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1. 发明授权

US5424008A Coating solutions for forming transparent conductive ceramic coatings, substrates coated with transparent conductive ceramic coatings and process for preparing same, and uses of substrates coated with transparent conductive ceramic coatings 失效
标题翻译：用于形成透明导电陶瓷涂层的涂料溶液，涂覆有透明导电陶瓷涂层的基材及其制备方法，以及涂覆有透明导电陶瓷涂层的基材的使用
公开(公告)号：US5424008A
公开(公告)日：1995-06-13
申请号：US310170
申请日：1994-09-21
申请人： Toshiharu Hirai , Yoneji Abe , Michio Komatsu
发明人： Toshiharu Hirai , Yoneji Abe , Michio Komatsu
IPC分类号： C03C17/25 , C09D5/24 , C23C18/12 , H01B1/20 , B32B17/00 , H01B1/22
CPC分类号： C09D5/24 , C03C17/25 , C23C18/1208 , C23C18/1245 , C23C18/14 , C03C2217/23 , C03C2218/11 , Y10T428/31504
摘要： In accordance with the present invention, there are provided coating solutions for forming transparent conductive ceramic coatings, said coating solutions being homogeneous solutions or dispersions of acetylacetonate chelate compound, conductive substances and, if necessary, silicon compound and/or alkoxides of metals other than silicon in mixtures of water and organic solvents, and substrates having thereon transparent conductive ceramic coatings formed from said coating solutions and uses thereof.
摘要翻译：根据本发明，提供了用于形成透明导电陶瓷涂层的涂布溶液，所述涂布溶液是乙酰丙酮化合物螯合化合物的均匀溶液或分散体，导电物质，如果需要，还有硅以外的金属的硅化合物和/或醇盐在水和有机溶剂的混合物中，以及其上具有由所述涂布溶液形成的透明导电陶瓷涂层的基材及其用途。

2. 发明授权

US5078915A Coating liquids for forming conductive coatings 失效
标题翻译：涂层液形成导电涂料
公开(公告)号：US5078915A
公开(公告)日：1992-01-07
申请号：US298607
申请日：1988-10-11
申请人： Goro Sato , Michio Komatsu , Toshiharu Hirai , Yoneji Abe , Keiichi Mihara
发明人： Goro Sato , Michio Komatsu , Toshiharu Hirai , Yoneji Abe , Keiichi Mihara
IPC分类号： B32B15/00 , C03C17/23 , C03C17/25
CPC分类号： C03C17/25 , C03C17/23 , C03C2217/23 , C03C2218/11
摘要： In accordance with the present invention, there are provided coating liquids for forming conductive coatings, which comprise (i) a zirconium oxysalt, (ii) a conductive substance and, if necessary, (iii) at least one member selected from non-sedimentary silica dispersion and silicon alkoxide or its derivative. The coating liquids, when coated on substrates, form thereon transparent conductive coatings which are excellent in transparency, scratch resistance, permanence properties and adhesion to the substrates and, moreover, excellent in antistatic effect. In particular, when the coating liquids for forming conductive coatings mentioned above are coated by the spray method on appropriate substrates followed by drying and/or heating, there are obtained face-plates for display devices, which have excellent regular reflection reducing effect (non-glare) and antistatic effect.
摘要翻译： PCT No.PCT / JP88 / 00122 Sec。 371日期：1988年10月11日 102（e）日期1988年10月11日PCT提交1988年2月9日PCT公布。公开号WO88 / 06331 日本1988年8月25日。根据本发明，提供了用于形成导电涂层的涂料液体，其包含（i）锆氧基钾，（ii）导电物质，如果需要，（iii）至少一种成员选自非沉积二氧化硅分散体和硅烷醇盐或其衍生物。涂布液在基材上涂布时，在其上形成透明性，耐擦伤性，耐久性和对基材的粘合性优异的抗静电效果的透明导电性涂料。特别地，当将用于形成上述导电涂层的涂布液通过喷涂方法涂覆在适当的基材上，然后进行干燥和/或加热时，获得具有优异的正常反射减少效果的显示装置用面板，眩光）和抗静电效果。

3. 发明授权

US5270072A Coating liquids for forming conductive coatings 失效
标题翻译：用于形成导电涂层的涂料液体
公开(公告)号：US5270072A
公开(公告)日：1993-12-14
申请号：US746403
申请日：1991-08-16
申请人： Goro Sato , Michio Komatsu , Toshiharu Hirai , Yoneji Abe , Keiichi Mihara
发明人： Goro Sato , Michio Komatsu , Toshiharu Hirai , Yoneji Abe , Keiichi Mihara
IPC分类号： C03C17/23 , C03C17/25 , B05D5/12
CPC分类号： C03C17/25 , C03C17/23 , C03C2217/23 , C03C2218/11
摘要： In accordance with the present invention, there are provided coating liquids for forming conductive coatings, which comprise (i) a zirconium oxysalt, (ii) a conductive substance and, if necessary, (iii) at least one member selected from non-sedimentary silica dispersion and silicon alkoxide or its derivative. The coating liquids, when coated on substrates, form thereon transparent conductive coatings which are excellent in transparency, scratch resistance, permanence properties and adhesion to the substrates and, moreover, excellent in antistatic effect. In particular, when the coating liquids for forming conductive coatings mentioned above are coated by the spray method on appropriate substrates followed by drying and/or heating, there are obtained face plates for display devices, which have excellent regular reflection reducing effect (non-glare) and antistatic effect.
摘要翻译：根据本发明，提供了用于形成导电涂层的涂布液，其包括（i）锆氧化锡，（ii）导电物质，如果需要，（iii）至少一种选自非沉积二氧化硅分散体和烷氧基硅烷或其衍生物。涂布液在基材上涂布时，在其上形成透明性，耐擦伤性，耐久性和对基材的粘合性优异的抗静电效果的透明导电性涂料。特别地，当用上述形成导电涂层的涂布液通过喷涂方法在适当的基材上进行干燥和/或加热涂覆时，得到具有优异的均匀反射减少效果（非眩光）的显示装置用面板）和抗静电效果。

4. 发明授权

US5492762A Conductive substrate and display device provided with transparent conductive substrate 失效
标题翻译：具有透明导电性基板的导电性基板和显示装置
公开(公告)号：US5492762A
公开(公告)日：1996-02-20
申请号：US315223
申请日：1994-09-29
申请人： Toshiharu Hirai , Michio Komatsu , Akira Nakashima , Yoneji Abe , Yukihiro Iwasaki
发明人： Toshiharu Hirai , Michio Komatsu , Akira Nakashima , Yoneji Abe , Yukihiro Iwasaki
IPC分类号： B05D3/02 , B05D3/04 , B05D3/06 , C03C17/00 , C09D5/24 , G02F1/1343 , H01B1/20 , H01B1/22 , H01B1/24 , H05K1/09 , B32B9/04 , B32B17/00
CPC分类号： H01B1/24 , B05D3/046 , B05D3/067 , C03C17/007 , C03C17/009 , C09D5/24 , H01B1/20 , H01B1/22 , B05D3/0254 , C03C2217/45 , C03C2217/475 , C03C2217/476 , G02F1/13439 , H05K1/095 , Y10T428/31612 , Y10T428/31663
摘要： Conductive substrate having on their surface a coating formed from a coating solution for forming a transparent conductive coating prepared by dispersion of dissolving in water and/or organic solvent such conductive particles as having (a) an average particle diameter of not more than 500 .ANG., wherein (b) an amount of particles having a particle diameter of not more than 600 .ANG. is more than 60% by weight, (c) an amount of particles having a particle diameter of not more than 100 .ANG. is more than 5% by weight and (d) an amount of particles having a particle diameter of more than 1000 .ANG. is not more than 15% by weight, and a matrix comprising a silica polymer having (A) an average degree of polymerization of 1,500-10,000, and (B) an amount of the polymer having a degree of polymerization of not more than 3,000 being not more than 50% by weight, and (C) an amount of the polymer having a degree of polymerization of more than 10,000 being not more than 20% by weight, are excellent in adhesion and surface smoothness and also excellent in durability and transparency. Display devices provided with the above-mentioned transparent conductive substrates as the display panel are excellent in resolving power, and give constantly clear and sharp images.
摘要翻译：导电基材在其表面上具有由用于形成透明导电涂层的涂布溶液形成的涂层，该透明导电涂层通过溶解在水和/或有机溶剂中而形成，例如（a）平均粒径不大于500的导电颗粒，其中（b）粒径不大于600的颗粒的量大于60wt％，（c）粒径不大于100的颗粒的量大于5wt％和（d）粒径大于1000的颗粒的量不超过15重量％，包含（A）平均聚合度为1,500〜10,000的二氧化硅聚合物的基体和（B ）聚合度不大于3,000的聚合物的量不超过50重量％，（C）聚合度大于10,000的聚合物的量不超过20％，其量重量，粘合性和表面平滑性优异，耐久性和透明性也优异。设置有作为显示面板的上述透明导电基板的显示装置具有优异的分辨率，并且给出不断清晰和清晰的图像。

5. 发明授权

US5273828A Coating liquids for forming conductive coatings 失效
标题翻译：用于形成导电涂层的涂料液体
公开(公告)号：US5273828A
公开(公告)日：1993-12-28
申请号：US746402
申请日：1991-08-16
申请人： Goro Sato , Michio Komatsu , Toshiharu Hirai , Yoneji Abe , Keiichi Mihara
发明人： Goro Sato , Michio Komatsu , Toshiharu Hirai , Yoneji Abe , Keiichi Mihara
IPC分类号： B32B15/00 , C03C17/23 , C03C17/25
CPC分类号： C03C17/25 , C03C17/23 , C03C2217/23 , C03C2218/11
摘要： In accordance with the present invention, there are provided coating liquids for forming conductive coatings, which comprise (i) a zirconium oxysalt, (ii) a conductive substance and, if necessary, (iii) at least one member selected from non-sedimentary silica dispersion and silicon alkoxide or its derivative. The coating liquids, when coated on substrates, form thereon transparent conductive coatings which are excellent in transparency, scratch resistance, permanence properties and adhesion to the substrates and, moreover, excellent in antistatic effect. In particular, when the coating liquids for forming conductive coatings mentioned above are coated by the spray method on appropriate substrates followed by drying and/or heating, there are obtained face-plates for display devices, which have excellent regular reflection reducing effect (non-glare) and antistatic effect.
摘要翻译：根据本发明，提供了用于形成导电涂层的涂布液，其包括（i）锆氧化锡，（ii）导电物质，如果需要，（iii）至少一种选自非沉积二氧化硅分散体和烷氧基硅烷或其衍生物。涂布液在基材上涂布时，在其上形成透明性，耐擦伤性，耐久性和对基材的粘合性优异的抗静电效果的透明导电性涂料。特别地，当将用于形成上述导电涂层的涂布液通过喷涂方法涂覆在适当的基材上，然后进行干燥和/或加热时，获得具有优异的正常反射减少效果的显示装置用面板，眩光）和抗静电效果。

6. 发明授权

US5013607A Transparent conductive ceramic-coated substrate processes for preparing same and uses thereof 失效
标题翻译：透明导电陶瓷涂布基板的制备方法及其用途
公开(公告)号：US5013607A
公开(公告)日：1991-05-07
申请号：US391604
申请日：1989-06-08
申请人： Goro Sato , Michio Komatsu , Toshiharu Hirai , Yoneji Abe , Noboru Senjyuu
发明人： Goro Sato , Michio Komatsu , Toshiharu Hirai , Yoneji Abe , Noboru Senjyuu
IPC分类号： C03C17/25 , C09D5/24
CPC分类号： C03C17/25 , C09D5/24 , C03C2217/23 , C03C2218/11 , C03C2218/113 , Y10T428/31612 , Y10T428/31663
摘要： Disclosed are transparent conductive ceramiccoated substrates having a surface resistance of 10.sup.3 -10.sup.11 .OMEGA./.quadrature., a total light transmission of at least 85% and a haze of less than 10%, said coated substrates being prepared by coating on the substrate a water organic solvent mixture type coating liquid containing dialkoxy-bisacetylacetonato zirconium, a partial hydrolysate of silicon alkoxide and a conductive substance, processes for preparing said coated substrates, and display and copy machine using said coated substrates.
摘要翻译： PCT No.PCT / JP88 / 00793 Sec。 371日期：1989年6月8日 102（e）日期1989年6月8日PCT PCT 1988年8月10日PCT公布。公开号WO89 / 03114 日期为1989年4月6日。公开的是透明导电陶瓷涂层基材，其表面电阻为103-1011欧米茄/平方厘米，总透光率至少为85％，雾度小于10％，所述涂覆的基材通过涂布在基材上，含有二烷氧基 - 双乙酰丙酮酸锆的部分水解有机溶剂混合物型涂料液，硅氧烷和导电物质的部分水解产物，制备所述涂覆的基材的方法，以及使用所述涂覆的基材的显示和复印机。

7. 发明授权

US5382383A Coating solutions for forming transparent conductive ceramic coatings, substrates coated with transparent conductive ceramic coatings and process for preparing same, and uses of substrates coated with transparent conductive ceramic coatings 失效
标题翻译：用于形成透明导电陶瓷涂层的涂料溶液，涂覆有透明导电陶瓷涂层的基材及其制备方法，以及涂覆有透明导电陶瓷涂层的基材的使用
公开(公告)号：US5382383A
公开(公告)日：1995-01-17
申请号：US474117
申请日：1990-04-24
申请人： Toshiharu Hirai , Yoneji Abe , Michio Komatsu
发明人： Toshiharu Hirai , Yoneji Abe , Michio Komatsu
IPC分类号： C03C17/25 , C09D5/24 , C23C18/12 , H01B1/00 , H01B1/24
CPC分类号： C09D5/24 , C03C17/25 , C23C18/1208 , C23C18/1245 , C23C18/14 , C03C2217/23 , C03C2218/11 , Y10T428/31504
摘要： In accordance with the present invention, there are provided coating solutions for forming transparent conductive ceramic coatings, said coating solutions being homogeneous solutions or dispersions of acetylacetonate chelate compound, conductive substances and, if necessary, silicon compound and/or alkoxides of metals other than silicon in mixtures of water and organic solvents, and substrates having thereon transparent conductive ceramic coatings formed from said coating solutions and uses thereof.
摘要翻译： PCT No.PCT / JP89 / 00866 Sec。 371日期：1990年04月24日 102（e）日期1990年4月24日PCT 1989年8月24日PCT公布。 WO90 / 02157 PCT出版物 1990年3月8日。根据本发明，提供了用于形成透明导电陶瓷涂层的涂料溶液，所述涂料溶液是乙酰丙酮化合物螯合化合物的均匀溶液或分散体，导电物质，如果需要，硅化合物和/ 或水与有机溶剂的混合物中的硅以外的金属的醇盐，以及其上具有由所述涂布溶液形成的透明导电陶瓷涂层的基材及其用途。

8. 发明授权

US5376308A Coating solution for forming transparent conductive coating and process for preparing same 失效
标题翻译：用于形成透明导电涂层的涂布溶液及其制备方法
公开(公告)号：US5376308A
公开(公告)日：1994-12-27
申请号：US910300
申请日：1992-07-20
申请人： Toshiharu Hirai , Michio Komatsu , Akira Nakashima , Yoneji Abe , Yukihiro Iwasaki
发明人： Toshiharu Hirai , Michio Komatsu , Akira Nakashima , Yoneji Abe , Yukihiro Iwasaki
IPC分类号： B05D3/02 , B05D3/04 , B05D3/06 , C03C17/00 , C09D5/24 , G02F1/1343 , H01B1/20 , H01B1/22 , H01B1/24 , H05K1/09 , H01B1/02 , C08K3/20 , H01B1/06
CPC分类号： H01B1/24 , B05D3/046 , B05D3/067 , C03C17/007 , C03C17/009 , C09D5/24 , H01B1/20 , H01B1/22 , B05D3/0254 , C03C2217/45 , C03C2217/475 , C03C2217/476 , G02F1/13439 , H05K1/095 , Y10T428/31612 , Y10T428/31663
摘要： Conductive substrate having on their surface a coating formed from a coating solution for forming a transparent conductive coating prepared by dispersion of dissolving in water and/or organic solvent such conductive particles as having (a) an average particle diameter of not more than 500 .ANG., wherein (b) an amount of particles having a particle diameter of not more than 600 .ANG. is more than 60% by weight, (c) an amount of particles having a particle diameter of not more than 100 .ANG. is more than 5% by weight and (d) an amount of particles having a particle diameter of more than 1000 .ANG. is not more than 15% by weight, and a matrix comprising a silica polymer having (A) an average degree of polymerization of 1,500-10,000, and (B) an amount of the polymer having a degree of polymerization of not more than 3,000 being not more than 50% by weight, and (C) an amount of the polymer having a degree of polymerization of more than 10,000 being not more than 20% by weight, are excellent in adhesion and surface smoothness and also excellent in durability and transparency. Display devices provided with the above-mentioned transparent conductive substrates as the display panel are excellent in resolving power, and give constantly clear and sharp images.
摘要翻译： PCT No.PCT / JP91 / 01603 Sec。 371日期：1992年7月20日 102（e）日期1992年7月20日PCT 1991年11月21日PCT PCT。出版物WO92 / 09665 日期：1992年6月11日。导电基材在其表面上具有由用于形成透明导电涂层的涂布液形成的涂层，所述涂料溶液通过将溶解在水和/或有机溶剂中的分散体制备，所述导电颗粒具有（a）平均粒径不超过500，其中（b）粒径不大于600的颗粒的量大于60wt％，（c）粒径不大于100的颗粒数量ANGSTROM 大于5重量％，（d）粒径大于1000的颗粒的量不超过15重量％，并且包含二氧化硅聚合物的基质，其具有（A）平均聚合度（B）聚合度不大于3,000的聚合物的量不大于50重量％，（C）聚合度大于10,000的聚合物的量不是更多的t 韩20重量％，粘合性和表面平滑性优异，耐久性和透明性优异。设置有作为显示面板的上述透明导电基板的显示装置具有优异的分辨率，并且给出不断清晰和清晰的图像。

9. 发明授权

US5256484A Substrate having a transparent coating thereon 失效
标题翻译：基材在其上具有透明涂层
公开(公告)号：US5256484A
公开(公告)日：1993-10-26
申请号：US746406
申请日：1991-08-16
申请人： Goro Sato , Michio Komatsu , Toshiharu Hirai , Yoneji Abe , Keiichi Mihara
发明人： Goro Sato , Michio Komatsu , Toshiharu Hirai , Yoneji Abe , Keiichi Mihara
IPC分类号： C03C17/23 , C03C17/25 , B32B17/06
CPC分类号： C03C17/23 , C03C17/25 , C03C2217/23 , C03C2218/11 , Y10T428/31598 , Y10T428/31609
摘要： In accordance with the present invention, there are provided coating liquids for forming conductive coatings, which comprise (i) a zirconium oxysalt, (ii) a conductive substance and, if necessary, (iii) at least one member selected from non-sedimentary silica dispersion and silicon alkoxide or its derivative. The coating liquids, when coated on substrate, form thereon transparent conductive coatings which are excellent in transparency, scratch resistance, permanence properties and adhesion to the substrates and, moreover, excellent in antistatic effect. In particular, when the coating liquids for forming conductive coatings mentioned above are coated by the spray method on appropriate substrates followed by drying and/or heating, there are obtained face-plates for display devices, which have excellent regular reflection reducing effect (non-glare) and antistatic effect.
摘要翻译：根据本发明，提供了用于形成导电涂层的涂布液，其包括（i）锆氧化锡，（ii）导电物质，如果需要，（iii）至少一种选自非沉积二氧化硅分散体和烷氧基硅烷或其衍生物。涂布液在基材上涂布时，在透明性，耐刮擦性，耐久性和对基材的粘附性上具有优异的抗静电效果的透明导电性涂料。特别地，当将用于形成上述导电涂层的涂布液通过喷涂方法涂覆在适当的基材上，然后进行干燥和/或加热时，获得具有优异的正常反射减少效果的显示装置用面板，眩光）和抗静电效果。

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