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    • 6. 发明授权
    • Aryl styrene-based copolymer
    • 芳基苯乙烯基共聚物
    • US5403908A
    • 1995-04-04
    • US56588
    • 1993-04-30
    • Masami WatanabeShuji MachidaSatoshi Asahi
    • Masami WatanabeShuji MachidaSatoshi Asahi
    • C08F12/04C08F212/32
    • C08F12/04C08F4/65912
    • The present invention provides an aryl styrene-based polymer of a degree of polymerization of at least 5 having recurring units represented by the general formula ##STR1## in the formula, R.sup.1 to R.sup.5 each denote a hydrogen atom, halogen atom or substituent group containing at least either one kind of a carbon atom, oxygen atom, nitrogen atom, sulfur atom, phosphorus atom, selenium atom, silicon atom and tin atom and at least one of the R.sup.1 to R.sup.5 denotes an aryl group having a hydrogen atom, aryl group having a halogen atom or aryl group having a substituent group containing at least either one kind of a carbon atom, oxygen atom, nitrogen atom, sulfur atom, phosphorus atom, selenium atom, silicon atom and tin atom, of which the stereospecificity is a mainly syndiotactic configuration and a method for the preparation thereof as well as a styrene-based copolymer and a method for the preparation thereof.The aryl styrene-based copolymer of the-present invention has a high syndiotacticity and is excellent in the heat resistance, resistance against chemicals and electric properties.Further, the styrene-based copolymer of the present invention has a high syndiotacticity and, in addition, has a wide temperature range suitable for melt molding or is excellent in the heat resistance.Accordingly, the present invention can be effectively utilized as heat-resistant resins, base materials of films and the like.
    • 本发明提供一种聚合度至少为5的芳族苯乙烯基聚合物,其具有式中通式(I)[I]表示的重复单元,R1至R5各自表示氢原子,卤原子或取代基 含有至少一种碳原子,氧原子,氮原子,硫原子,磷原子,硒原子,硅原子和锡原子的基团,并且R 1至R 5中的至少一个表示具有氢原子的芳基, 具有卤素原子的芳基或具有至少含有碳原子,氧原子,氮原子,硫原子,磷原子,硒原子,硅原子和锡原子中的一种的取代基的芳基,立体定向性为 主要是间同立构构型及其制备方法以及苯乙烯基共聚物及其制备方法。 本发明的芳基苯乙烯类共聚物具有高的间同立构规整性,耐热性,耐化学性和电性能优异。 此外,本发明的苯乙烯系共聚物具有高的间同立构规整度,另外,具有适合于熔融成型的宽温度范围或耐热性优异。 因此,本发明可以有效地用作耐热树脂,膜的基材等。
    • 8. 发明授权
    • Catalyst and process for stereospecific polymerization of .alpha.-olefins
    • 催化剂和α-烯烃的立体有择聚合方法
    • US4482686A
    • 1984-11-13
    • US538352
    • 1983-10-03
    • Satoshi AsahiShigeo MoriYasuhiro Takeshita
    • Satoshi AsahiShigeo MoriYasuhiro Takeshita
    • C08F4/64C08F4/60C08F10/00C08F36/06C08F4/02C08F10/06
    • C08F10/00C08F36/06
    • A process for the stereospecific polymerization of .alpha.-olefins which comprises polymerizing an .alpha.-olefin with a catalyst comprising (A) the reaction product of a magnesium compound and a titanium compound and (B) an organo-aluminum compound. Component (A) is prepared by reacting a (i) magnesium compound of the formula Mg(OR.sup.1).sub.n X.sup.1.sub.2-n wherein R.sup.1 contains from 1 to 10 carbon atoms and is an alkyl group, a cycloalkyl group, an aryl group, or an aralkyl group, X.sup.1 is a halogen atom, and n is a real number of from 1.0 to 2.0, with (ii) at least one halogen-containing compound selected from the group consisting of halogenated hydrocarbons, oxygen-containing halogenated hydrocarbons, halogenated thionyls, halogen-containing phosphorus compounds and halogen-containing nitrogen compounds, and (iii) an oxygen-containing titanium compound of the formula Ti(OR.sup.2).sub.4 wherein R.sup.2 contains from 1 to 10 carbon atoms and is an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group, (iv) in the presence or in the absence of an organic acid ester to produce a solid reaction product. Said solid reaction product is, as it is or after a pre-treatment with an organic acid ester, reacted with a halogen-containing tetravalent titanium compound of the formula Ti(OR.sup.3).sub.m X.sup.2.sub.4-m wherein R.sup.3 contains from 1 to 10 carbon atoms and is an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group, X.sup.2 is a halogen atom, and m is a real number of from 0 to 3.0, in the presence or in the absence of an organic acid ester, and always in the presence of an organic acid ester when an organic acid ester was not used in at least one of the preceding steps.
    • 一种α-烯烃的立体有择聚合方法,其包括用包含(A)镁化合物和钛化合物的反应产物和(B)有机铝化合物)的催化剂聚合α-烯烃的α-烯烃。 组分(A)通过使(ⅰ)式(ⅰ)镁(OR 1)n X 12-n的镁化合物(其中R 1含有1至10个碳原子)并且是烷基,环烷基,芳基或芳烷基 基团,X 1是卤素原子,n是1.0至2.0的实数,其中(ii)至少一种选自卤代烃,含氧卤代烃,卤代亚硫酰基,卤素的卤素化合物 的含磷化合物和含卤素的氮化合物,和(iii)式Ti(OR2)4的含氧钛化合物,其中R 2含有1至10个碳原子并且是烷基,环烷基,芳基 基团或芳烷基,(iv)在存在或不存在有机酸酯的情况下产生固体反应产物。 所述固体反应产物原样或经有机酸酯预处理后与式Ti(OR 3)m X 24-m的卤素四价钛化合物反应,其中R 3含有1至10个碳原子,和 是烷基,环烷基,芳基或芳烷基,X2是卤素原子,m是0-3.0的实数,在存在或不存在有机酸酯的情况下,总是 当在上述至少一个步骤中未使用有机酸酯时,在有机酸酯存在下进行。