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1. 发明授权

US06090741A Catalyst combination and process for the low-temperature co-production of methanol and methyl formate in liquid phase 失效
标题翻译：催化剂组合和方法用于液相中甲醇和甲酸甲酯的低温共生产
公开(公告)号：US06090741A
公开(公告)日：2000-07-18
申请号：US145735
申请日：1998-09-02
申请人： Yutang Wu , Shizhong Luo , Xingquan Liu , Wenkai Chen , Chaoxia Jia , Shunfen Li , Zuolong Yu
发明人： Yutang Wu , Shizhong Luo , Xingquan Liu , Wenkai Chen , Chaoxia Jia , Shunfen Li , Zuolong Yu
IPC分类号： B01J23/86 , C07C29/154 , C07C67/36 , B01J31/00
CPC分类号： C07C29/154 , B01J23/868 , C07C67/36 , Y02P20/52
摘要： The present invention relates to a novel catalyst combination and a novel ocess for the synthesis of methanol and methyl formate (MF), and more specifically to the production of methanol and MF by contacting syngas under relatively mild conditions in a slurry phase with the novel catalyst combination comprising unreduced copper chromite prepared using specifical method, alkali alcoholates, a nonionics and a non-polar solvent. The nonionics, for example, C.sub.8 H.sub.17 --(C.sub.6 H.sub.4)--O--(C.sub.2 H.sub.4 O).sub.n H (where n is between 4 and 60) is used in the amount that is at least 5 vol. % of the slurry (liquid reaction medium). And the non-polar solvent having a dielectricity constant between 2 and 3 at 20.degree. C. is used in the amount that is at least 50 vol. % of the slurry. The present invention allows the synthesis of methanol and MF to occur in the temperature range of approximately 100-150.degree. C., and the pressure range of 3-8 MPa. The process produces methanol and MF with up to 95% syngas conversion per pass and up to 99% selectivity to methanol and MF. Very small amount of water, carbon dioxide and dimethyl ether is also produced. A space-time-yield of 88.3 gms./L/h is achieved when using a continuous stirring tank reactor(CSTR). A tubular slurry reactor of 10 liter volume without any mechanical agitator has been successfully used. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.
摘要翻译：本发明涉及一种新的催化剂组合和用于合成甲醇和甲酸甲酯（MF）的新方法，更具体地涉及在相对温和的条件下在新鲜催化剂的淤浆相中使合成气接触生产甲醇和MF 组合包括使用特殊方法制备的未还原的亚铬酸铜，碱金属醇盐，非离子表面活性剂和非极性溶剂。非离子表面活性剂例如C8H17-（C6H4）-O-（C2H4O）nH（其中n在4和60之间）的用量至少为5体积％。％的浆液（液体反应介质）。并且在20℃下介电常数介于2和3之间的非极性溶剂的用量至少为50体积％。％的浆料。本发明允许甲醇和MF的合成在约100-150℃的温度范围和3-8MPa的压力范围内进行。该过程产生甲醇和MF，每次通过高达95％的合成气转化率，对甲醇和MF的选择性高达99％。也产生非常少量的水，二氧化碳和二甲醚。当使用连续搅拌釜反应器（CSTR）时，实现88.3gms./L/h的时空产量。已经成功地使用了没有任何机械搅拌器的10升体积的管状浆料反应器。本催化剂组合还能够耐受H2 / CO比的波动，而不会对反应速率产生重大的有害影响。此外，二氧化碳和水也是耐受的，而没有实质的催化剂失活。

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