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    • 2. 发明申请
    • METHODS FOR THE RECOVERY OF HCL AND FOR THE PRODUCTION OF CARBOHYDRATES
    • HCL的回收和碳水化合物的生产方法
    • US20130047979A1
    • 2013-02-28
    • US13499638
    • 2010-09-21
    • Aharon EyalRobert Jansen
    • Aharon EyalRobert Jansen
    • C13K1/02C01B7/07C09K3/00
    • C07H3/02C01B7/0712C01B7/0737C13K1/04
    • The invention provides an organic phase composition comprising: a. a first component selected from the group consisting of quaternary amines; b. a second component selected from: b1. The group consisting of category B organic acids; b2. The group consisting of a mixtures of category B organic acids and category C organic acids at a B/C molar ratio of RB/C; and b3. The group consisting of a mixtures of category A organic acids and category C organic acids at an A/C molar ratio of RA/C; c. a third component selected from the group consisting of solvents for said first component and for said second component, wherein (i) all three components are oil-soluble and water-insoluble; (ii) the molar concentration of each of said first component and said second component is greater than 0.6 mol/Kg; (iii) the molar ratio between said second component and said first component is greater than 0.9; (iv) RB/C and RA/c are greater than 2; (v) category A organic acids are selected from the group consisting of poly-aromatic sulfonic acids, naphthalene sulfonic acids and acids with a pKa in the range within +/−0.5 pKa units of that of naphthalene sulfonic acid; (vi) category B organic acids are selected from the group consisting of mono-aromatic sulfonic acids, benzene sulfonic acids, and acids with a pKa in the range within +/−0.5 pKa units of that of benzene sulfonic acid; and (vii) category C organic acids are selected from the group consisting of phosphoric acid esters and acids with a pKa in the range within +/−0.5 pKa units of that of di-octyl esters of phosphoric acid.
    • 本发明提供一种有机相组合物,其包含:a。 选自季胺的第一组分; b。 第二个组件选自:b1。 由B类有机酸组成的组; b2。 由B / C摩尔比为RB / C的B类有机酸和C类有机酸的混合物组成的组; 和b3。 由A / C摩尔比为RA / C的A类有机酸和C类有机酸的混合物组成的组; C。 选自由所述第一组分和所述第二组分的溶剂组成的组的第三组分,其中(i)所有三种组分都是油溶性和水不溶性的; (ii)所述第一组分和所述第二组分的摩尔浓度大于0.6mol / Kg; (iii)所述第二组分和所述第一组分之间的摩尔比大于0.9; (iv)RB / C和RA / c大于2; (v)A类有机酸选自聚芳族磺酸,萘磺酸和pKa在萘磺酸的+/- 0.5pKa单位范围内的酸; (vi)B类有机酸选自单芳族磺酸,苯磺酸和pKa在苯磺酸的+/- 0.5pKa单位范围内的酸; 和(vii)C类有机酸选自磷酸酯和酸,其中pKa在磷酸二辛基酯的+/- 0.5pKa单位范围内。
    • 7. 发明申请
    • VISCOUS CARBOHYDRATE COMPOSITIONS AND METHODS FOR THE PRODUCTION THEREOF
    • 粘土碳酸氢盐组合物及其生产方法
    • US20120279497A1
    • 2012-11-08
    • US13491485
    • 2012-06-07
    • Robert JansenAharon Eyal
    • Robert JansenAharon Eyal
    • C13K13/00
    • C13K13/007C13K1/02C13K13/002
    • A viscous fluid comprising 2% wt to 25% wt water, at least 75% wt carbohydrate (calculated by 100×[carbohydrate/(carbohydrate weight+water weight)]), between 0% wt and 25% wt of a second organic solvent and between 10% wt and 55% wt HCl (calculated by 100×[HCl weight/HCl weight+water weight]), which second organic solvent is characterized by at least one of: (a2) having a polarity related component of Hoy's cohesion parameter between 0 and 15 MPa1/2; (b2) having a Hydrogen bonding related component of Hoy's cohesion parameter between 0 and 20 MPa1/2; and (c2) having a solubility in water of less than 15% and forming a heterogeneous azeotrope with water, wherein the weight/weight ratio of said second organic solvent to water is in the range of between 50 and 0.02, and wherein the solubility of water in said organic solvent is less than 20%.
    • 包含2重量%至25重量%水,至少75重量%碳水化合物(由100克碳水化合物/(碳水化合物重量+水重量)计算))的粘性流体),0重量%至25重量%的第二有机溶剂 和10重量%至55重量%HCl(通过100×[HCl重量/ HCl重量+水重量]计算)计算),该第二有机溶剂的特征在于以下至少一个:(a2)具有Hoy的内聚力的极性相关成分 参数介于0和15 MPa1 / 2之间; (b2)具有0〜20MPa1 / 2的Hoy粘附参数的氢键相关成分; 和(c2)在水中的溶解度小于15%并与水形成非均相共沸物,其中所述第二有机溶剂与水的重量/重量比在50和0.02之间,其中溶解度 所述有机溶剂中的水不足20%。