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1. 发明授权

US06429330B1 Process for producing carbocyclic nitriles 有权
标题翻译：制备碳环腈的方法
公开(公告)号：US06429330B1
公开(公告)日：2002-08-06
申请号：US09613632
申请日：2000-07-11
申请人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
发明人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
IPC分类号： C07C25328
CPC分类号： C07C253/28 , C07D213/85 , C07C255/51
摘要： A carbocyclic or heterocyclic compound, ammonia and an oxygen-containing gas are subjected to fluid catalytic reaction in vapor phase in the presence of a catalyst containing alkali metal to produce an aromatic or heterocyclic nitrile. The use of the catalyst containing a specific amount of alkali metal enables the stable production of the aromatic or heterocyclic nitrile in high yields with little change with time even when water is present in the reaction system. The use of the catalyst containing the alkali metal also enables the recycle and reuse of unreacted ammonia which is usually accompanied by water, thereby reducing production costs.
摘要翻译：在含有碱金属的催化剂存在下，将碳环或杂环化合物，氨和含氧气体在气相中进行流化催化反应以产生芳族或杂环腈。使用含有特定量的碱金属的催化剂能够以高产率稳定地生产芳族或杂环腈，即使在反应体系中存在水时也几乎不改变。使用含有碱金属的催化剂也能够再循环和再利用通常伴有水的未反应的氨，从而降低生产成本。

2. 发明授权

US07179945B2 High-selective production method of di(aminomethyl)-substituted aromatic compound 有权
标题翻译：二（氨基甲基）取代芳族化合物的高选择性生产方法
公开(公告)号：US07179945B2
公开(公告)日：2007-02-20
申请号：US10781884
申请日：2004-02-20
申请人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yoshiaki Yamamoto
发明人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yoshiaki Yamamoto
IPC分类号： C07C211/00
CPC分类号： C07C253/30 , C07C209/48 , C07C211/27 , C07C211/30 , C07C255/58
摘要： A di(aminomethyl)-substituted aromatic compound is produced by a two-stage hydrogenation. In the first stage, an aromatic dinitrile is hydrogenated into a cyano(aminomethyl)-substituted aromatic compound in the presence of a Pd-containing catalyst. The resultant cyano(aminomethyl)-substituted aromatic compound is then hydrogenated in the second stage into the target di(aminomethyl)-substituted aromatic compound in the presence of a Ni- and/or Co-containing catalyst. By the above method, the di(aminomethyl)-substituted aromatic compound is produced in a high selectivity and a sufficiently high yield without reducing the catalyst life.
摘要翻译：二（氨基甲基）取代的芳族化合物是通过两阶段氢化制备的。在第一阶段中，在含Pd催化剂的存在下，将芳族二腈氢化为氰基（氨基甲基）取代的芳族化合物。然后将所得的氰基（氨基甲基）取代的芳香族化合物在Ni-和/或含Co催化剂存在下，在第二阶段中氢化成目标二（氨基甲基） - 取代的芳族化合物。通过上述方法，在不降低催化剂寿命的情况下以高选择性和足够高的产率制备二（氨基甲基）取代的芳族化合物。

3. 发明授权

US06541632B2 Process for producing heterocyclic nitriles 有权
标题翻译：制备杂环腈的方法
公开(公告)号：US06541632B2
公开(公告)日：2003-04-01
申请号：US10173619
申请日：2002-06-19
申请人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
发明人： Hideaki Ogino , Takashi Okawa , Shuji Ebata , Yoshinori Kanamori
IPC分类号： C07D24124
CPC分类号： C07C253/28 , C07D213/85 , C07C255/51
摘要： A carbocyclic or heterocyclic compound, ammonia and an oxygen-containing gas are subjected to fluid catalytic reaction in vapor phase in the presence of a catalyst containing alkali metal to produce an aromatic or heterocyclic nitrile. The use of the catalyst containing a specific amount of alkali metal enables the stable production of the aromatic or heterocyclic nitrile in high yields with little change with time even when water is present in the reaction system. The use of the catalyst containing the alkali metal also enables the recycle and reuse of unreacted ammonia which is usually accompanied by water, thereby reducing production costs.
摘要翻译：在含有碱金属的催化剂存在下，将碳环或杂环化合物，氨和含氧气体在气相中进行流化催化反应以产生芳族或杂环腈。使用含有特定量的碱金属的催化剂能够以高产率稳定地生产芳族或杂环腈，即使在反应体系中存在水时也几乎不改变。使用含有碱金属的催化剂也能够再循环和再利用通常伴有水的未反应的氨，从而降低生产成本。

4. 发明申请

US20050277790A1 High-selective production method of di(aminomethyl)-substituted aromatic compound 有权
标题翻译：二（氨基甲基）取代芳族化合物的高选择性生产方法
公开(公告)号：US20050277790A1
公开(公告)日：2005-12-15
申请号：US10781884
申请日：2004-02-20
申请人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yoshiaki Yamamoto
发明人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yoshiaki Yamamoto
IPC分类号： C07C209/48 , C07C211/27 , C07C211/30 , C07C253/30 , C07C255/58 , C07C211/00
CPC分类号： C07C253/30 , C07C209/48 , C07C211/27 , C07C211/30 , C07C255/58
摘要： A di(aminomethyl)-substituted aromatic compound is produced by a two-stage hydrogenation. In the first stage, an aromatic dinitrile is hydrogenated into a cyano(aminomethyl)-substituted aromatic compound in the presence of a Pd-containing catalyst. The resultant cyano(aminomethyl)-substituted aromatic compound is then hydrogenated in the second stage into the target di(aminomethyl)-substituted aromatic compound in the presence of a Ni- and/or Co-containing catalyst. By the above method, the di(aminomethyl)-substituted aromatic compound is produced in a high selectivity and a sufficiently high yield without reducing the catalyst life.
摘要翻译：二（氨基甲基）取代的芳族化合物是通过两阶段氢化制备的。在第一阶段中，在含Pd催化剂的存在下，将芳族二腈氢化为氰基（氨基甲基）取代的芳族化合物。然后将所得的氰基（氨基甲基）取代的芳香族化合物在Ni-和/或含Co催化剂存在下，在第二阶段中氢化成目标二（氨基甲基） - 取代的芳族化合物。通过上述方法，在不降低催化剂寿命的情况下以高选择性和足够高的产率制备二（氨基甲基）取代的芳族化合物。

5. 发明授权

US07468342B2 Catalysts and process for producing aromatic amines 有权
标题翻译：催化剂和生产芳香胺的方法
公开(公告)号：US07468342B2
公开(公告)日：2008-12-23
申请号：US10139214
申请日：2002-05-07
申请人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yasushi Hiramatsu
发明人： Yoshinori Kanamori , Shuji Ebata , Kengo Tsukahara , Yasushi Hiramatsu
IPC分类号： B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： B01J21/066 , B01J21/06 , B01J23/70 , B01J23/755 , B01J23/868 , B01J37/0009 , B01J37/03 , C07C209/48 , C07C211/27
摘要： As catalysts for producing aromatic amines by hydrogenating aromatic nitrites, there are disclosed (1) the catalyst comprising a metal catalyst component comprising Ni and/or Co and a specific amount of zirconia as a carrier component, which is prepared by drying, calcining and forming a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; and (2) the catalyst comprising the metal catalyst component and the carrier component, which is prepared by filtering a precipitate produced by adding an aqueous solution containing soluble salts of the metal catalyst component and the carrier component to an aqueous alkali solution; forming the precipitate without drying to obtain a formed product; and subjecting the formed product to drying and then calcining. These catalysts are free from breaking owing to rapid generation of methane and evaporation of liquid ammonia by hydrogenolysis of high boiling by-products of the hydrogenation when reactivated after deactivation of the catalyst, which allows the long-term use of the catalysts.
摘要翻译：作为用于通过氢化芳族亚硝酸盐生产芳族胺的催化剂，公开了（1）催化剂，其包含由Ni和/或Co组成的金属催化剂组分和特定量的氧化锆作为载体组分，其通过干燥，煅烧和形成通过将含有金属催化剂组分和载体组分的可溶性盐的水溶液加入到碱性水溶液中而产生的沉淀物; 和（2）包含金属催化剂组分和载体组分的催化剂，其通过将含有金属催化剂组分和载体组分的可溶性盐的水溶液过滤到碱水溶液中制备的沉淀物; 在不干燥的状态下形成沉淀物，得到成形品; 对成形体进行干燥，然后煅烧。由于催化剂失活后再活化时氢化的高沸点副产物的氢解，液体氨的迅速产生和液氨的蒸发，这些催化剂不会破裂，这允许长期使用催化剂。

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