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1. 发明授权

US09352304B2 Methods for preparing ethylene glycol from polyhydroxy compounds 有权
标题翻译：从多羟基化合物制备乙二醇的方法
公开(公告)号：US09352304B2
公开(公告)日：2016-05-31
申请号：US13395470
申请日：2010-11-04
申请人： Tao Zhang , Zhijun Tai , Aiqin Wang , Mingyuan Zheng
发明人： Tao Zhang , Zhijun Tai , Aiqin Wang , Mingyuan Zheng
IPC分类号： C07C29/00 , B01J23/888 , B01J23/652 , C07C29/132 , B01J23/30 , B01J23/42 , B01J23/46 , B01J23/755 , B01J35/00
CPC分类号： B01J23/888 , B01J23/30 , B01J23/42 , B01J23/462 , B01J23/468 , B01J23/6527 , B01J23/755 , B01J35/0006 , C07C29/132 , Y02P20/52 , C07C31/202
摘要： This invention provides methods for producing ethylene glycol from polyhydroxy compounds such as cellulose, starch, hemicellulose, glucose, sucrose, fructose, fructan, xylose and soluble xylooligosaccharides. The methods uses polyhydroxy compounds as the reactant, a composite catalyst having active components comprising one or more transition metals of Groups 8, 9, or 10, including iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, as well as tungsten oxide, tungsten sulfide, tungsten hydroxide, tungsten chloride, tungsten bronze oxide, tungsten acid, tungstate, metatungstate acid, metatungstate, paratungstate acid, paratungstate, peroxotungstic acid, pertungstate, heteropoly acid containing tungsten. Reacting at a temperature of 120-300° C. and a hydrogen pressure of 1-13 MPa under hydrothermal conditions to accomplish one-step catalytic conversion. It realizes efficient, highly selective, high yield preparation of ethylene glycol and propylene glycol from polyhydroxy compounds. The advantage of processes disclosed in this invention include renewable raw material and high atom economy. At the same time, compared with other technologies that converts biomass raw materials into polyols, methods disclosed herein enjoy advantages including simple reaction process, high yield of targeted products, as well as easy preparation and low cost for the catalysts.
摘要翻译：本发明提供从多羟基化合物如纤维素，淀粉，半纤维素，葡萄糖，蔗糖，果糖，果聚糖，木糖和可溶性低聚木糖中生产乙二醇的方法。该方法使用多羟基化合物作为反应物，具有包含一种或多种第8,9或10族过渡金属（包括铁，钴，镍，钌，铑，钯，铱和铂）的活性组分的复合催化剂，以及作为氧化钨，硫化钨，氢氧化钨，氯化钨，青铜氧化钨，钨酸，钨酸盐，偏钨酸，偏钨酸盐，仲钨酸，仲钨酸盐，过钨酸，过钨酸盐，含钨杂多酸。在水热条件下，在120-300℃的温度和1-13MPa的氢压下进行反应，完成一步催化转化。它实现了从多羟基化合物的乙二醇和丙二醇的高效，高选择性，高产率的制备。本发明公开的方法的优点包括可再生原料和高原子经济性。同时，与将生物质原料转化为多元醇的其他技术相比，本文公开的方法具有包括简单的反应过程，高产率的目标产物以及易于制备和低成本的优点。

2. 发明申请

US20110046419A1 METHOD FOR PRODUCING ETHYLENE GLYCOL FROM POLYHYDROXY COMPOUND 有权
标题翻译：从聚羟基化合物生产乙烯甘油的方法
公开(公告)号：US20110046419A1
公开(公告)日：2011-02-24
申请号：US12916625
申请日：2010-10-31
申请人： Tao ZHANG , Mingyuan ZHENG , Aiqin WANG , Na JI , Jifeng PANG , Zhijun TAI , Likun ZHOU , Jingguang CHEN , Xiaodong WANG
发明人： Tao ZHANG , Mingyuan ZHENG , Aiqin WANG , Na JI , Jifeng PANG , Zhijun TAI , Likun ZHOU , Jingguang CHEN , Xiaodong WANG
IPC分类号： C07C29/00
CPC分类号： B01J23/6525 , B01J21/04 , B01J21/06 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/652 , B01J23/6527 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/19 , B01J27/22 , B01J27/24 , B01J37/0205 , B01J37/18 , C07C29/00 , C07C29/132 , Y02P20/52 , C07C31/202 , C07C31/26
摘要： A method for producing ethylene glycol, including (a) adding a polyhydroxy compound and water to a sealed high-pressure reactor, (b) removing air and introducing hydrogen, and (c) allowing the polyhydroxy compound to react in the presence of a catalyst while stiffing. The catalyst includes a first active ingredient and a second active ingredient. The first active ingredient includes a transition metal of Group 8, 9, or 10 selected from iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, and/or a mixture thereof. The second active ingredient includes a metallic state of molybdenum and/or tungsten, or a carbide, nitride, or phosphide thereof. The method is carried out at a hydrogen pressure of 1-12 MPa, at a temperature of 120-300° C. for not less than 5 min in a one-step catalytic reaction. The efficiency, selectivity, and the yield of ethylene glycol are high. The preparation process is simple and the materials used are renewable.
摘要翻译：一种生产乙二醇的方法，包括（a）在密封的高压反应器中加入多羟基化合物和水，（b）除去空气和引入氢，和（c）使多羟基化合物在催化剂存在下反应同时僵硬。催化剂包括第一活性成分和第二活性成分。第一活性成分包括选自铁，钴，镍，钌，铑，钯，铱和铂的第8,9或10族的过渡金属和/或它们的混合物。第二活性成分包括钼和/或钨的金属状态，或其碳化物，氮化物或磷化物。该方法在1-12MPa的氢气压力下，在120-300℃的温度下在一步催化反应中不少于5分钟进行。乙二醇的效率，选择性和产率高。制备过程简单，使用的材料是可再生的。

3. 发明申请

US20120172633A1 METHODS FOR PREPARING ETHYLENE GLYCOL FROM POLYHYDROXY COMPOUNDS 有权
标题翻译：从聚羟基化合物制备乙烯甘油的方法
公开(公告)号：US20120172633A1
公开(公告)日：2012-07-05
申请号：US13395470
申请日：2010-11-04
申请人： Tao Zhang , Zhijun Tai , Aiqin Wang , Mingyuan Zheng
发明人： Tao Zhang , Zhijun Tai , Aiqin Wang , Mingyuan Zheng
IPC分类号： C07C29/132
CPC分类号： B01J23/888 , B01J23/30 , B01J23/42 , B01J23/462 , B01J23/468 , B01J23/6527 , B01J23/755 , B01J35/0006 , C07C29/132 , Y02P20/52 , C07C31/202
摘要： This invention provides methods for producing ethylene glycol from polyhydroxy compounds such as cellulose, starch, hemicellulose, glucose, sucrose, fructose, fructan, xylose and soluble xylooligosaccharides. The methods uses polyhydroxy compounds as the reactant, a composite catalyst having active components comprising one or more transition metals of Groups 8, 9, or 10, including iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, as well as tungsten oxide, tungsten sulfide, tungsten hydroxide, tungsten chloride, tungsten bronze oxide, tungsten acid, tungstate, metatungstate acid, metatungstate, paratungstate acid, paratungstate, peroxotungstic acid, pertungstate, heteropoly acid containing tungsten. Reacting at a temperature of 120-300° C. and a hydrogen pressure of 1-13 MPa under hydrothermal conditions to accomplish one-step catalytic conversion. It realizes efficient, highly selective, high yield preparation of ethylene glycol and propylene glycol from polyhydroxy compounds. The advantage of processes disclosed in this invention include renewable raw material and high atom economy. At the same time, compared with other technologies that converts biomass raw materials into polyols, methods disclosed herein enjoy advantages including simple reaction process, high yield of targeted products, as well as easy preparation and low cost for the catalysts.
摘要翻译：本发明提供从多羟基化合物如纤维素，淀粉，半纤维素，葡萄糖，蔗糖，果糖，果聚糖，木糖和可溶性低聚木糖中生产乙二醇的方法。该方法使用多羟基化合物作为反应物，具有包含一种或多种第8,9或10族过渡金属（包括铁，钴，镍，钌，铑，钯，铱和铂）的活性组分的复合催化剂以及作为氧化钨，硫化钨，氢氧化钨，氯化钨，青铜氧化钨，钨酸，钨酸盐，偏钨酸，偏钨酸盐，仲钨酸，仲钨酸盐，过钨酸，过钨酸盐，含钨杂多酸。在水热条件下，在120-300℃的温度和1-13MPa的氢压下进行反应，完成一步催化转化。它实现了从多羟基化合物的乙二醇和丙二醇的高效，高选择性，高产率的制备。本发明公开的方法的优点包括可再生原料和高原子经济性。同时，与将生物质原料转化为多元醇的其他技术相比，本文公开的方法具有包括简单的反应过程，高产率的目标产物以及易于制备和低成本的优点。

4. 发明授权

US08324433B2 Method for producing ethylene glycol from polyhydroxy compound 有权
标题翻译：从多羟基化合物制备乙二醇的方法
公开(公告)号：US08324433B2
公开(公告)日：2012-12-04
申请号：US12916625
申请日：2010-10-31
申请人： Tao Zhang , Mingyuan Zheng , Aiqin Wang , Na Ji , Jifeng Pang , Zhijun Tai , Likun Zhou , Jingguang Chen , Xiaodong Wang
发明人： Tao Zhang , Mingyuan Zheng , Aiqin Wang , Na Ji , Jifeng Pang , Zhijun Tai , Likun Zhou , Jingguang Chen , Xiaodong Wang
IPC分类号： C07C29/132 , C07C29/60
CPC分类号： B01J23/6525 , B01J21/04 , B01J21/06 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/652 , B01J23/6527 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/19 , B01J27/22 , B01J27/24 , B01J37/0205 , B01J37/18 , C07C29/00 , C07C29/132 , Y02P20/52 , C07C31/202 , C07C31/26
摘要： A method for producing ethylene glycol, including (a) adding a polyhydroxy compound and water to a sealed high-pressure reactor, (b) removing air and introducing hydrogen, and (c) allowing the polyhydroxy compound to react in the presence of a catalyst while stiffing. The catalyst includes a first active ingredient and a second active ingredient. The first active ingredient includes a transition metal of Group 8, 9, or 10 selected from iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, and/or a mixture thereof. The second active ingredient includes a metallic state of molybdenum and/or tungsten, or a carbide, nitride, or phosphide thereof. The method is carried out at a hydrogen pressure of 1-12 MPa, at a temperature of 120-300° C. for not less than 5 min in a one-step catalytic reaction. The efficiency, selectivity, and the yield of ethylene glycol are high. The preparation process is simple and the materials used are renewable.
摘要翻译：一种生产乙二醇的方法，包括（a）在密封的高压反应器中加入多羟基化合物和水，（b）除去空气和引入氢，和（c）使多羟基化合物在催化剂存在下反应同时僵硬。催化剂包括第一活性成分和第二活性成分。第一活性成分包括选自铁，钴，镍，钌，铑，钯，铱和铂的第8,9或10族的过渡金属和/或它们的混合物。第二活性成分包括钼和/或钨的金属状态，或其碳化物，氮化物或磷化物。该方法在1-12MPa的氢气压力下，在120-300℃的温度下在一步催化反应中不少于5分钟进行。乙二醇的效率，选择性和产率高。制备过程简单，使用的材料是可再生的。

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