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    • 10. 发明授权
    • Production of light hydrocarbons by treatment of heavy hydrocarbons with
water
    • 通过用水处理重质烃来生产轻烃
    • US4543177A
    • 1985-09-24
    • US619663
    • 1984-06-11
    • Andiappan K. S. MurthyKundanbhai M. PatelAlex Y. Bekker
    • Andiappan K. S. MurthyKundanbhai M. PatelAlex Y. Bekker
    • C10G9/00C10G31/08C10G29/02C07C4/04C10G35/02
    • C10G9/00C10G31/08
    • A process is disclosed for converting heavy hydrocarbons into light hydrocarbons which comprises contacting, in a first zone, a heavy hydrocarbon having an API gravity at 25.degree. C. of less than about 20, such as Boscan heavy crude oil and tar sand bitumen, with a liquid comprising water, in the absence of externally added catalyst and hydrogen, while maintaining the first zone at a temperature between 400.degree. and about 480.degree. C. and at a pressure at least about 690 kPa (about 100 psig, about 6.76 atm) and less than about 5,000 kPa (about 725 psig, about 148 atm), for a contact time under continuous flow conditions sufficient to produce a uniform (i.e., intimate) reaction mixture; forwarding the uniform reaction mixture to a second zone wherein the temperature and pressure conditions of the first zone are maintained at substantially steady state conditions for a time sufficient to separate the uniform mixture into a residue and a phase comprising light hydrocarbons, gas and water, withdrawing the residue and said phase from the second zone; and recovering a light hydrocarbon product having an API gravity at 25.degree. C. of greater than about 20 and substantially free of vanadium and nickel values, i.e., less than 50 ppm, preferably less than 10 or 5 ppm, a gaseous product, and a residue.
    • 公开了一种将重质烃转化为轻质烃的方法,其包括在第一区域中将具有小于约20的API重力在25℃的重质烃如Boscan重质原油和焦油砂沥青与 在没有外加催化剂和氢的情况下,包含水的液体,同时将第一区域保持在400至约480℃之间的温度和至少约690kPa(约100psig,约6.76atm)的压力下, 和约5,000kPa(约725psig,约148atm),在足以产生均匀(即紧密)的反应混合物的连续流动条件下的接触时间; 将均匀的反应混合物转移到第二区,其中第一区的温度和压力条件保持在基本上稳定的状态条件下足以将均匀混合物分离成残余物的时间和包含轻质烃,气体和水的相,抽出 残留物和来自第二区的所述相; 并回收具有大于约20的API重力在25℃下的基本上不含钒和镍值的轻烃产物,即小于50ppm,优选小于10或5ppm的气态产物,以及 残留物