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1. 发明授权

US4636486A Polymerization catalysts 失效
标题翻译：聚合催化剂
公开(公告)号：US4636486A
公开(公告)日：1987-01-13
申请号：US760539
申请日：1985-07-30
申请人： Adolfo Mayr , Ermanno Susa , Antonio Leccese , Velmore Davoli , Ettore Giachetti
发明人： Adolfo Mayr , Ermanno Susa , Antonio Leccese , Velmore Davoli , Ettore Giachetti
IPC分类号： C08F4/00 , B01J21/00 , B01J31/38 , C08F2/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/76 , C08F10/00
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： Polymerization catalysts, particularly catalysts for the polymerization of olefins, are disclosed. The catalysts are prepared by mixing(A) an organometallic compound or hydride of a metal belonging to Groups I to III of the Mendelyeev Periodic Table; with(B) the product obtained by contacting (1) an addition product obtained by reacting a di-, tri-, or tetravalent titanium compound with an electron-donor compound, with (2) an anhydrous magnesium halide, in particular anhydrous MgCl.sub.2 or MgBr.sub.2, which is either preactivated or mixed with the Ti compound under conditions which result in its activation; or by contacting (A) with(B') the product obtained by contacting a di-, tri, or tetravalent Ti compound with an electron-donor compound and a support consisting of an anhydrous Mg halide, in particular MgCl.sub.2 or anhydrous MgBr.sub.2, which is either preactivated or mixed with the Ti compound and electron-donor under conditions such that the Mg halide is activated.
摘要翻译：公开了聚合催化剂，特别是用于烯烃聚合的催化剂。催化剂通过混合（A）属于门多利夫周期表第I至III组的金属的有机金属化合物或氢化物来制备; 与（B）通过使（1）通过使二 - ，三 - 或四价钛化合物与电子给体化合物反应获得的加成产物与（2）无水卤化镁，特别是无水MgCl 2或 MgBr2，其在导致其活化的条件下预活化或与Ti化合物混合; 或者通过使（A）与（B'）使二价，三价或四价Ti化合物与电子给体化合物和由无水卤化镁，特别是MgCl 2或无水MgBr 2组成的载体接触而获得的产物在使Mg卤化物活化的条件下，预先活化或与Ti化合物和电子给体混合。

2. 发明授权

US4113654A Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US4113654A
公开(公告)日：1978-09-12
申请号：US733709
申请日：1976-10-18
申请人： Adolfo Mayr , Velmore Davoli , Antonio Leccese , Ermanno Susa
发明人： Adolfo Mayr , Velmore Davoli , Antonio Leccese , Ermanno Susa
IPC分类号： C08F10/00 , C08F4/64
CPC分类号： C08F10/00
摘要： There are disclosed catalysts which are highly active in the polymerization of olefins and which are prepared by mixing hydrides or organometallic compounds of metals belonging to Groups I to III of the Mendelyeev Periodic Table with the product of reaction between an organic magnesium halide and a halogenated titanium compound, said reaction product containing titanium in an amount of from 0.05% to 10% by weight. Methods for preparing the aforesaid catalysts and the use of the catalysts in the polymerization of ethylene and mixtures thereof with higher alpha-olefins and/or diolefins are also disclosed.
摘要翻译：公开了在烯烃聚合中高活性的催化剂，其通过将属于门多利夫周期表第I至III族的金属的氢化物或有机金属化合物与有机卤化镁和卤化钛之间的反应产物化合物，所述反应产物含有0.05重量％至10重量％的钛。还公开了制备上述催化剂的方法和在乙烯聚合中使用催化剂及其与高级α-烯烃和/或二烯烃的混合物的方法。

3. 发明授权

US4544717A Polymerization catalysts 失效
标题翻译：聚合催化剂
公开(公告)号：US4544717A
公开(公告)日：1985-10-01
申请号：US152531
申请日：1980-05-22
申请人： Adolfe Mayr , Ermanno Susa , Antonio Leccese , Velmore Davoli , Ettoro Giachetti
发明人： Adolfe Mayr , Ermanno Susa , Antonio Leccese , Velmore Davoli , Ettoro Giachetti
IPC分类号： C08F4/00 , B01J21/00 , B01J31/38 , C08F2/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/76 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： Polymerization catalysts, particularly catalysts for the polymerization of olefins, are disclosed. The catalysts are prepared by mixing(A) an organometallic compound or hydride of a metal belonging to Groups I to III of the Mendelyeev Periodic Table; with(B) the product obtained by contacting (1) an addition product obtained by reacting a di-, tri-, or tetravalent titanium compound with an electron-donor compound, with (2) an anhydrous magnesium halide, in particular anhydrous MgCl.sub.2 or MgBr.sub.2, which is either preactivated or mixed with the Ti compound under conditions which result in its activation; or by contacting (A) with(B') the product obtained by contacting a di-, tri-, or tetravalent Ti compound with an electron-donor compound and a support consisting of an anhydrous Mg halide, in particular MgCl.sub.2 or anhydrous MgBr.sub.2, which is either preactivated or mixed with the Ti compound and electron-donor under conditions such that the Mg halide is activated.
摘要翻译：公开了聚合催化剂，特别是用于烯烃聚合的催化剂。催化剂通过混合（A）属于门多利夫周期表第I至III组的金属的有机金属化合物或氢化物来制备; 与（B）通过使（1）通过使二 - ，三 - 或四价钛化合物与电子给体化合物反应获得的加成产物与（2）无水卤化镁，特别是无水MgCl 2或 MgBr2，其在导致其活化的条件下预活化或与Ti化合物混合; 或通过使（A）与（B'）使二价，三价或四价Ti化合物与电子给体化合物和由无水卤化镁，特别是MgCl 2或无水MgBr 2组成的载体接触而获得的产物，在使卤化镁活化的条件下，其被预活化或与Ti化合物和电子给体混合。

4. 发明授权

US4476289A Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US4476289A
公开(公告)日：1984-10-09
申请号：US269604
申请日：1981-06-02
申请人： Adolfo Mayr , Ermanno Susa , Ettore Giachetti
发明人： Adolfo Mayr , Ermanno Susa , Ettore Giachetti
IPC分类号： C08F4/00 , C08F4/02 , C08F4/16 , C08F4/60 , C08F4/64 , C08F4/654 , C08F4/657 , C08F10/00 , C08F10/02 , C08F110/02
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： Catalysts useful in the polymerization of olefins, more particularly of ethylene and mixtures thereof with higher alpha-olefins and/or diolefins, are disclosed. The new catalysts are obtained by mixing a hydride or organometallic compound of a metal belonging to Groups I to III of the Mendelyeev Periodic System with the product obtained by contacting a titanium tetrahalide with a support comprising an anhydrous magnesium or zinc halide in an active form, under particular conditions.
摘要翻译：公开了可用于烯烃聚合，尤其是乙烯聚合的催化剂及其与高级α-烯烃和/或二烯烃的混合物。通过将属于门多利夫定期系统的第I至III族金属的氢化物或有机金属化合物与通过使四卤化钛与包含活性形式的无水镁或锌的卤化物的载体接触而获得的产物来获得新的催化剂，在特定条件下。

5. 发明授权

US4495338A Components of catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂的组分
公开(公告)号：US4495338A
公开(公告)日：1985-01-22
申请号：US190375
申请日：1980-09-24
申请人： Adolfo Mayr , Ermanno Susa , Ettore Giachetti
发明人： Adolfo Mayr , Ermanno Susa , Ettore Giachetti
IPC分类号： C08F10/02 , C08F4/02 , C08F4/62 , C08F4/634 , C08F4/637 , C08F4/68 , C08F10/00
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： Catalysts useful in the polymerization of olefins, more particularly of ethylene and mixtures thereof with alpha-olefins and/or diolefins, are disclosed. The new catalysts are obtained by mixing a halide of titanium or vanadium in which the metal has a valency lower than 4, with a support comprising an anhydrous magnesium or zinc halide in an active form under particular conditions, and then activating the resulting product with a hydride or organometallic compound of a metal belonging to Groups I to III, inclusive, of the Mendelyeev Periodic System.
摘要翻译：公开了用于烯烃聚合，尤其是乙烯聚合的催化剂及其与α-烯烃和/或二烯烃的混合物。通过将金属中低于4的金属的钛或钒的卤化物与在特定条件下活性形式的无水镁或锌的卤化物的载体混合，然后用属于Mendelyeev定期系统的第I至III组（含III）族金属的氢化物或有机金属化合物。

6. 发明授权

US4298718A Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US4298718A
公开(公告)日：1981-11-03
申请号：US622550
申请日：1975-10-14
申请人： Adolfo Mayr , Paolo Galli , Ermanno Susa , Giovanni Di Drusco , Ettore Giachetti
发明人： Adolfo Mayr , Paolo Galli , Ermanno Susa , Giovanni Di Drusco , Ettore Giachetti
IPC分类号： C08F4/00 , C08F4/02 , C08F4/16 , C08F4/60 , C08F4/64 , C08F4/654 , C08F4/657 , C08F10/00 , C08F10/02 , C08F110/02
CPC分类号： C08F10/00 , C08F4/022 , Y10S526/906
摘要： Catalysts useful in the polymerization of olefins, more particularly of ethylene and mixtures thereof with higher alpha-olefins and/or diolefins, are disclosed. The new catalysts are obtained by mixing a hydride or organometallic compound of a metal belonging to Groups I to III of the Mendelyeev Periodic System with the product obtained by contacting a titanium tetrahalide with a support comprising an anhydrous magnesium or zinc halide in an active form, under particular conditions.
摘要翻译：公开了可用于烯烃聚合，尤其是乙烯聚合的催化剂及其与高级α-烯烃和/或二烯烃的混合物。通过将属于门多利夫定期系统的第I至III族金属的氢化物或有机金属化合物与通过使四卤化钛与包含活性形式的无水镁或锌的卤化物的载体接触而获得的产物来获得新的催化剂，在特定条件下。

7. 发明授权

US4542198A Polymerization catalysts 失效
标题翻译：聚合催化剂
公开(公告)号：US4542198A
公开(公告)日：1985-09-17
申请号：US554705
申请日：1983-11-23
申请人： Adolfo Mayr , Umberto Giannini , Ermanno Susa , Paolo Longi , Ettore Giachetti , Domenico DeLuca
发明人： Adolfo Mayr , Umberto Giannini , Ermanno Susa , Paolo Longi , Ettore Giachetti , Domenico DeLuca
IPC分类号： C08F4/76 , C08F4/02 , C08F4/42 , C08F4/64 , C08F10/00 , C08F10/02
CPC分类号： C08F4/022 , C08F10/00 , Y10S526/906 , Y10S526/908 , Y10S526/909
摘要： Highly active catalysts for the polymerization of olefins are disclosed. The catalysts are prepared by mixing a hydride or organometallic compound of a metal belonging to Groups I, II or III of the Mendelyeev Periodic Table with the product obtained by contacting an oxygenated Ti compound in which one or more Ti atoms are bound through oxygen atoms to organic radicals with an activated anhydrous Mg dihalide. The polymerization of ethylene by means of said catalysts is also disclosed.
摘要翻译：公开了用于烯烃聚合的高活性催化剂。通过将属于门多利夫周期表第I，II或III族的金属的氢化物或有机金属化合物与通过氧原子结合的氧化Ti化合物与氧原子结合获得的产物有机基团与活化的无水Mg二卤化物。还公开了通过所述催化剂聚合乙烯。

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