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1. 发明授权

US07064171B1 Non-random styrene-butadiene rubber 失效
标题翻译：无规丁苯橡胶
公开(公告)号：US07064171B1
公开(公告)日：2006-06-20
申请号：US11232685
申请日：2005-09-22
申请人： Adel Farhan Halasa , Wen-Liang Hsu , David Michael Smith, Sr. , Warren James Busch , John Joseph Andre Verthe , Scott Edwards Johnson
发明人： Adel Farhan Halasa , Wen-Liang Hsu , David Michael Smith, Sr. , Warren James Busch , John Joseph Andre Verthe , Scott Edwards Johnson
IPC分类号： C08F236/10
CPC分类号： C08L9/06 , B60C1/0016 , C08F236/10 , C08L7/00 , C08L9/00 , C08L97/005 , Y10S152/905 , C08L2666/02 , C08L2666/08
摘要： The present invention reveals a tire having a tread that is comprised of (1) 30 phr to 80 phr of a non-random styrene-butadiene rubber comprised of polymer chains that are derived from styrene and 1,3-butadiene, wherein from about 10 weight percent to about 50 weight percent of the repeat units in the styrene-butadiene rubber are derived from styrene, wherein from about 60 weight percent to about 90 weight percent of the repeat units in the styrene-butadiene rubber are derived from 1,3-butadiene, wherein from about 30 weight percent to about 50 weight percent of the styrene repeat units are in sequences containing 5 to 20 styrene repeat units, wherein the bound styrene content found in the first half of the polymer chains differs from the bound styrene content found in the second half of the polymer chains by at least 5 weight percent, wherein the styrene-butadiene rubber has a 1,2-vinyl content which is within the range of about 8 percent to about 20 percent, wherein the styrene-butadiene rubber has a number average molecular weight which is within the range of 200,000 to 475,000, and wherein the styrene-butadiene rubber has a glass transition temperature which is within the range of −82° C. to −50° C. and (2) 20 phr to 70 phr of polybutadiene. The tire tread formulation can optionally contain silica and lignin.
摘要翻译：本发明揭示了具有胎面的轮胎，该胎面由（1）30phr至80phr由衍生自苯乙烯和1,3-丁二烯的聚合物链组成的非无规丁苯橡胶组成，其中约10 苯乙烯 - 丁二烯橡胶中重复单元的重量百分比至约50重量％衍生自苯乙烯，其中苯乙烯 - 丁二烯橡胶中重复单元的约60重量％至约90重量％丁二烯，其中约30重量％至约50重量％的苯乙烯重复单元是含有5至20个苯乙烯重复单元的序列，其中在聚合物链的前半部分中发现的结合苯乙烯含量与发现的结合的苯乙烯含量不同在所述聚合物链的后半部分中至少5重量％，其中所述苯乙烯 - 丁二烯橡胶具有在约8％至约20％范围内的1,2-乙烯基含量，其中所述苯乙烯 - 丁二烯 iene橡胶的数均分子量在200,000至475,000的范围内，其中丁苯橡胶的玻璃化转变温度在-82℃至-50℃的范围内，（2 ）20phr至70phr的聚丁二烯。轮胎胎面配方可任选地含有二氧化硅和木质素。

2. 发明授权

US07884168B2 Heterogeneous rubbery polymers having random, tapered, and block portions therein and methods of making same 有权
标题翻译：具有随机，锥形和嵌段部分的非均相橡胶状聚合物及其制备方法
公开(公告)号：US07884168B2
公开(公告)日：2011-02-08
申请号：US12371122
申请日：2009-02-13
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Leh-Yeh Hsu, legal representative , Warren James Busch , David Michael Smith, Sr. , Jennifer Elizabeth Labbe , Scott Edwards Johnson
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Warren James Busch , David Michael Smith, Sr. , Jennifer Elizabeth Labbe , Scott Edwards Johnson
IPC分类号： C08F236/10 , C08F2/04 , C08F4/48
CPC分类号： B60C1/0016 , C08F212/08 , C08F236/10 , Y10S152/905 , C08F2/001
摘要： A heterogeneous rubbery polymer is provided that includes a polymer chain derived from a vinyl aromatic monomer and a conjugated diolefin monomer, wherein from greater than 20 weight percent to about 40 weight percent of units in the rubbery polymer are derived from the vinyl aromatic monomer and from about 60 weight percent to about 80 weight percent of units in the rubbery polymer are derived from the conjugated diolefin monomer. The polymer chain is further characterized by having greater than zero and less than about 30 weight percent of the vinyl aromatic units in sequences containing 1 vinyl aromatic unit, from about 5 weight percent to about 20 weight percent of the vinyl aromatic units in sequences containing 5 to 8 vinyl aromatic units, and greater than zero and less than about 5 weight percent of the vinyl aromatic units in sequences containing 9 or more vinyl aromatic units.
摘要翻译：提供了一种异相橡胶状聚合物，其包括衍生自乙烯基芳族单体和共轭二烯烃单体的聚合物链，其中橡胶状聚合物中大于20重量％至约40重量％的单元衍生自乙烯基芳族单体和橡胶状聚合物中约60重量％至约80重量％的单元衍生自共轭二烯单体。聚合物链的特征还在于具有大于零且小于约30重量％的含有乙烯基芳族单元的乙烯基芳族单元，约5重量％至约20重量％的乙烯基芳族单元，其序列包含5 至8个乙烯基芳族单元，并且大于零且小于约5重量％的含有9个或更多个乙烯基芳族单元的乙烯基芳族单元。

3. 发明申请

US20100206443A1 Heterogeneous Rubbery Polymers Having Random, Tapered, and Block Portions Therein and Methods of Making Same 有权
标题翻译：具有随机，锥形和块状部分的异质橡胶聚合物及其制造方法
公开(公告)号：US20100206443A1
公开(公告)日：2010-08-19
申请号：US12371122
申请日：2009-02-13
申请人： Adel Farhan Halasa , Wen-Liang Hsu , Leh-Yeh Hsu , Warren James Busch , David Michael Smith, SR. , Jennifer Elizabeth Labbe , Scott Edwards Johnson
发明人： Adel Farhan Halasa , Wen-Liang Hsu , Leh-Yeh Hsu , Warren James Busch , David Michael Smith, SR. , Jennifer Elizabeth Labbe , Scott Edwards Johnson
IPC分类号： B60C11/00 , C08F112/08 , C08F2/00
CPC分类号： B60C1/0016 , C08F212/08 , C08F236/10 , Y10S152/905 , C08F2/001
摘要： A heterogeneous rubbery polymer is provided that includes a polymer chain derived from a vinyl aromatic monomer and a conjugated diolefin monomer, wherein from greater than 20 weight percent to about 40 weight percent of units in the rubbery polymer are derived from the vinyl aromatic monomer and from about 60 weight percent to about 80 weight percent of units in the rubbery polymer are derived from the conjugated diolefin monomer. The polymer chain is further characterized by having greater than zero and less than about 30 weight percent of the vinyl aromatic units in sequences containing 1 vinyl aromatic unit, from about 5 weight percent to about 20 weight percent of the vinyl aromatic units in sequences containing 5 to 8 vinyl aromatic units, and greater than zero and less than about 5 weight percent of the vinyl aromatic units in sequences containing 9 or more vinyl aromatic units.
摘要翻译：提供了一种异相橡胶状聚合物，其包括衍生自乙烯基芳族单体和共轭二烯烃单体的聚合物链，其中橡胶状聚合物中大于20重量％至约40重量％的单元衍生自乙烯基芳族单体和橡胶状聚合物中约60重量％至约80重量％的单元衍生自共轭二烯单体。聚合物链的特征还在于具有大于零且小于约30重量％的含有乙烯基芳族单元的乙烯基芳族单元，约5重量％至约20重量％的乙烯基芳族单元，其序列包含5 至8个乙烯基芳族单元，并且大于零且小于约5重量％的含有9个或更多个乙烯基芳族单元的乙烯基芳族单元。

4. 发明授权

US07081504B2 Synthesis of 1,4-polybutadiene 失效
公开(公告)号：US07081504B2
公开(公告)日：2006-07-25
申请号：US10929977
申请日：2004-08-30
申请人： Michael Joseph Rachita , Scott Edwards Johnson
发明人： Michael Joseph Rachita , Scott Edwards Johnson
IPC分类号： C08F2/06 , C08F136/06
CPC分类号： C08F36/06 , C08F136/06 , Y10S526/907 , C08F4/7098
摘要： This invention is based upon the unexpected discovery that alkylated diphenylamines can be used in conjunction with nickel based catalyst systems which contain (a) an organonickel compound, (b) an organoaluminum compound, and (c) a fluorine containing compound to produce cis-1,4-polybutadiene having reduced molecular weight and an increased level of branching. This results in the cis-1,4-polybutadiene exhibiting good processability without sacrificing cold flow characteristics. Additionally, the alkylated diphenylamine which remains in the rubber acts in a manner which provides it with antioxidant protection. In other words, the use of alkylated diphenylamines accomplishes the three major objectives that are realized by employing para-styrenated diphenylamines (reduced molecular weight, regulated polymer macrostructure through branching and antidegradant protection). However, the utilization of alkylated diphenylamines, unlike para-styrenated diphenylamines, offers the additional advantage of being soluble in aliphatic solvents. By virtue of this increased level of solubility in aliphatic solvents, such as hexane, alkylated diphenylamines can be employed at greatly reduced levels of aromatic solvents. Likewise, when mixed catalyst streams containing alkylated diphenyl amines are combined precipitation is minimized compared to para-styrenated diphenylamine significantly improving issues related to fouling. The subject invention more specifically discloses a process for producing cis-1,4-polybutadiene having a reduced molecular weight and improved processability which comprises polymerizing 1,3-butadiene in the presence of (a) an organonickel compound, (b) an organoaluminum compound, (c) a fluorine containing compound, and (d) an alkylated diphenylamine; wherein the alkylated diphenylamine has alkyl groups that contain from 2 to 18 carbon atoms, and wherein the organoaluminum compound and the fluorine containing compound are brought together in the presence of the alkylated diphenylamine.

5. 发明授权

US06294683B1 Solid/liquid phase transfer system 有权
标题翻译：固相/液相转移系统
公开(公告)号：US06294683B1
公开(公告)日：2001-09-25
申请号：US09456764
申请日：1999-12-07
申请人： Scott Edwards Johnson , Dane Kenton Parker , Niranjan Shah
发明人： Scott Edwards Johnson , Dane Kenton Parker , Niranjan Shah
IPC分类号： C07F708
CPC分类号： C07F7/1892
摘要： The present invention discloses a technique for reacting a first liquid chemical compound with a second liquid chemical compound which comprises (1) supporting the first liquid chemical compound on a solid support; (2) subsequently bringing the solid support into contact with the second liquid chemical compound; and (3) allowing the first chemical compound to react with the second chemical compound in the presence of a phase transfer catalyst to produce a reaction product. This technique is particularly useful in the synthesis of sulfur containing organosilicon compounds of the formula Z-Alk-Sn-Alk-Z wherein Z is selected from the group consisting of wherein R1 is an alkyl group of 1 to 4 carbon atoms, cyclohexyl or phenyl; wherein R2 is an alkoxy group of 1 to 8 carbon atoms or a cycloalkoxy group of 5 to 8 carbon atoms; wherein Alk is a divalent hydrocarbon of 1 to 18 carbon atoms; and wherein n is an integer of 2 to 8. For instance, such sulfur containing organosilicon compounds can be made by reacting aqueous solutions of various polysulfidic anions in saturated sodium chloride brine solutions with chloropropyltriethoxysilane (CPTES) supported on carbon black in the presence of a phase transfer catalyst.
摘要翻译：本发明公开了一种使第一液体化合物与第二液体化合物反应的技术，其包括（1）在固体载体上支撑第一液体化合物; （2）随后将固体支持物与第二液体化合物接触; 和（3）允许第一化合物在相转移催化剂存在下与第二化合物反应以产生反应产物。该方法特别适用于合成式Z-Alk-Sn-Alk-Z的含硫有机硅化合物，其中Z选自其中R1是1-4个碳原子的烷基，环己基或苯基; 其中R2为1-8个碳原子的烷氧基或5-8个碳原子的环烷氧基; 其中Alk是1至18个碳原子的二价烃; 并且其中n为2至8的整数。例如，这种含硫有机硅化合物可以通过使饱和氯化钠盐水溶液中的各种多硫代阴离子的水溶液与负载在炭黑上的氯丙基三乙氧基硅烷（CPTES）反应，相转移催化剂。

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