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1. 发明授权

US09938400B2 Propylene copolymers in soft thermoplastic blends 有权
公开(公告)号：US09938400B2
公开(公告)日：2018-04-10
申请号：US12108336
申请日：2008-04-23
申请人： Abdelhadi Sahnoune , Sudhin Datta , Mun Fu Tse , Charles L. Sims , James N. Coffey , Peijun Jiang
发明人： Abdelhadi Sahnoune , Sudhin Datta , Mun Fu Tse , Charles L. Sims , James N. Coffey , Peijun Jiang
IPC分类号： C08L23/00 , C08L23/10 , C08L23/14
CPC分类号： C08L23/10 , C08L23/14 , C08L23/142 , C08L2666/04
摘要： Thermoplastic polyolefins (TPOs) and/or thermoplastic vulcanizates (TPVs) are blended with low molecular weight propylene-dominated copolymers to provide polymeric compositions with an improved balance between processability and toughness. The compositions have improved processability by facilitating the ease with which a TPO or TPV, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into articles.

2. 发明申请

US20090270545A1 Propylene Copolymers In Soft Thermoplastic Blends 有权
标题翻译：软质热塑性共混物中的丙烯共聚物
公开(公告)号：US20090270545A1
公开(公告)日：2009-10-29
申请号：US12108336
申请日：2008-04-23
申请人： Abdelhadi Sahnoune , Sudhin Datta , Mun Fu Tse , Charles L. Sims , James N. Coffey , Peijun Jiang
发明人： Abdelhadi Sahnoune , Sudhin Datta , Mun Fu Tse , Charles L. Sims , James N. Coffey , Peijun Jiang
IPC分类号： C08K5/01
CPC分类号： C08L23/10 , C08L23/14 , C08L23/142 , C08L2666/04
摘要： Thermoplastic polyolefins (TPOs) and/or thermoplastic vulcanizates (TPVs) are blended with low molecular weight propylene-dominated copolymers to provide polymeric compositions with an improved balance between processability and toughness. The compositions have improved processability by facilitating the ease with which a TPO or TPV, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into articles.
摘要翻译：将热塑性聚烯烃（TPO）和/或热塑性硫化橡胶（TPV）与低分子量丙烯主导的共聚物共混以提供加工性和韧性之间改善的平衡的聚合物组合物。组合物通过促进TPO或TPV通常难以熔融加工的容易性，可以以高线速度加工，从而改进了组合物形成制品，从而改进了加工性能。

3. 发明申请

US20080249231A1 Soft homogeneous isotactic polypropylene compositions 有权
标题翻译：软均匀全同立构聚丙烯组合物
公开(公告)号：US20080249231A1
公开(公告)日：2008-10-09
申请号：US12080486
申请日：2008-04-03
申请人： Sudhin Datta , Charles L. Sims , Peijun Jiang , Abdelhadi Sahnoune , Derek W. Thurman
发明人： Sudhin Datta , Charles L. Sims , Peijun Jiang , Abdelhadi Sahnoune , Derek W. Thurman
IPC分类号： C08L23/16 , C08L9/00
CPC分类号： C08L23/10 , C08L23/12 , C08L23/142 , C08L2205/02 , C08L2666/06
摘要： The present invention also discloses a homogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR @ 230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.
摘要翻译：本发明还公开了一种均匀的共混组合物，其包含： a）1重量％至99重量％的第一聚合物组分的共混物，其包含5重量％至35重量％的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量％至95重量％来自全同立构聚丙烯序列的结晶度为0.1％至约25％的丙烯衍生单元的第一聚合物组分，熔点为45℃至105℃，并且其中熔体流动速率（MFR @ 230℃ 。）的第一聚合物组分在300g / 10min至5000g / 10min之间。 b）1重量％至99重量％的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物的共混物，其中共聚物中共聚α-烯烃的百分比为0.0-9重量％所述第二聚合物组分并且其中所述第二聚合物组分具有大于约110℃的熔点，其中所述第一聚合物组分具有小于1000ppm的由分子降解剂的化学反应产生的反应产物。

4. 发明授权

US07858701B2 Soft homogeneous isotactic polypropylene compositions 有权
标题翻译：软均匀全同立构聚丙烯组合物
公开(公告)号：US07858701B2
公开(公告)日：2010-12-28
申请号：US12080486
申请日：2008-04-03
申请人： Sudhin Datta , Charles L. Sims , Peijun Jiang , Abdelhadi Sahnoune , Derek W. Thurman
发明人： Sudhin Datta , Charles L. Sims , Peijun Jiang , Abdelhadi Sahnoune , Derek W. Thurman
IPC分类号： C08L23/10
CPC分类号： C08L23/10 , C08L23/12 , C08L23/142 , C08L2205/02 , C08L2666/06
摘要： The present invention also discloses a homogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR @ 230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.
摘要翻译：本发明还公开了一种均匀的共混组合物，其包含： a）1重量％至99重量％的第一聚合物组分的共混物，其包含5重量％至35重量％的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量％至95重量％来自全同立构聚丙烯序列的结晶度为0.1％至约25％的丙烯衍生单元的第一聚合物组分，熔点为45℃至105℃，并且其中熔体流动速率（MFR @ 230℃ 。）的第一聚合物组分在300g / 10min至5000g / 10min之间。 b）1重量％至99重量％的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物的共混物，其中共聚物中共聚α-烯烃的百分比为0.0-9重量％所述第二聚合物组分并且其中所述第二聚合物组分具有大于约110℃的熔点，其中所述第一聚合物组分具有小于1000ppm的由分子降解剂的化学反应产生的反应产物。

5. 发明申请

US20080249232A1 Soft heterogeneous isotactic polypropylene compositions 有权
标题翻译：软异相全同立构聚丙烯组合物
公开(公告)号：US20080249232A1
公开(公告)日：2008-10-09
申请号：US12080495
申请日：2008-04-03
申请人： Sudhin Datta , Charles L. Sims , Peijun Jiang , Abdelhadi Sahnoune , Derek W. Thurman
发明人： Sudhin Datta , Charles L. Sims , Peijun Jiang , Abdelhadi Sahnoune , Derek W. Thurman
IPC分类号： C08L23/16 , C08L9/00
CPC分类号： C08L23/10 , C08L23/16 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要： The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.
摘要翻译：本发明还公开了一种非均相共混组合物，其包含： a）1重量％至99重量％的第一聚合物组分的共混物，其包含5重量％至35重量％的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量％至95重量％来自全同立构聚丙烯序列的结晶度为0.1％至约25％的丙烯衍生单元的第一聚合物组分，熔点为45℃至105℃，并且其中熔体流动速率（MFR @ 230℃ ）第一聚合物组分的量为300g / 10min至5000g / 10min，b）1重量％至99重量％的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物，其中共聚物中的共聚α-烯烃的百分比为第二聚合物组分的0.0％至9％，其中第二聚合物组分的熔点大于约110℃，其中第一聚合物组分的含量小于产生1000ppm的反应产物来自分子降解剂的化学反应。

6. 发明授权

US08263707B2 Soft heterogeneous isotactic polypropylene compositions 有权
标题翻译：软异相全同立构聚丙烯组合物
公开(公告)号：US08263707B2
公开(公告)日：2012-09-11
申请号：US12080495
申请日：2008-04-03
申请人： Sudhin Datta , Charles L. Sims , Peijun Jiang , Abdelhadi Sahnoune , Derek W. Thurman
发明人： Sudhin Datta , Charles L. Sims , Peijun Jiang , Abdelhadi Sahnoune , Derek W. Thurman
IPC分类号： C08L23/00 , C08L23/10 , C08K5/00
CPC分类号： C08L23/10 , C08L23/16 , C08L2205/02 , C08L2205/03 , C08L2666/02
摘要： The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.
摘要翻译：本发明还公开了一种非均相共混组合物，其包含： a）1重量％至99重量％的第一聚合物组分的共混物，其包含5重量％至35重量％的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量％至95重量％来自全同立构聚丙烯序列的结晶度为0.1％至约25％的丙烯衍生单元的第一聚合物组分，熔点为45℃至105℃，并且其中熔体流动速率（MFR @ 230℃ 第一聚合物组分的重量比在300g / 10min至5000g / 10min之间b）1重量％至99重量％的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物，其中共聚物中的共聚α-烯烃的百分比为第二聚合物组分的0.0％至9％，其中第二聚合物组分的熔点大于约110℃，其中第一聚合物组分的含量小于产生1000ppm的反应产物来自分子降解剂的化学反应。

7. 发明授权

US08227547B2 Foamable thermoplastic reactor blends and foam article therefrom 有权
标题翻译：可发泡热塑性反应器共混物和泡沫制品
公开(公告)号：US08227547B2
公开(公告)日：2012-07-24
申请号：US12986645
申请日：2011-01-07
申请人： Peijun Jiang , Abdelhadi Sahnoune , Armenag Dekmezian
发明人： Peijun Jiang , Abdelhadi Sahnoune , Armenag Dekmezian
IPC分类号： C08F8/00 , C08L23/10 , C08J9/00 , C08J9/12 , C08J9/30
CPC分类号： C08L23/10 , C08F255/02 , C08J9/0061 , C08J2205/052 , C08J2323/10 , C08J2423/12 , C08L23/12 , C08L23/142 , C08L2203/14 , C08L2205/02 , C08L2205/025 , C08L2666/06
摘要： This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt % propylene and from 0 to less than 10 wt % comonomer, said first propylene component having a Tm of 120° C. or more; and (b) a second propylene polymer component comprising from 30 to 90 wt % propylene and 70 to 10 wt % comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120° C.; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%, and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec−1 and temperature of 180° C.; and where when the blend is foamed with a foaming agent, the foamed article has a density of 800 kg/m3 or less.
摘要翻译：本发明涉及包含反应器内聚合物共混物的可发泡共混物，其包含：（a）包含90至100重量％丙烯和0至小于10重量％共聚单体的第一丙烯聚合物组分，所述第一丙烯组分的Tm为 120℃以上; 和（b）第二丙烯聚合物组分，其包含30至90重量％的丙烯和70至10重量％的共聚单体，所述第二丙烯聚合物的Mw为30,000g / mol以上，所述第二丙烯聚合物具有结晶度与第一聚合物不同，其中所述聚合物共混物在与发泡剂组合之前具有：（i）至少120℃的Tm; （ii）10dg / min以上的MFR; （iii）至少8MPa的拉伸强度; （iv）断裂伸长率至少为200％，（v）当在1秒-1的应变速率和温度为180℃下测量伸长粘度时，断裂时的拉伸粘度与线性粘度之比为5以上 C。; 并且当共混物用发泡剂发泡时，发泡制品的密度为800kg / m 3或更小。

8. 发明申请

US20100076128A1 Polyolefin Adhesive Compositions And Articles Made Therefrom 有权
标题翻译：聚烯烃粘合剂组合物和制品
公开(公告)号：US20100076128A1
公开(公告)日：2010-03-25
申请号：US12624697
申请日：2009-11-24
申请人： Ramin Abhari , Charles Lewis Sims , Kenneth Lewtas , Mun Fu Tse , Patrick Brant , Peijun Jiang , Wai Yan Chow , Jean-Roch Schauder , Caiguo Gong , David Raymond Johnsrud , Jo Ann Marie Canich
发明人： Ramin Abhari , Charles Lewis Sims , Kenneth Lewtas , Mun Fu Tse , Patrick Brant , Peijun Jiang , Wai Yan Chow , Jean-Roch Schauder , Caiguo Gong , David Raymond Johnsrud , Jo Ann Marie Canich
IPC分类号： C09J123/00 , C09J133/00
CPC分类号： C09J123/12 , C08L23/10 , C08L91/06 , C08L2666/24 , C09J123/10
摘要： Embodiments of the present invention relate to article comprising 1) a functionalized component, 2) tackifier, and 3) an olefin polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 5 mole % of ethylene having a Dot T-Peel of 1 Newton or more, a branching index (g′) of 0.95 or less measured at the Mz of the polymer; and an Mw of 100,000 or less; where the functional component is selected from the group consisting of functionalized polymers, functionalized oligomers and beta nucleating agents; and where the Gardner color of the adhesive does not change by more than 7 Gardner units when the adhesive has been heat aged at 180° C. for 48 hours as compared to the Gardner color of the unaged composition.
摘要翻译：本发明的实施方案涉及包含1）官能化组分，2）增粘剂和3）包含一种或多种C 3至C 40烯烃，任选一种或多种二烯烃和小于5摩尔％的具有 1牛顿或更多的点T剥离，在聚合物的Mz处测量的支化指数（g'）为0.95或更小; Mw为100,000以下; 其中所述官能组分选自官能化聚合物，官能化低聚物和β成核剂; 当粘合剂与未老化组合物的加德纳颜色相比，当粘合剂在180℃加热老化48小时时，粘合剂的加德纳颜色不会改变超过7加纳德单位。

9. 发明授权

US07700707B2 Polyolefin adhesive compositions and articles made therefrom 有权
标题翻译：聚烯烃粘合剂组合物和由其制成的制品
公开(公告)号：US07700707B2
公开(公告)日：2010-04-20
申请号：US10825348
申请日：2004-04-15
申请人： Ramin Abhari , Charles Lewis Sims , Kenneth Lewtas , Mun Fu Tse , Patrick Brant , Peijun Jiang , Wai Yan Chow , Jean-Roch Schauder , Caiguo Gong , David Raymond Johnsrud , Jo Ann Marie Canich
发明人： Ramin Abhari , Charles Lewis Sims , Kenneth Lewtas , Mun Fu Tse , Patrick Brant , Peijun Jiang , Wai Yan Chow , Jean-Roch Schauder , Caiguo Gong , David Raymond Johnsrud , Jo Ann Marie Canich
IPC分类号： C08F210/00
CPC分类号： C09J123/12 , C08L23/10 , C08L91/06 , C08L2666/24 , C09J123/10
摘要： Embodiments of the present invention relate to article comprising 1) a functionalized component, 2) tackifier, and 3) an olefin polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 5 mole % of ethylene having a Dot T-Peel of 1 Newton or more, a branching index (g′) of 0.95 or less measured at the Mz of the polymer; and an Mw of 100,000 or less; where the functional component is selected from the group consisting of functionalized polymers, functionalized oligomers and beta nucleating agents; and where the Gardner color of the adhesive does not change by more than 7 Gardner units when the adhesive has been heat aged at 180° C. for 48 hours as compared to the Gardner color of the unaged composition.
摘要翻译：本发明的实施方案涉及包含1）官能化组分，2）增粘剂和3）包含一种或多种C 3至C 40烯烃，任选一种或多种二烯烃和小于5摩尔％的具有 1牛顿或更多的点T剥离，在聚合物的Mz处测量的支化指数（g'）为0.95或更小; Mw为100,000以下; 其中所述官能组分选自官能化聚合物，官能化低聚物和β成核剂; 当粘合剂与未老化组合物的加德纳颜色相比，当粘合剂在180℃加热老化48小时时，粘合剂的加德纳颜色不会改变超过7加纳德单位。

10. 发明申请

US20130150531A1 Functionalized Olefin Polymers 有权
标题翻译：官能化烯烃聚合物
公开(公告)号：US20130150531A1
公开(公告)日：2013-06-13
申请号：US13524288
申请日：2012-06-15
申请人： Ramin Abhari , Charles Lewis Sims , Mun Fu Tse , Patrick Brant , Peijun Jiang , David Raymond Johnsrud
发明人： Ramin Abhari , Charles Lewis Sims , Mun Fu Tse , Patrick Brant , Peijun Jiang , David Raymond Johnsrud
IPC分类号： C08L23/16 , C08L23/26
CPC分类号： C08L23/16 , C08F10/06 , C08F110/06 , C08F210/06 , C08L23/12 , C08L23/26 , C08L51/06 , C08L2314/06 , C08L2666/24 , C08F2500/09 , C08F2500/20 , C08F210/16
摘要： This invention relates to a composition comprising a functionalized C3 to C40 olefin polymer comprising at least 50 mol % of one or more C3 to C40 olefins, and where the olefin polymer, prior to functionalization, has: a Dot T-Peel of 1 Newton or more on Kraft paper; an Mw of 10,000 to 100,000; and a branching index (g′) of 0.98 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 60,000, or a branching index of 0.95 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 100,000; and where the C3 to C40 olefin polymer comprises at least 0.001 wt % of a functional group. This invention further relates to blends of such functionalized polymers with other polymers including non-functionalized C3 to C40 olefin polymers as described above.
摘要翻译：本发明涉及包含官能化的C 3至C 40烯烃聚合物的组合物，其包含至少50摩尔％的一种或多种C 3至C 40烯烃，并且其中在官能化之前烯烃聚合物具有：1牛顿的点T- 更多牛皮纸; 10,000至100,000的Mw; 和当聚合物的Mw为10,000至60,000时聚合物的Mz测量的支化指数（g'）为0.98或更小，或当聚合物具有聚合物的Mw时，在聚合物的Mz下测量的支化指数为0.95或更小 Mw为10,000至100,000; 并且其中C 3至C 40烯烃聚合物包含至少0.001重量％的官能团。本发明还涉及这种官能化聚合物与其它聚合物的混合物，包括如上所述的非官能化的C 3至C 40烯烃聚合物。

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