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    • 1. 发明授权
    • Lithium ion secondary battery
    • 锂离子二次电池
    • US08900757B2
    • 2014-12-02
    • US13397790
    • 2012-02-16
    • Ikuo OzakiYoshimasa KoishikawaYoshihisa OkudaYuki Takei
    • Ikuo OzakiYoshimasa KoishikawaYoshihisa OkudaYuki Takei
    • H01M4/24H01M4/505H01M4/525H01M10/052H01M4/02H01M4/62
    • H01M10/052H01M4/02H01M4/505H01M4/525H01M4/621H01M2004/021Y02E60/122
    • A positive electrode capable of achieving both of high volumetric energy density and high volumetric power density and a lithium ion secondary battery using the same are provided. A lithium ion secondary battery includes a positive electrode including a current collector with a positive active material mixture layer applied on both faces thereof, the positive active material mixture layer including active material particles, conductive additive particles and a binder. The active material particles used have a value D of an average particle diameter D50 of the active material particles in the range from 1 to 10 μm. The ratio b/a of the volume fraction b of the vacancy volume in the positive active material mixture layer to the volume fraction a of the active material particles in the positive active material mixture layer is in the range of −0.01D+0.57≦b/a≦−0.01D+0.97.
    • 提供能够实现高体积能量密度和高体积功率密度的正极和使用其的锂离子二次电池。 锂离子二次电池包括具有集电体的正极,所述集电体具有施加在其两个面上的正极活性物质混合层,所述正极活性物质混合物层包含活性物质粒子,导电性添加剂粒子和粘合剂。 使用的活性物质粒子的活性物质粒子的平均粒径D50的值D为1〜10μm。 正极活性物质混合层中的活性物质粒子的体积分数b与正极活性物质混合层中的活性物质粒子的体积分数a的体积分数b的比b / a为-0.01D + 0.57< b / a≦̸ -0.01D + 0.97。
    • 2. 发明申请
    • NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY
    • 非水电解质二次电池
    • US20130130114A1
    • 2013-05-23
    • US13813309
    • 2010-07-30
    • Yusuke OhnoYoshihisa Okuda
    • Yusuke OhnoYoshihisa Okuda
    • H01M4/583
    • H01M4/583C04B35/532C04B2235/425H01M4/0404H01M4/366H01M4/587H01M4/625H01M10/0525
    • A non-aqueous electrolyte secondary battery comprising amorphous carbon as a main agent of a negative electrode active material and having high energy density, less degradation of capacity during storage in a charged state, and excellent in cycle life characteristics is provided.The negative electrode active material comprises a mixture of easily graphitizable carbon, less graphitizable carbon, and graphite, the mixture comprising composite particles having a structure where less graphitizable carbon is deposited to the surface of particles of easily graphitizable carbon and graphite. Particularly, it is preferred that the ratio of the less graphitizable carbon content relative to the total weight of the mixture is from 0.5 to 7%, the ratio of graphite content relative to the total weight of the mixture is from 5 to 20% in which the less graphitizable carbon is present at the surface of particles of easily graphitizable carbon by a mechanochemical treatment.
    • 提供一种非水电解质二次电池,其包含无定形碳作为负极活性物质的主要成分并且具有高能量密度,在充电状态下储存期间的容量降低较少,并且具有优异的循环寿命特性。 负极活性材料包括容易石墨化的碳,较少可石墨化的碳和石墨的混合物,该混合物包含具有较少可石墨化的碳沉积到容易石墨化的碳和石墨的颗粒表面的结构的复合颗粒。 特别优选的是,相对于混合物的总重量,石墨石墨含量相对于混合物总重量的比例为0.5〜7%,石墨含量相对于混合物总重量的比例为5〜20%,其中 通过机械化学处理,易于石墨化的碳的颗粒的表面存在较少石墨化的碳。