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    • 2. 发明授权
    • Process for preparing phthalocyanine compounds
    • 酞菁化合物的制备方法
    • US07314273B2
    • 2008-01-01
    • US10507594
    • 2003-02-13
    • Colin Dick RobertsonJill Louise JohnsonPrakash Patel
    • Colin Dick RobertsonJill Louise JohnsonPrakash Patel
    • C09B47/26
    • C09D11/328C09B47/24C09B47/26C09B67/0035
    • A process for preparing a mixture of copper phthalocyanine dyes of Formula (1): CuPc(SO3M)x(SO2NH2)y, wherein: CuPc is copper phthalocyanine; M is a cation; x and y each independently have a value of from 0.5 to 3.5; and (x+y)=2 to 5; which process includes: chlorosulphonating a copper phthalocyanine compound using a chlorosulphonating agent; and condensing the product of step (i) with ammonia to give a mixture of copper phthalocyanine dyes of Formula (1); optionally exchanging the cation M in the mixture of copper phthalocyanine dyes of Formula (1) resulting from step (ii) for an alternative cation M; wherein the chlorosulphonating agent includes a mixture of chlorosulphonic acid and a chlorinating agent selected from phosphorous oxychloride and phosphorous trichloride. Also the dyes obtainable from this process; compositions and inks including these dyes; materials printed with these dyes, compositions or inks; ink-jet printer cartridges containing inks made from the dyes; and ink-jet printers including these cartridges.
    • 制备式(1)的铜酞菁染料的混合物的方法:CuPc(SO 3 N)M(SO 3 N)NH >其中:CuPc是铜酞菁; M是阳离子; x和y各自独立地具有0.5至3.5的值; 和(x + y)= 2〜5; 该方法包括:使用氯磺化剂对铜酞菁化合物进行氯磺化; 并将步骤(i)的产物与氨缩合得到式(1)的铜酞菁染料的混合物; 任选地将由步骤(ii)得到的式(1)铜酞菁染料与替代阳离子M的阳离子M交换; 其中氯磺化剂包括氯磺酸和选自三氯氧化磷和三氯化磷的氯化剂的混合物。 也可以从该方法得到的染料; 包括这些染料的组合物和油墨; 用这些染料,组合物或油墨印刷的材料; 含有由染料制成的油墨的喷墨打印机墨盒; 以及包括这些盒的喷墨打印机。
    • 3. 发明授权
    • Phthalocyanine dyes, inks containing the same and use thereof in ink jet
printing
    • 酞菁染料,含有它们的油墨以及在喷墨印刷中的用途
    • US6149722A
    • 2000-11-21
    • US240602
    • 1999-02-01
    • Colin Dick RobertsonMark Kenworthy
    • Colin Dick RobertsonMark Kenworthy
    • C09B47/26C09D11/00C09D11/02B05D1/00B32B3/00C09B47/04
    • C09D11/32C09B47/26C09D11/328
    • Phthalocyanine compounds of Formula (1) have utility as colorants in inks for ink-jet printing, where Formula (1) represents: ##STR1## in which: M represents a metal or H;Pc represents a phthalocyanine nucleus; andR.sup.1 represents H or --(CH.sub.2).sub.n R.sup.3 ; R.sup.2 represents(CH.sub.2).sub.n R.sup.3 ; or R.sup.1 and R.sup.2 together with the nitrogen atom to which they are attached represent a 5 or 6-membered ring; where:n is independently an integer from 1 to 30; andR.sup.3 is independently a group selected from hydroxy, sulpho, cyano, --SR.sup.4, --CO.sub.2 R.sup.5, --PO.sub.3 H.sub.2 and --NR.sup.6 R.sup.7 ; where:R.sup.4, R.sup.5, R.sup.6 and R.sup.7 independently represent H, C.sub.1-30 alkyl optionally substituted by one or more groups selected from hydroxy, mercapto, sulpho, carboxy, cyano and --PO.sub.3 H.sub.2 ;v is the valence of Pc divided by the valence of M;x is from 1.2 to 3.8;y is from 0.1 to 2.7;z is from 0.1 to 2.7; andx, y and z satisfy 2.ltoreq.x+y+z.ltoreq.4.
    • 式(1)的酞菁化合物在用于喷墨印刷的油墨中具有着色剂的用途,其中式(1)表示:其中:M表示金属或H; Pc代表酞菁核; 并且R 1表示H或 - (CH 2)n R 3; R2表示(CH2)nR3; 或R 1和R 2与它们所连接的氮原子一起代表5或6元环; 其中:n独立地为1至30的整数; 和R 3独立地是选自羟基,磺基,氰基,-SR 4,-CO 2 R 5,-PO 3 H 2和-NR 6 R 7的基团; 其中:R4,R5,R6和R7独立地表示H,任选被一个或多个选自羟基,巯基,磺基,羧基,氰基和-PO 3 H 2的基团取代的C 1-3-30烷基; v是Pc的化合价除以M的化合价; x为1.2〜3.8; y为0.1〜2.7; z为0.1〜2.7; x,y和z满足2