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    • 1. 发明授权
    • Photographic material for the preparation of printing plates
    • 用于制作印刷版的摄影材料
    • US3721559A
    • 1973-03-20
    • US3721559D
    • 1971-08-23
    • AGFA GEVAERT NV
    • DE HAES LGEVERS HVANHEERTUM J
    • G03F7/06G03F7/02
    • G03F7/063
    • A planographic printing plate is prepared from a photographic sheet material comprising a support, a light-sensitive silver halide emulsion layer and an exterior hydrophilic colloid stratum having at its free surface a pattern of finely divided silver particles, by contacting the same with an aqueous alkaline fixer composition containing an oxidizing agent for metallic silver and an organic thione, or mercapto tautomer thereof, for converting the pattern of silver particles into a hydrophobic ink-receptive pattern, the colloid stratum being hardened before the material is used for printing and preferably before or at least concurrently with its contact with said fixer composition, the extent of the hardening being at least that necessary to prevent removal of the colloid material during printing. The pattern of silver particles is produced by means of the silver complex diffusion transfer process in which insoluble development nuclei are applied to the free layer surface either from the diffusion transfer developing liquid or a separate liquid applied prior to the developing liquid. Preferably the colloid stratum is hardened by means of a latent hardener released during the course of the diffusion transfer process. The colloid stratum can be an external stratum of the emulsion layer or a separate colloid layer applied to the emulsion layer.