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1. 发明授权

US4260179A Color-developing sheet for pressure-sensitive recording sheets 失效
标题翻译：压敏记录纸的显色片
公开(公告)号：US4260179A
公开(公告)日：1981-04-07
申请号：US068581
申请日：1979-08-22
申请人： Akihiro Yamaguchi , Tadashi Kobayashi , Keizaburo Yamaguchi , Kisuke Osawa , Hisamichi Murakami , Noboru Yamato , Akira Hasegawa
发明人： Akihiro Yamaguchi , Tadashi Kobayashi , Keizaburo Yamaguchi , Kisuke Osawa , Hisamichi Murakami , Noboru Yamato , Akira Hasegawa
IPC分类号： B41M5/00 , C07F3/00 , B41M5/16 , B41M5/22
CPC分类号： C07C317/00 , C07F3/003 , Y10S428/914 , Y10T428/273 , Y10T428/277
摘要： A color-developing sheet for pressure-sensitive recording sheets, said sheet comprising as a color-developing agent at least one 2,2'-bisphenolsulfone zinc salt selected from compounds of the general formula ##STR1## wherein R.sub.1 and R.sub.2 are identical or different, and represent a hydrogen atom, a halogen atom, an alkyl group containing 1 to 10 carbon atoms, a cycloalkyl group containing 3 to 10 carbon atoms, an aralkyl group containing 7 to 11 carbon atoms, or a phenyl group.
摘要翻译：一种用于压敏记录片材的显色片材，所述片材包含作为显色剂的至少一种选自通式（I）的化合物（I）的2,2'-双酚砜锌盐，其中R1和R2是代表氢原子，卤素原子，含1-10个碳原子的烷基，含3-10个碳原子的环烷基，含有7至11个碳原子的芳烷基或苯基。

2. 发明授权

US4275240A Process for the preparation of 2,2'-bisphenol sulfoxides 失效
标题翻译：制备2,2'-双酚亚砜的方法
公开(公告)号：US4275240A
公开(公告)日：1981-06-23
申请号：US126980
申请日：1980-03-03
申请人： Akihiro Yamaguchi , Keizaburo Yamaguchi , Hisamichi Murakami , Tadashi Kobayashi
发明人： Akihiro Yamaguchi , Keizaburo Yamaguchi , Hisamichi Murakami , Tadashi Kobayashi
IPC分类号： C07C317/00
CPC分类号： C07C317/00
摘要： 2,2'-Bisphenol sulfoxides are prepared by oxidizing 2,2'-bisphenol sulfides with hydrogen peroxide in the presence of such an organic solvent as not to form any organic peracids under reaction conditions.
摘要翻译： 2,2'-双酚亚砜通过在这种有机溶剂的存在下用过氧化氢氧化2,2'-双酚硫化物制备，在反应条件下不形成任何有机过酸。

3. 发明授权

US4287366A Process for preparing bisphenol sulfone derivatives 失效
标题翻译：制备双酚砜衍生物的方法
公开(公告)号：US4287366A
公开(公告)日：1981-09-01
申请号：US128712
申请日：1980-03-10
申请人： Akihiro Yamaguchi , Keizaburo Yamaguchi , Hisamichi Murakami , Tadashi Kobayashi
发明人： Akihiro Yamaguchi , Keizaburo Yamaguchi , Hisamichi Murakami , Tadashi Kobayashi
IPC分类号： C07C315/02 , C07C317/22 , C07C147/10
CPC分类号： C07C315/02
摘要： A process for preparing bisphenol sulfone derivatives represented by the general formula (I) ##STR1## where R stands for hydrogen, a halogen, an alkyl radical, a cycloalkyl radical, an aryl radical, an aralkyl radical, hydroxyl group, an alkoxy radical, allyloxy group, carboxyl group, or a carboalkoxy radical, m is an integer of from 1 to 3, and when m is 2 or more, R may be identical to or different from each other, and adjacent Rs may be combined to form a ring, by oxidizing with hydrogen peroxide a compound represented by the general formula (II) ##STR2## where R and m have the same meanings as defined for the formula (I), and n is zero or 1, in the presence of an alkali in an amount more than the equimolar amount thereof relative to said compound in water and/or an organic solvent which do not form any organic peracids under reaction conditions.
摘要翻译：一种制备由通式（I）表示的双酚砜衍生物的方法，其中R代表氢，卤素，烷基，环烷基，芳基，芳烷基，羟基，烷氧基，烯丙氧基，羧基或烷氧羰基，m为1〜3的整数，当m为2以上时，R可以相同也可以不同，相邻的Rs可以组合成形成环，通过用过氧化氢氧化由通式（II）表示的化合物（II）其中R和m具有与式（I）所定义相同的含义，并且n为0或1，在在水和/或在反应条件下不形成任何有机过酸的有机溶剂中，相对于所述化合物，碱的存在量超过等摩尔量。

4. 发明授权

US4380671A Process for the preparation of 2,2'-bis(4-substituted phenol)sulfides 失效
标题翻译：制备2,2'-双（4-取代苯酚）硫化物的方法
公开(公告)号：US4380671A
公开(公告)日：1983-04-19
申请号：US288428
申请日：1981-07-30
申请人： Akihiro Yamaguchi , Tadashi Kobayashi , Keizaburo Yamaguchi , Hisamichi Murakami
发明人： Akihiro Yamaguchi , Tadashi Kobayashi , Keizaburo Yamaguchi , Hisamichi Murakami
IPC分类号： C07C20060101 , C07C319/14 , C07C321/30 , C08K5/13 , C08K5/36 , C10M169/00 , C07C149/36
CPC分类号： C07C323/00
摘要： Disclosed is a process for the preparation of 2,2'-bis(4-substituted phenol)sulfides which comprises reacting a 4-substituted phenol with sulfur dichloride in a hydrocarbon solvent at a temperature of from -10.degree. to 40.degree. C. in the presence of a Lewis acid catalyst. For example, 2,2'-bis(4-cumylphenol)-sulfide, i.e. 2,2'-bis(4-.alpha.,.alpha.-dimethyl benzyl-phenol)monosulfide, which is a novel compound can be prepared by reacting 4-cumylphenol with sulfur dichloride in benzene at a temperature of from 0.degree.to 10.degree. C. in the presence of zinc chloride.
摘要翻译：公开了一种制备2,2'-双（4-取代苯酚）硫化物的方法，其包括使4-取代的苯酚与二氯化硫在烃溶剂中在-10℃至40℃的温度下反应存在路易斯酸催化剂。例如，作为新化合物的2,2'-双（4-枯基苯酚）硫化物，即2,2'-双（4-甲基-α，α-二甲基苄基 - 苯酚）单硫化物可以通过使4- 异丙苯酚与二氯化硫在苯中，在氯化锌存在下，在0〜10℃的温度下进行。

5. 发明授权

US4407892A Heat sensitive recording sheet 失效
标题翻译：热敏记录纸
公开(公告)号：US4407892A
公开(公告)日：1983-10-04
申请号：US400016
申请日：1982-07-20
申请人： Akihiro Yamaguchi , Keizaburo Yamaguchi , Hisamichi Murakami
发明人： Akihiro Yamaguchi , Keizaburo Yamaguchi , Hisamichi Murakami
IPC分类号： B41M5/333 , B41M5/337 , C09D11/00 , B41M5/18
CPC分类号： B41M5/3375 , B41M5/3336 , Y10S428/913 , Y10S428/914
摘要： Heat sensitive recording sheet having improved light resistance and water resistance. A developer contained therein is one or more specified metal salts of 2,2'-bisphenolsulfide, 2,2'-bisphenolsulfoxide and 2,2'-bisphenolsulfone compounds. The heat sensitive recording sheet can further contain a heat fusible material having a melting point of 50.degree. to 190.degree. C.
摘要翻译：具有改善的耐光性和耐水性的热敏记录纸。其中所含的显影剂是2,2'-双酚硫醚，2,2'-双酚亚砜和2,2'-双酚砜化合物的一种或多种特定的金属盐。热敏记录片材还可以含有熔点为50〜190℃的热熔材料。

6. 发明授权

US4312522A Heat sensitive recording sheet 失效
标题翻译：热敏记录纸
公开(公告)号：US4312522A
公开(公告)日：1982-01-26
申请号：US177999
申请日：1980-08-14
申请人： Akihiro Yamaguchi , Keizaburo Yamaguchi , Hisamichi Murakami
发明人： Akihiro Yamaguchi , Keizaburo Yamaguchi , Hisamichi Murakami
IPC分类号： B41M5/333 , B41M5/18 , B41M5/22
CPC分类号： B41M5/3336 , Y10S428/913 , Y10S428/914
摘要： This invention discloses a heat sensitive recording sheet which contains, as a developer, at least one of the compounds represented by the general formula ##STR1## where R represents hydrogen, an alkyl radical of from 1 to 12 carbon atoms, a cycloalkyl radical of from 3 to 10 carbon atoms, an aralkyl radical of from 7 to 10 carbon atoms, and a phenyl radical, and may be identical to or different from each other, n is zero, or an integer of 1 or 2.The heat sensitive recording sheet of this invention has a sharper rise in developed color density and is advantageous for its handling and storage as well as gives a developed color image having an excellent fastness to light and water resistance in addition to very little decrease in density of the developed color image with time.
摘要翻译：本发明公开了一种热敏记录片材，其包含作为显影剂的至少一种由通式“IMAGE”表示的化合物，其中R表示氢，1至12个碳原子的烷基， 3至10个碳原子，7至10个碳原子的芳烷基和苯基，并且可以彼此相同或不同，n为零或1或2的整数。热敏记录片材本发明的显色浓度明显提高，并且其处理和储存有利，并且除了显影的彩色图像的密度几乎没有降低之外，还提供了具有优异的耐光和耐水牢度的显影彩色图像时间。

7. 发明授权

US4248804A Process for the preparation of 2,2'-bis[4-(1,1,3,3-tetramethylbutyl)phenol]sulfide 失效
标题翻译：制备2,2'-双[4-（1,1,3,3-四甲基丁基）苯酚]硫化物的方法
公开(公告)号：US4248804A
公开(公告)日：1981-02-03
申请号：US70614
申请日：1979-08-29
申请人： Akihiro Yamaguchi , Tadashi Kobayashi , Keisaburo Yamaguchi , Hisamichi Murakami
发明人： Akihiro Yamaguchi , Tadashi Kobayashi , Keisaburo Yamaguchi , Hisamichi Murakami
IPC分类号： C07C319/14 , C07C321/30 , C07C149/36
CPC分类号： C07C323/00
摘要： 2,2'-bis[4-(1,1,3,3-tetramethylbutyl)phenol]sulfide is prepared by suspending 4-(1,1,3,3-tetramethylbutyl)phenol in an organic solvent, reacting it with sulfur dichloride or sulfur monochloride at a temperature of from -10.degree. to 40.degree. C., and isolating the precipitate so formed.
摘要翻译：通过将4-（1,1,3,3-四甲基丁基）苯酚在有机溶剂中悬浮，使其与硫反应制备2,2'-双[4-（1,1,3,3-四甲基丁基）苯酚]硫醚二氯化物或一氯化硫，在-10℃至40℃的温度下，分离形成的沉淀物。

8. 发明授权

US4262938A Color-developing sheet for pressure-sensitive recording sheets 失效
标题翻译：压敏记录纸的显色片
公开(公告)号：US4262938A
公开(公告)日：1981-04-21
申请号：US68580
申请日：1979-08-22
申请人： Akihiro Yamaguchi , Tadashi Kobayashi , Kenzaburo Yamuguchi , Hisamichi Murakami , Noboru Yamato , Akira Hasegawa
发明人： Akihiro Yamaguchi , Tadashi Kobayashi , Kenzaburo Yamuguchi , Hisamichi Murakami , Noboru Yamato , Akira Hasegawa
IPC分类号： B41M5/155 , C07C317/22 , C07F3/00 , C07F15/04 , B41M5/16 , B41M5/22
CPC分类号： B41M5/155 , C07C317/22 , C07F15/045 , C07F3/003 , Y10S428/914 , Y10T428/273 , Y10T428/277
摘要： A color-developing sheet for pressure-sensitive recording sheets, said sheet comprising as a color-developing agent at least one 2,2'-bisphenolsulfone nickel salt selected from compounds of the following formula ##STR1## wherein R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are identical or different, and represent a hydrogen atom, a halogen atom, an alkyl group containing 1 to 10 carbon atoms, a cycloalkyl group containing 3 to 10 carbon atoms, an aralkyl group containing 7 to 11 carbon atoms, or a phenyl group, or a mixture of at least one 2,2'-bisphenolsulfone nickel salt of the above formulae (II) and (III) and at least one 2,2'-bisphenolsulfone zinc salt of the following formula ##STR2## wherein R.sub.1 and R.sub.2 are the same as R.sub.3 through R.sub.8 defined above.
摘要翻译：一种用于压敏记录片的显色片，所述片包含作为显色剂的至少一种2,2'-双酚砜镍盐，其选自下式（II）和（iii）的化合物，其中 R 3，R 4，R 5，R 6，R 7和R 8相同或不同，表示氢原子，卤素原子，含有1〜10个碳原子的烷基，含有3〜10个碳原子的环烷基， 7至11个碳原子，或苯基，或上述式（II）和（III）的至少一种2,2'-双酚砜镍盐的混合物和至少一种2,2'-双酚砜锌盐下式（Ⅰ）其中R1和R2与上述定义的R3至R8相同。

9. 发明授权

US4338259A Alpha-halogeno-beta-aminopropionitriles or the mineral acid salts thereof, and processes for production thereof 失效
标题翻译： α-卤代-β-氨基丙腈或其无机酸盐及其制备方法
公开(公告)号：US4338259A
公开(公告)日：1982-07-06
申请号：US173715
申请日：1980-07-30
申请人： Ryuichi Mita , Akihiro Yamaguchi , Toshio Kato , Chojiro Higuchi , Hisamichi Murakami
发明人： Ryuichi Mita , Akihiro Yamaguchi , Toshio Kato , Chojiro Higuchi , Hisamichi Murakami
IPC分类号： C07C255/24 , C07C67/00 , C07C253/00 , C07C121/43 , C07C120/00
CPC分类号： C07C255/00
摘要： A process for producing an alpha-halogeno-beta-aminopropionitrile which comprises reacting an alpha,beta-dihalogenopropionitrile with ammonia in water and/or an organic solvent. Action of a mineral acid on the reaction product gives a mineral acid salt of an alpha-halogeno-beta-aminopropionitrile. An isolated alpha-halogeno-beta-aminopropionitrile and a sulfate thereof are also provided.
摘要翻译：一种制备α-卤代-β-氨基丙腈的方法，其包括使α，β-二卤代丙腈与氨在水和/或有机溶剂中反应。无机酸对反应产物的作用得到α-卤代-β-氨基丙腈的无机酸盐。还提供了分离的α-卤代-β-氨基丙腈及其硫酸盐。

10. 发明授权

US06310242B1 Process for preparing D-alloisoleucine and intermediates for preparation 失效
标题翻译：制备D-异亮氨酸和制备中间体的方法
公开(公告)号：US06310242B1
公开(公告)日：2001-10-30
申请号：US09251475
申请日：1999-02-17
申请人： Hirofumi Noda , Koji Ohsaka , Kenichi Sakai , Hisamichi Murakami
发明人： Hirofumi Noda , Koji Ohsaka , Kenichi Sakai , Hisamichi Murakami
IPC分类号： C07C20500
CPC分类号： C07C229/08 , C07C227/34 , C07C227/36
摘要： Disclosed are a novel process for preparing D-alloisoleucine and an improved process for epimerizing L-isoleucine to prepare D-alloisoleucine. In the former process, (2S, 3S)-tartaric acid derivative of formula I below; wherein R stands for a hydrogen atom, a C1-C3 lower alkyl group, lower alkoxy group, chlorine atom, bromine atom and nitro group; and “n” is a number of 0, 1 and 2; is combined with an epimer mixture of L-isoleucine and D-alloisoleucine in a reaction medium to form a complex of D-alloisoleucine and the compound of formula I. The precipitated complex is decomposed by putting it in an alcohol to isolate D-alloisoleucine. In the latter process, L-isoleucine is suspended in an inert solvent which does not substantially dissolve amino acids, and epimerized in the presence of C1-C5 saturated lower fatty acid and salicylaldehyde.
摘要翻译：公开了制备D-异亮氨酸的新方法和用于差异化L-异亮氨酸以制备D-异亮氨酸的改进方法。在前一方法中，下式I的（2S，3S） - 酒石酸衍生物; 其中R代表氢原子，C1-C3低级烷基，低级烷氧基，氯原子，溴原子和硝基; “n”是0,1,2的数; 与L-异亮氨酸和D-异亮氨酸的差向异构体混合物在反应介质中组合以形成D-异亮氨酸与式I化合物的络合物。沉淀的络合物通过将其放入酒精中分离D-异亮氨酸来分解。在后一过程中，将L-异亮氨酸悬浮在基本上不溶解氨基酸的惰性溶剂中，并在C1-C5饱和低级脂肪酸和水杨醛存在下差向异构化。

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