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    • 1. 发明授权
    • Process for treating gas containing hydrogen sulfide
    • 处理含硫化氢气体的方法
    • US3941875A
    • 1976-03-02
    • US354868
    • 1973-04-26
    • Hidemasa TsurutaYukinori HiwatashiTeruhiko HirabayashiSeiji Kumata
    • Hidemasa TsurutaYukinori HiwatashiTeruhiko HirabayashiSeiji Kumata
    • B01D53/52B01D53/77C01B17/05C01B17/16C10K1/10C01B17/06B01D53/34
    • C10K1/10C01B17/167
    • A process for treating a hydrogen sulfide-containing gas in a closed loop system wherein said gas is passed through and absorbed by an alkaline aqueous absorbent containing an alkali carbonate and an oxidation catalyst. The solution containing the dissolved hydrogen sulfide is oxidized with an oxygen-containing gas to convert the absorbed hydrogen sulfide into elementary sulfur and sulfur salt compounds. After separation of the elementary sulfur from the solution, the solution is re-circulated for use as alkaline absorbent. A part of the re-circulated solution is diverted and subjected to mixed-combustion with an auxiliary fuel in a combustion furnace at an air ratio lower than 0.9 and at a temperature of 700.degree.C to 1100.degree.C to thermally decompose the sulfur compounds into hydrogen sulfide and an alkali carbonate. The gaseous products of decomposition are brought into direct contact with boiling water to collect the alkali carbonate in the form of an aqueous solution and leaving hydrogen sulfide in the gas.
    • 一种在闭环系统中处理含硫化氢的气体的方法,其中所述气体通过并被含有碱金属碳酸盐和氧化催化剂的碱性含水吸收剂吸收。 含有溶解的硫化氢的溶液用含氧气体氧化,将吸收的硫化氢转化为单硫和硫盐化合物。 在从溶液中分离出元素硫后,溶液再循环用作碱性吸收剂。 一部分再循环的溶液被转向并在燃烧炉中以空气比低于0.9,在700℃至1100℃的温度下与辅助燃料混合燃烧,以将硫化合物热分解成 硫化氢和碱金属碳酸盐。 将分解的气态产物与沸水直接接触,收集水溶液形式的碱金属碳酸盐,并在气体中留下硫化氢。