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    • 2. 发明授权
    • Polyesterurethane elastomers and process for their production
    • 聚氨酯弹性体及其生产工艺
    • US06579952B1
    • 2003-06-17
    • US09647416
    • 2000-11-16
    • Akihiro NikiHirotake MatsumotoAkihiko FujiwaraJuichi Fukatani
    • Akihiro NikiHirotake MatsumotoAkihiko FujiwaraJuichi Fukatani
    • C08G1842
    • C08G18/6618C08G18/0895C08G18/4018C08G18/4202C08G18/4244C08G18/4854
    • The present invention has for its object to provide an ester elastomer having a high block of the hard and soft segment components, high flexibility, and good mechanical properties at high temperature, particularly high temperature creep resistance and a process for producing said ester elastomer. The present invention relates to an ester elastomer which is a block copolymer comprising a polyester copolymer (A) and a polymer having hydroxyl groups at both terminal ends (B) (hereinafter referred to sometimes as hydroxyl-terminated polymer) coupled to each other through the intermediary of an urethane component (C) consisting in a group of general formula (1); —O—CO—NH—R1—NH—CO—O—  (1) (wherein R1 represents an alkylene group containing 2 to 15 carbon atoms, —C6H4—, —C6H4—CH2—, —C6H4—CH2—C6H4— (where —C6H4— represents phenylene)) or a group of general formula (2); —O—CO—NH—R2—NH—CO—  (2) (wherein R2 represents an alkylene group containing 2 to 15 carbon atoms, —C6H4—, —C6H4—CH2— or C6H4—CH2—C6H4— (wherein —C6H4— represents phenylene)).
    • 本发明的目的是提供一种具有高块硬组分和软链段组分的高弹性,高温下的良好机械性能,特别是耐高温蠕变性的酯弹性体,以及制备所述酯弹性体的方法。 本发明涉及一种酯弹性体,其是包含聚酯共聚物(A)和在两个末端具有羟基的聚合物(B)(以下有时称为羟基封端的聚合物)的嵌段共聚物,其通过 由通式(1)组成的氨基甲酸酯组分(C)的中间体;(其中R 1表示含有2至15个碳原子的亚烷基,-C 6 H 4 - , - C 6 H 4 -CH 2 - , - C 6 H 4 -CH 2 -C 6 H 4 - (其中-C 6 H 4 - 表示亚苯基))或通式(2)的基团;(其中R 2表示含有2至15个碳原子的亚烷基,-C 6 H 4 - , - C 6 H 4 -CH 2 - 或C 6 H 4 -CH 2 -C 6 H 4 - ( 其中-C 6 H 4 - 代表亚苯基))。