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    • 2. 发明授权
    • 1,2,3-triazole based metal-organic framework as photo-active materials
    • 1,2,3-三唑基金属有机骨架作为光活性材料
    • US08779155B2
    • 2014-07-15
    • US13068489
    • 2011-05-12
    • Xiaodong Shi
    • Xiaodong Shi
    • C07D249/06
    • C07D249/06
    • A TAF compound that can have substitutions on either of the two benzene rings and/or the C-5 position of the triazole to alter the properties of the TAF compound can be wherein X can be H, an aromatic group, a hetero aromatic group, an alkyl or any substituted alkyl group, ketone, aldyhyde, carboxylic acid derivatives; Y1, Y2, Y3, Y4, and Y5 can be one or more of H, aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives; and Z1, Z2, Z3, Z4, and Z5 can be one or more of H aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives. Included is a preparation of the TAF compound and use as a photoactive and/or catalyst.
    • 可以在三唑的两个苯环和/或C-5位的任一个上具有取代以改变TAF化合物的性质的TAF化合物可以是其中X可以是H,芳族基团,杂芳族基团, 烷基或任何取代的烷基,酮,醛,羧酸衍生物; Y 1,Y 2,Y 3,Y 4和Y 5可以是H,芳族基团,杂芳族基团,烷基或任何取代的烷基,酮,醛或羧酸衍生物中的一种或多种; Z 1,Z 2,Z 3,Z 4和Z 5可以是H芳族基团,杂芳族基团,烷基或任何取代的烷基,酮,醛或羧酸衍生物中的一种或多种。 包括TAF化合物的制备和用作光活性和/或催化剂。
    • 5. 发明授权
    • 1,2,3-triazole bound borane compounds, synthesis of, and use in reduction reactions
    • 1,2,3-三唑结合的硼烷化合物,合成并用于还原反应
    • US08026373B1
    • 2011-09-27
    • US12798299
    • 2010-04-01
    • Xiaodong Shi
    • Xiaodong Shi
    • C07D403/00
    • C07F5/022
    • A 1,2,3-triazole coordinated borane such as where the B and the R3 groups can be on any of the three N positions and R1, R2, R3, R4, and R5 can be one or more of H, any alkyl, aryl, or substituted alkyl or aryl groups and the position of the final products are the combination of any N position; i.e. N1—R3—N3—BH etc. The triazole-borane compounds can be synthesized in a single-step from simple organic molecules under mild reactions. The 1,2,3-triazole coordinated borane can be synthesized by use of about a 1 to 1 equivalent of the benzole-triazole and the BR3 can be added together without solution or dissolved in an organic solvent (between about 5 M to about 0.001 M for each reactant). The solution can be stirred for about 1 to about 5 hours at an effective temperature to yield the triazole-borane. These compounds can be used as an effective reductant in a reduction reaction for one or more of the groups aldehyde, ketone, imine, and reductive coupling between aldehyde/ketone with amine (both primary and secondary) in a wide range of media.
    • B,R 3,R 3,R 4,R 5,R 5,R 5,R 5,R 5,R 5,R 5,R 5,R 5,R 5, 芳基或取代的烷基或芳基,并且最终产物的位置是任何N位的组合; 即N1-R3-N3-BH等。三唑 - 硼烷化合物可以在轻微的反应下从简单的有机分子中单步合成。 1,2,3-三唑配位的硼烷可以通过使用约1至1当量的苯并三唑来合成,并且BR 3可以一起加入而不用溶液或溶解在有机溶剂中(约5M至约0.001 M为每种反应物)。 该溶液可在有效温度下搅拌约1至约5小时,得到三唑 - 硼烷。 这些化合物可用作一种或多种醛,酮,亚胺和醛/酮与胺(主要和次要的)在宽范围的介质中的还原偶联的还原反应中的有效还原剂。
    • 6. 发明申请
    • Synthesis of triazole derivatives from Lewis base mediated nitroalkene-aldehyde coupling
    • 从路易斯碱介导的硝基烯 - 醛偶联合成三唑衍生物
    • US20090048451A1
    • 2009-02-19
    • US12228924
    • 2008-08-18
    • Xiaodong Shi
    • Xiaodong Shi
    • C07D249/04
    • C07D249/04
    • In the present invention a method to synthesize a triazole derivative from a Lewis base mediated nitroalkene-aldehyde coupling is revealed. In this synthesis a nitroalkene is reacted with an aromatic aldehyde in the presence of a Lewis Base, NaN3, and a solvent for about 2 hours to about 48 hours at ambient conditions such as room temperature. The synthesized product may be any type of 4,5 disubstituted-1,2,3-triazoles. Of the nitroalkenes alkenes most β-alkyl nitroalkenes can react such as a β-substituted alkene. The aromatic aldehyde can be any 6 carbon aromatic aldehyde whether unsubstituted, substituted, disubstituted, heterocyclic, or a five carbon thiophene carboxaldehyde. The reaction takes place in the presence of NaN3, a Lewis base, and solvents.
    • 在本发明中,揭示了从路易斯碱介导的硝基烯 - 醛偶联合成三唑衍生物的方法。 在该合成中,在环境条件如室温下,在路易斯碱,NaN 3和溶剂存在下,将芳基烯与芳族醛反应约2小时至约48小时。 合成的产物可以是任何类型的4,5二取代-1,2,3-三唑。 在硝基烯烃烯烃中,大多数β-烷基硝基烯烃可以反应,如β-取代的烯烃。 芳醛可以是任何6碳芳族醛,无论是未取代的,取代的,二取代的,杂环的,或五碳噻吩甲醛。 反应在NaN3,路易斯碱和溶剂的存在下进行。
    • 7. 发明申请
    • 1,2,3-triazole based metal-organic framework as photo-active materials
    • 1,2,3-三唑基金属有机骨架作为光活性材料
    • US20110282071A1
    • 2011-11-17
    • US13068489
    • 2011-05-12
    • Xiaodong Shi
    • Xiaodong Shi
    • C07D249/06
    • C07D249/06
    • A TAF compound that can have substitutions on either of the two benzene rings and/or the C-5 position of the triazole to alter the properties of the TAF compound can be wherein X can be H, an aromatic group, a hetero aromatic group, an alkyl or any substituted alkyl group, ketone, aldyhyde, carboxylic acid derivatives; Y1, Y2, Y3, Y4, and Y5 can be one or more of H, aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives; and Z1, Z2, Z3, Z4, and Z5 can be one or more of H aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives. Included is a preparation of the TAF compound and use as a photoactive and/or catalyst.
    • 可以在三唑的两个苯环和/或C-5位的任一个上具有取代以改变TAF化合物的性质的TAF化合物可以是其中X可以是H,芳族基团,杂芳族基团, 烷基或任何取代的烷基,酮,醛,羧酸衍生物; Y 1,Y 2,Y 3,Y 4和Y 5可以是H,芳族基团,杂芳族基团,烷基或任何取代的烷基,酮,醛或羧酸衍生物中的一种或多种; Z 1,Z 2,Z 3,Z 4和Z 5可以是H芳族基团,杂芳族基团,烷基或任何取代的烷基,酮,醛或羧酸衍生物中的一种或多种。 包括TAF化合物的制备和用作光活性和/或催化剂。
    • 8. 发明申请
    • 1,2,3-TRIAZOLE BOUND BORANE COMPOUNDS, SYNTHESIS OF, AND USE IN REDUCTION REACTIONS
    • 1,2,3-三唑环绕硼烷化合物,减少反应的合成和使用
    • US20110245507A1
    • 2011-10-06
    • US12798299
    • 2010-04-01
    • Xiaodong Shi
    • Xiaodong Shi
    • C07F5/02
    • C07F5/022
    • A 1,2,3-triazole coordinated borane such as where the B and the R3 groups can be on any of the three N positions and R1, R2, R3, R4, and R5 can be one or more of H, any alkyl, aryl, or substituted alkyl or aryl groups and the position of the final products are the combination of any N position; i.e. N1—R3—N3—BH etc. The triazole-borane compounds can be synthesized in a single-step from simple organic molecules under mild reactions. The 1,2,3-triazole coordinated borane can be synthesized by use of about a 1 to 1 equivalent of the benzole-triazole and the BR3 can be added together without solution or dissolved in an organic solvent (between about 5 M to about 0.001 M for each reactant). The solution can be stirred for about 1 to about 5 hours at an effective temperature to yield the triazole-borane. These compounds can be used as an effective reductant in a reduction reaction for one or more of the groups aldehyde, ketone, imine, and reductive coupling between aldehyde/ketone with amine (both primary and secondary) in a wide range of media.
    • B,R 3,R 3,R 4,R 5,R 5,R 5,R 5,R 5,R 5,R 5,R 5,R 5,R 5, 芳基或取代的烷基或芳基,并且最终产物的位置是任何N位的组合; 即N1-R3-N3-BH等。三唑 - 硼烷化合物可以在轻微的反应下从简单的有机分子中单步合成。 1,2,3-三唑配位的硼烷可以通过使用约1至1当量的苯并三唑来合成,并且BR 3可以一起加入而不用溶液或溶解在有机溶剂中(约5M至约0.001 M为每种反应物)。 该溶液可在有效温度下搅拌约1至约5小时,得到三唑 - 硼烷。 这些化合物可用作一种或多种醛,酮,亚胺和醛/酮与胺(主要和次要的)在宽范围的介质中的还原偶联的还原反应中的有效还原剂。
    • 9. 发明授权
    • 1,2,3-triazole based metal-organic framework as photo-active materials
    • 1,2,3-三唑基金属有机骨架作为光活性材料
    • US09284282B2
    • 2016-03-15
    • US14314325
    • 2014-06-25
    • Xiaodong Shi
    • Xiaodong Shi
    • C07D249/06
    • C07D249/06
    • A TAF compound that can have substitutions on either of the two benzene rings and/or the C-5 position of the triazole to alter the properties of the TAF compound can be wherein X can be H, an aromatic group, a hetero aromatic group, an alkyl or any substituted alkyl group, ketone, aldyhyde, carboxylic acid derivatives; Y1, Y2, Y3, Y4, and Y5 can be one or more of H, aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives; and Z1, Z2, Z3, Z4 and Z5 can be one or more of H aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives. Included is a preparation of the TAF compound and use as a photoactive and/or catalyst.
    • 可以在三唑的两个苯环和/或C-5位的任一个上具有取代以改变TAF化合物的性质的TAF化合物可以是其中X可以是H,芳族基团,杂芳族基团, 烷基或任何取代的烷基,酮,醛,羧酸衍生物; Y 1,Y 2,Y 3,Y 4和Y 5可以是H,芳族基团,杂芳族基团,烷基或任何取代的烷基,酮,醛或羧酸衍生物中的一种或多种; Z 1,Z 2,Z 3,Z 4和Z 5可以是H芳族基团,杂芳族基团,烷基或任何取代的烷基,酮,醛或羧酸衍生物中的一种或多种。 包括TAF化合物的制备和用作光活性和/或催化剂。
    • 10. 发明申请
    • 1,2,3-Triazole Based Metal-Organic Framework as Photo-Active Materials
    • 1,2,3-三唑基金属有机骨架作为光活性材料
    • US20140371465A1
    • 2014-12-18
    • US14314325
    • 2014-06-25
    • Xiaodong Shi
    • Xiaodong Shi
    • C07D249/06
    • C07D249/06
    • A TAF compound that can have substitutions on either of the two benzene rings and/or the C-5 position of the triazole to alter the properties of the TAF compound can be wherein X can be H, an aromatic group, a hetero aromatic group, an alkyl or any substituted alkyl group, ketone, aldyhyde, carboxylic acid derivatives; Y1, Y2, Y3, Y4, and Y5 can be one or more of H, aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives; and Z1, Z2, Z3, Z4 and Z5 can be one or more of H aromatic groups, hetero aromatic groups, alkyl or any substituted alkyl groups, ketone, aldyhyde, or carboxylic acid derivatives. Included is a preparation of the TAF compound and use as a photoactive and/or catalyst.
    • 可以在三唑的两个苯环和/或C-5位的任一个上具有取代以改变TAF化合物的性质的TAF化合物可以是其中X可以是H,芳族基团,杂芳族基团, 烷基或任何取代的烷基,酮,醛,羧酸衍生物; Y 1,Y 2,Y 3,Y 4和Y 5可以是H,芳族基团,杂芳族基团,烷基或任何取代的烷基,酮,醛或羧酸衍生物中的一种或多种; Z 1,Z 2,Z 3,Z 4和Z 5可以是H芳族基团,杂芳族基团,烷基或任何取代的烷基,酮,醛或羧酸衍生物中的一种或多种。 包括TAF化合物的制备和用作光活性和/或催化剂。