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    • 3. 发明申请
    • METHOD FOR PRODUCTION OF POLYARYLENE SULFIDE RESIN WITH EXCELLENT LUMINOSITY AND THE POLYARYLENE SULFIDE RESIN
    • 用于生产具有优异亮度的聚亚烷基硫酸盐树脂的方法和聚氯乙烯树脂
    • US20100105845A1
    • 2010-04-29
    • US12518243
    • 2008-01-04
    • Young-Rok LeeIl-Hoon ChaJun-Sang Cho
    • Young-Rok LeeIl-Hoon ChaJun-Sang Cho
    • C08L81/04C08G75/14C08G65/38
    • C08G75/0263C08G75/0209C08G75/0231C08G75/0281C08L81/02C08L81/00
    • The present invention relates to a process of producing polyarylene sulfide (PAS) and PAS resin produced therefrom, and more specifically, to a process of preparing polyarylene sulfide with better thermal properties and luminosity than conventional PAS and the PAS resin produced therefrom, including the steps of: a) melting and mixing a composition including solid sulfur, iodinated aryl compounds, and a polymerization terminator; b) polymerizing the molten mixture of step a) for 1 to 30 hours while increasing the temperature and decreasing the pressure from initial reaction conditions of a temperature of 180 to 250° C. and a pressure of 50 to 450 Torr to final reaction conditions of a temperature of 270 to 350° C. and a pressure of 0.001 to 20 Torr; and c) heating the reaction product of step b) at a temperature of 270 to 350° C. for 1 to 25 hours. The process of polyarylene sulfide resin further includes a step of heating the polymerized product at a high temperature following the polymerization step, and uses the polymerization terminator in a suitable amount to control the molecular weight of polyarylene sulfide, thereby producing polyarylene sulfide with excellent thermal properties and luminosity.
    • 本发明涉及一种生产聚芳硫醚(PAS)和由其制备的PAS树脂的方法,更具体地说,涉及制备具有比常规PAS和由其制备的PAS树脂更好的热性能和发光度的聚芳硫醚的方法,包括步骤 a)熔融和混合包括固体硫,碘化芳基化合物和聚合终止剂的组合物; b)使步骤a)的熔融混合物聚合1至30小时,同时增加温度并将温度从180-250℃的初始反应条件和50至450托的压力降低至最终反应条件 温度为270〜350℃,压力为0.001〜20托; 和c)将步骤b)的反应产物在270至350℃的温度下加热1至25小时。 聚芳硫醚树脂的方法还包括在聚合步骤之后在高温下加热聚合产物的步骤,并且使用适当量的聚合终止剂来控制聚芳硫醚的分子量,由此制备具有优异热性质的聚芳硫醚 和亮度。
    • 4. 发明授权
    • Method for production of polyarylene sulfide resin with excellent luminosity and the polyarylene sulfide resin
    • 具有优异亮度的聚芳硫醚树脂的生产方法和聚芳硫醚树脂
    • US08492502B2
    • 2013-07-23
    • US12518243
    • 2008-01-04
    • Young-Rok LeeII-Hoon ChaJun-Sang Cho
    • Young-Rok LeeII-Hoon ChaJun-Sang Cho
    • C08G75/00
    • C08G75/0263C08G75/0209C08G75/0231C08G75/0281C08L81/02C08L81/00
    • The present invention relates to a process of producing polyarylene sulfide (PAS) and PAS resin produced therefrom, and more specifically, to a process of preparing polyarylene sulfide with better thermal properties and luminosity than conventional PAS and the PAS resin produced therefrom, including the steps of: a) melting and mixing a composition including solid sulfur, iodinated aryl compounds, and a polymerization terminator; b) polymerizing the molten mixture of step a) for 1 to 30 hours while increasing the temperature and decreasing the pressure from initial reaction conditions of a temperature of 180 to 250° C. and a pressure of 50 to 450 Torr to final reaction conditions of a temperature of 270 to 350° C. and a pressure of 0.001 to 20 Torr; and c) heating the reaction product of step b) at a temperature of 270 to 350° C. for 1 to 25 hours. The process of polyarylene sulfide resin further includes a step of heating the polymerized product at a high temperature following the polymerization step, and uses the polymerization terminator in a suitable amount to control the molecular weight of polyarylene sulfide, thereby producing polyarylene sulfide with excellent thermal properties and luminosity.
    • 本发明涉及一种生产聚芳硫醚(PAS)和由其制备的PAS树脂的方法,更具体地说,涉及制备具有比常规PAS和由其制备的PAS树脂更好的热性能和发光度的聚芳硫醚的方法,包括步骤 a)熔融和混合包括固体硫,碘化芳基化合物和聚合终止剂的组合物; b)使步骤a)的熔融混合物聚合1至30小时,同时增加温度并将温度从180-250℃的初始反应条件和50至450托的压力降低至最终反应条件 温度为270〜350℃,压力为0.001〜20托; 和c)将步骤b)的反应产物在270至350℃的温度下加热1至25小时。 聚芳硫醚树脂的方法还包括在聚合步骤之后在高温下加热聚合产物的步骤,并且使用适当量的聚合终止剂来控制聚芳硫醚的分子量,由此制备具有优异热性质的聚芳硫醚 和亮度。