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1. 发明授权

US06489474B1 Process for producing amide compound 失效
标题翻译：酰胺化合物的制备方法
公开(公告)号：US06489474B1
公开(公告)日：2002-12-03
申请号：US09926816
申请日：2001-12-21
申请人： Yuuji Kawaragi , Tohru Setoyama
发明人： Yuuji Kawaragi , Tohru Setoyama
IPC分类号： C07D20104
CPC分类号： C07D201/04
摘要： Object of the present invention is to provide a process for producing an amide compound with high efficiency by subjecting an oxime compound to Beckmann rearrangement in a liquid phase under mild reaction conditions. Namely, the invention relates to a process for producing an amide compound such as &egr;-caprolactam by subjecting an oxime compound such as cyclohexanone oxime to Beckmann rearrangement in a liquid phase, characterized in that the reaction is carried out in the presence of (1) a non-fluorine-containing sulfonic anhydride and an N,N-disubstituted amide compound or (2) at least one compound selected from the group consisting of sulfonic acids and anhydrides thereof, an N,N-disubstituted amide compound, and a carboxylic anhydride.
摘要翻译：本发明的目的是提供一种通过在温和的反应条件下使肟化合物在液相中经受贝克曼重排而高效生产酰胺化合物的方法。即，本发明涉及通过使肟化合物如环己酮肟在液相中进行贝克曼重排来制备ε-己内酰胺的酰胺化合物的方法，其特征在于反应在（1）非含氟磺酸酐和N，N-二取代酰胺化合物或（2）至少一种选自磺酸及其酸酐，N，N-二取代酰胺化合物和羧酸酐的化合物。

2. 发明授权

US5414160A Method for dimerizing butenes, dimeric composition of butenes and method for producing alcohols by means thereof 失效
标题翻译：二聚丁烯的方法，丁二烯的二聚组合物及其制备方法
公开(公告)号：US5414160A
公开(公告)日：1995-05-09
申请号：US244718
申请日：1994-06-16
申请人： Keiichi Sato , Yuuji Kawaragi , Yasuko Higashino
发明人： Keiichi Sato , Yuuji Kawaragi , Yasuko Higashino
IPC分类号： B01J31/14 , B01J31/24 , C07C2/36 , C07C45/50 , C07C29/141 , C07C2/30 , C07C11/02 , C07C31/125
CPC分类号： C07C45/50 , B01J31/143 , B01J31/2404 , C07C2/36 , B01J2531/847 , C07C2531/04 , C07C2531/14 , C07C2531/24
摘要： A method for dimerizing an n-butene wherein a catalyst system is used which is produced in situ from an organonickel compound having no nickel-halogen bond, a triarylphosphine and/or a monoalkyldiarylphosphine, an organoaluminum compound and hydrogen. The resulting octenes are excellent as a raw material of alcohols for a plasticizer, and an excellent plasticizer can be obtained from alcohols having 9 carbon atoms produced by using the octenes.
摘要翻译： PCT No.PCT / JP93 / 01477 Sec。 371日期：1994年6月16日 102（e）日期1994年6月16日PCT提交1993年10月14日PCT公布。出版物WO94 / 08924 日本1994年4月28日。一种二正丁烯的方法，其中使用催化剂体系，其由不具有镍 - 卤键的有机镍化合物原位制备，三芳基膦和/或单烷基二芳基膦，有机铝化合物和氢。所得辛烯作为增塑剂的醇的原料是优异的，并且可以通过使用辛烯生产的具有9个碳原子的醇获得优异的增塑剂。

3. 发明授权

US5446213A Dimerization method of lower olefins and alcohol production with dimerized products 失效
标题翻译：低聚烯烃和二聚产物酒精生产的二聚方法
公开(公告)号：US5446213A
公开(公告)日：1995-08-29
申请号：US244212
申请日：1994-06-03
申请人： Keiichi Sato , Yuuji Kawaragi , Yasuko Higashino
发明人： Keiichi Sato , Yuuji Kawaragi , Yasuko Higashino
IPC分类号： C07C2/30 , C07C2/34 , C07C29/16 , C07C29/141 , C07C11/02 , C07C31/125
CPC分类号： C07C29/16 , C07C2/30 , C07C2/34 , C07C2531/02 , C07C2531/04 , C07C2531/14 , C07C2531/16
摘要： The present invention is directed to a method of dimerizing lower olefins which comprises dimerizing a lower olefins in the presence of a catalyst, wherein the catalyst used comprises a nickel compound, an organic aluminum compound, and a phosphite compound having the general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are phenyl groups optionally substituted by substituents and may be different from each other, at least two of R.sup.1, R.sup.2, R.sup.3, and R.sup.4 have a hydrocarbon group as a substituent in the ortho position; A is a divalent aliphatic, alicyclic or aromatic hydrocarbon group which optionally has a substituent; and n is 0 or 1. The present invention is also directed a method of producing alcohol by means of hydroformylating and hydrogenating the newly formed olefins obtained through the said dimerization method of the lower olefins. In the dimerization method of the lower olefins according to the present invention, it is possible to produce in an economic manner olefinic mixtures which are high in activity and low in degree of branching. In addition, the alcohols produced with the said olefins show totally superior performance as the raw material for plasticizers, which are thus valuable in industrial applications.
摘要翻译： PCT No.PCT / JP93 / 01425 Sec。 371日期：1994年6月3日 102（e）1994年6月3日PCT PCT日期为1993年10月5日。本发明涉及二烯化低级烯烃的方法，其包括在催化剂存在下使低级烯烃二聚，其中使用的催化剂包括镍化合物，有机铝化合物和具有通式（I）的亚磷酸酯化合物：其中R 1，R 2，R 3和R 4任选被取代基取代并且可以彼此不同的苯基，至少 R1，R2，R3和R4中的两个在邻位具有烃基作为取代基; A是任选具有取代基的二价脂族，脂环族或芳族烃基; n为0或1.本发明还涉及通过对通过所述低级烯烃的所述二聚方法获得的新形成的烯烃进行加氢甲酰化和氢化来制备醇的方法。在根据本发明的低级烯烃的二聚方法中，可以经济地制备活性高，支化度低的烯烃混合物。此外，用所述烯烃生产的醇显示出与用于增塑剂的原料完全相同的性能，因此在工业应用中是有价值的。

4. 发明授权

US6087528A Process for producing hydroxyalkyl monoacrylate using stannoxane catalysts 失效
标题翻译：使用锡氧烷催化剂生产羟基烷基单丙烯酸酯的方法
公开(公告)号：US6087528A
公开(公告)日：2000-07-11
申请号：US83964
申请日：1998-05-26
申请人： Toshiharu Yokoyama , Yuuji Kawaragi , Kouya Murai
发明人： Toshiharu Yokoyama , Yuuji Kawaragi , Kouya Murai
IPC分类号： B01J31/12 , B01J31/40 , C07C67/03 , C07C67/08 , C07C67/02
CPC分类号： B01J31/4015 , B01J31/122 , B01J31/2226 , C07C67/03 , C07C67/08 , B01J2231/49 , B01J2531/42 , Y02P20/584
摘要： A process for producing hydroxyalkyl monoacrylate of the present invention, comprises the steps of: reacting acrylic acid or an acrylic acid derivative with alkane diol for esterification and/or transesterification therebetween in the presence of a reaction catalyst comprising a stannoxane compound; recovering said reaction catalyst from a liquid reaction product by extraction; and recycling the recovered reaction catalyst to a reaction system for said esterification and/or transesterification. The process of the present invention is an industrially useful process for producing hydroxyalkyl monoacrylate, which is excellent in reactivity, selectivity for an aimed product, stability of a reaction catalyst used and stability of a reaction substrate and product, and is improved so as to effectively recover and reuse the reaction catalyst.
摘要翻译：本发明的羟基烷基单丙烯酸酯的制备方法包括以下步骤：在含有苯并恶烷化合物的反应催化剂的存在下，使丙烯酸或丙烯酸衍生物与烷二醇进行酯化和/或酯交换反应; 通过萃取从液体反应产物中回收所述反应催化剂; 并将回收的反应催化剂循环到用于所述酯化和/或酯交换反应的反应体系中。本发明的方法是工业上有用的制备羟基烷基单丙烯酸酯的方法，其反应性优异，目标产物的选择性，所用的反应催化剂的稳定性和反应底物和产物的稳定性都得到改善，从而有效地回收和再利用反应催化剂。

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