（L-乳酸）和聚（D-乳酸）捏合在一起获得固体并使捏合产物结晶; 和（ii）熔融捏合所得固体。

5. 发明申请

US20100266954A1 ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, AND CURING COMPOSITION CONTAINING ADAMANTANE DERIVATIVE 审中-公开
标题翻译：衍生物，其制备方法和含有ADAMANTANE衍生物的固化组合物
公开(公告)号：US20100266954A1
公开(公告)日：2010-10-21
申请号：US12742379
申请日：2008-11-10
申请人： Katsuki Ito , Shinji Tanaka , Naoya Kawano , Hideki Yamane , Hidetoshi Ono
发明人： Katsuki Ito , Shinji Tanaka , Naoya Kawano , Hideki Yamane , Hidetoshi Ono
IPC分类号： G03F7/004 , G03F7/20 , C07C69/608 , C08F20/10
CPC分类号： C07C69/54 , C07C2603/74 , C08F220/18 , C08F220/28 , G03F7/027 , G03F7/0397
摘要： An adamantane derivative capable of affording a cured product which is excellent in optical characteristics such as transparency and light resistance, durability such as long-term heat resistance, and electrical characteristics such as dielectric constant, a process for producing such an adamantane derivative, and a curable composition containing such an adamantane derivative, the adamantane derivative being represented by the general formula (I) shown below and having a group selected from an acrylate group, a methacrylate group and a trifluoromethacrylate group, where R1 represents a group selected from a hydroxyl group, an acrylate group, a methacrylate group and a trifluoromethacrylate group, R2 represents a group selected from a hydrogen atom, a methyl group and a trifluoromethyl group, k is an integer of 0 to 4 and n is an integer of 1 to 6.
摘要翻译：能够提供透明性，耐光性等光学特性，长期耐热性等耐久性，介电常数等电气特性，制造金刚烷衍生物的方法等的固化物的金刚烷衍生物，以及含有这种金刚烷衍生物的固化性组合物，金刚烷衍生物由下述通式（I）表示，具有选自丙烯酸酯基，甲基丙烯酸酯基和三氟甲基丙烯酸酯基的基团，其中R 1表示选自羟基的基团丙烯酸酯基，甲基丙烯酸酯基和三氟甲基丙烯酸酯基，R 2表示选自氢原子，甲基和三氟甲基的基团，k为0〜4的整数，n为1〜6的整数。

6. 发明授权

US07790917B2 Adamantyl group-containing epoxy-modified (meth)acrylate and resin composition containing the same 有权
标题翻译：含有金刚烷基的环氧改性（甲基）丙烯酸酯和含有其的树脂组合物
公开(公告)号：US07790917B2
公开(公告)日：2010-09-07
申请号：US12298260
申请日：2007-04-24
申请人： Yasunari Okada , Hajime Ito , Hideki Yamane , Nobuaki Matsumoto
发明人： Yasunari Okada , Hajime Ito , Hideki Yamane , Nobuaki Matsumoto
IPC分类号： C07C69/34 , C08D303/12
CPC分类号： C08F290/06 , C08F222/1006 , C08F290/061 , C08F290/064 , C08G59/186
摘要： The present invention provides an adamantyl group containing epoxy-modified (meth)acrylate and a resin composition containing it which are imparted by transparency, optical characteristics such as (durable) light resistance and the like, heat-resistance, and good mechanical properties.For example, they are an adamantyl group containing epoxy-modified (meth)acrylate having the following general formula (I) and a composition containing it. In the formula, R1 represents a hydrogen atom or a methyl group, and R2 represents a halogen atom or an aliphatic hydrocarbon group which may contain a hetero atom. Plural R2 may be the same or different, and m represents an integer of 0 to 4 and n represents an integer of 0 or more.
摘要翻译：本发明提供含有环氧改性（甲基）丙烯酸金刚烷基和含有它的树脂组合物，它们由透明性，耐光性等光学特性赋予耐热性和良好的机械性能。例如，它们是含有具有以下通式（I）的环氧改性（甲基）丙烯酸酯和含有它的组合物的金刚烷基。在该式中，R 1表示氢原子或甲基，R 2表示卤素原子或可含有杂原子的脂肪族烃基。多个R2可以相同或不同，m表示0〜4的整数，n表示0以上的整数。

7. 发明授权

US07718580B2 Internal-olefin composition and base oil comprising the composition for oil drilling 有权
标题翻译：内烯烃组合物和基油，其包含用于石油钻井的组合物
公开(公告)号：US07718580B2
公开(公告)日：2010-05-18
申请号：US11574558
申请日：2005-09-02
申请人： Tetsuya Saruwatari , Nobuo Fujikawa , Hideki Yamane
发明人： Tetsuya Saruwatari , Nobuo Fujikawa , Hideki Yamane
IPC分类号： C09K8/02
CPC分类号： C09K8/34 , C09K8/32 , C10M105/04 , C10M2203/0206 , C10N2220/026 , C10N2220/028 , C10N2220/10 , C10N2240/00 , C10N2270/00 , Y10S507/905
摘要： The present invention provides an internal olefin composition comprising a mixture of 60 to 80% by mass of an olefin having 16 carbon atoms and 40 to 20% by mass of an olefin having 18 carbon atoms wherein a content of an α-olefin in the mixture is 10% by mass or less, and a content of a branched olefin in the mixture is 10% by mass or less, which has a good biodegradability even when discharged into the environments, a less toxicity against marine organisms, etc., and a sufficient fluidity when used as a base oil for oil drilling, etc.
摘要翻译：本发明提供含有60〜80质量％的碳原子数为16〜80的烯烃和40〜20质量％的碳原子数为18的烯烃的混合物的内部烯烃组合物，其中混合物中的α-烯烃的含量为10质量％以下，混合物中的支链烯烃的含量为10质量％以下，即使排放到环境中也具有良好的生物降解性，对海洋生物等的毒性小，用作石油钻井等基础油时的充分流动性

8. 发明申请

US20070270315A1 Internal-Olefin Composition and Base Oil Comprising the Composition for Oil Drilling 有权
标题翻译：内部烯烃组合物和基础油，包括用于钻井的组合物
公开(公告)号：US20070270315A1
公开(公告)日：2007-11-22
申请号：US11574558
申请日：2005-09-02
申请人： Tetsuya Saruwatari , Nobuo Fujikawa , Hideki Yamane
发明人： Tetsuya Saruwatari , Nobuo Fujikawa , Hideki Yamane
IPC分类号： C09K8/32
CPC分类号： C09K8/34 , C09K8/32 , C10M105/04 , C10M2203/0206 , C10N2220/026 , C10N2220/028 , C10N2220/10 , C10N2240/00 , C10N2270/00 , Y10S507/905
摘要： The present invention provides an internal olefin composition comprising a mixture of 60 to 80% by mass of an olefin having 16 carbon atoms and 40 to 20% by mass of an olefin having 18 carbon atoms wherein a content of an α-olefin in the mixture is 10% by mass or less, and a content of a branched olefin in the mixture is 10% by mass or less, which has a good biodegradability even when discharged into the environments, a less toxicity against marine organisms, etc., and a sufficient fluidity when used as a base oil for oil drilling, etc.
摘要翻译：本发明提供了含有60〜80质量％的碳原子数为16〜80的烯烃和40〜20质量％的碳原子数为18的烯烃的混合物的内部烯烃组合物，其中，所述混合物中的α-烯烃的含量为10质量％以下，混合物中的支链烯烃的含量为10质量％以下，即使排放到环境中也具有良好的生物降解性，对海洋生物等的毒性小，用作石油钻井等基础油时的充分流动性

9. 发明授权

US08945453B2 Method for producing polytetrafluoroethylene fiber and polytetrafluoroethylene fiber 有权
标题翻译：生产聚四氟乙烯纤维和聚四氟乙烯纤维的方法
公开(公告)号：US08945453B2
公开(公告)日：2015-02-03
申请号：US12665231
申请日：2008-06-16
申请人： Daisuke Kitagawa , Takashi Wano , Hideki Yamane , Yoshihito Takagi
发明人： Daisuke Kitagawa , Takashi Wano , Hideki Yamane , Yoshihito Takagi
IPC分类号： D01F6/12 , D01D5/12
CPC分类号： D01F6/12 , D01D5/08 , D01D5/12 , Y10T428/298
摘要： The present invention provides a method for producing a PTFE fiber that makes it possible, unlike the emulsion spinning process, to obtain a polytetrafluoroethylene (PTFE) fiber, particularly a long PTFE fiber, without using a matrix material, is more productive than conventional production methods such as a slit yarn process, and is capable of enhancing mechanical properties and the degree of freedom in diameter of the obtained fiber. The method for producing the PTFE fiber of the present invention includes the step of reducing a diameter of a string-shape PTFE-containing solid material (a first solid material) by drawing the first solid material at a temperature equal to or higher than a melting point of PTFE. The first solid material can be obtained from a PTFE-containing solid material (a second solid material) containing water and a surfactant, by reducing an amount of the water contained in the second solid material.
摘要翻译：本发明提供了一种PTFE纤维的制造方法，与乳液纺丝法不同，不需要使用基质材料即可获得聚四氟乙烯（PTFE）纤维，特别是长的PTFE纤维，与以往的制造方法相比，例如狭缝纱工艺，并且能够提高所获得的纤维的机械性能和直径的自由度。本发明的PTFE纤维的制造方法包括通过在等于或高于熔融的温度下拉伸第一固体材料来降低线状含PTFE固体材料（第一固体材料）的直径的步骤 PTFE点。通过减少第二固体材料中所含的水量，可以从含有水和表面活性剂的含PTFE固体材料（第二固体材料）获得第一固体材料。

10. 发明申请

US20110190555A1 METHOD FOR PRODUCING INTERNAL OLEFIN, INTERNAL OLEFIN MIXTURE, AND OIL DRILLING FLUID CONTAINING INTERNAL OLEFIN MIXTURE 审中-公开
标题翻译：用于生产内部烯烃的方法，内部烯烃混合物和含有内部烯烃混合物的油钻井液
公开(公告)号：US20110190555A1
公开(公告)日：2011-08-04
申请号：US13086538
申请日：2011-04-14
申请人： Tetsuya SARUWATARI , Hideki Yamane
发明人： Tetsuya SARUWATARI , Hideki Yamane
IPC分类号： C10L1/04 , C07C5/25
CPC分类号： C09K8/34 , C07C5/2518 , C07C11/02
摘要： A method for producing an internal olefin by stably isomerizing an α-olefin by using an inexpensive zeolite catalyst while preventing an oligomerization reaction is provided. The method for producing an internal olefin comprises a step of isomerizing an α-olefin having from 16 to 18 carbon atoms by passing through a zeolite catalyst bed, wherein the α-olefin having from 16 to 18 carbon atoms is circulated through and brought into contact with the zeolite catalyst bed before starting the isomerization reaction.
摘要翻译：提供通过使用便宜的沸石催化剂稳定异构化α-烯烃来制备内烯烃的方法，同时防止低聚反应。内烯烃的制造方法包括使通过沸石催化剂床异构化具有16〜18个碳原子的α-烯烃的步骤，其中具有16至18个碳原子的α-烯烃循环通过并接触在开始异构化反应之前用沸石催化剂床。

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