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1. 发明授权

US5556913A Cationic electrocoating composition 失效
标题翻译：阳离子电涂组合物
公开(公告)号：US5556913A
公开(公告)日：1996-09-17
申请号：US176508
申请日：1994-01-03
申请人： Kenshiro Tobinaga , Hiroyuki Sakamoto , Shinsuke Shirakawa , Satoshi Urano , Yasuyuki Tsuchiya
发明人： Kenshiro Tobinaga , Hiroyuki Sakamoto , Shinsuke Shirakawa , Satoshi Urano , Yasuyuki Tsuchiya
IPC分类号： C09D5/44 , C08J3/00 , C08K3/20 , C08L39/00
CPC分类号： C09D5/4473 , C09D5/4411 , Y10S524/901
摘要： The present invention provides a cationic electrocoating composition which cures at the preferred curing temperature range and provides superior curing properties and cured film properties. The cationic electrocoating composition of the present invention comprises a resinous component and an aqueous medium, wherein the resinous component is composed of one or more polymers and has as a whole an active hydrogen containing group, a cationic group and a substituted group and at least one of the polymers comprises a vinyl polymer which has 5 to 1,000 substituted acylamide groups.
摘要翻译：本发明提供一种阳离子电涂组合物，其在优选的固化温度范围内固化并提供优异的固化性能和固化膜性质。本发明的阳离子电泳涂料组合物包含树脂组分和水性介质，其中树脂组分由一种或多种聚合物组成，并且整体上含有活性氢基团，阳离子基团和取代基团以及至少一种的聚合物包含具有5至1,000个取代的酰基酰胺基团的乙烯基聚合物。

2. 发明授权

US5200461A Anionic microgel particle dispersion and a coating composition therefrom 失效
标题翻译：阴离子微凝胶颗粒分散体及其涂料组合物
公开(公告)号：US5200461A
公开(公告)日：1993-04-06
申请号：US548187
申请日：1990-07-05
申请人： Yasuyuki Tsuchiya , Kenshiro Tobinaga
发明人： Yasuyuki Tsuchiya , Kenshiro Tobinaga
IPC分类号： C08J3/26 , C08L13/02 , C09D5/44
CPC分类号： C09D5/4488 , C08J3/26 , C08L13/02 , C09D5/4403 , C09D5/4453 , C09D5/4484 , Y10S524/901
摘要： Disclosed is a micro gel particle having an anionic charge for which it is electrodepositable by itself. The present invention provides a process for preparing an anionic micro gel particle dispersion comprising:emulsifying in an aqueous medium a resin composition comprising(A) 100 parts by weight of an anionic film-forming aqueous resin, and(B) 10 to 250 parts by weight of a thermosetting crosslinking agent which is self-crosslinked or crosslinked with said aqueous resin (A) in terms of condensation or addition reaction excepting the combination of an acrylic resin and an alcoxylated methylol melamine; parts by weight being based on the solid content of the resin composition, andheating the resultant emulsion to above a crosslinkable temperature of said crosslinking agent (B).
摘要翻译：公开了具有阴离子电荷的微凝胶颗粒，其自身可电沉积。本发明提供了一种制备阴离子微凝胶颗粒分散体的方法，包括：在水性介质中乳化树脂组合物，所述树脂组合物包含（A）100重量份阴离子成膜水性树脂，（B）10至250重量份除了丙烯酸树脂和羟丙基羟甲基三聚氰胺的组合之外，与所述水性树脂（A）自缩合或加成反应自交联或交联的热固性交联剂的重量; 重量份是基于树脂组合物的固体含量，并将所得乳液加热至高于所述交联剂（B）的可交联温度。

3. 发明授权

US5070120A Aqueous dispersion of cationic crosslinked resin particles from resin having at least two vinyl groups 失效
标题翻译：具有至少两个乙烯基团的树脂的阳离子交联树脂颗粒的水分散
公开(公告)号：US5070120A
公开(公告)日：1991-12-03
申请号：US376601
申请日：1989-07-07
申请人： Hiroyuki Sakamoto , Kenshiro Tobinaga , Yasuyuki Tsuchiya
发明人： Hiroyuki Sakamoto , Kenshiro Tobinaga , Yasuyuki Tsuchiya
IPC分类号： C08J3/24 , C08L19/00 , C08L63/10 , C09D5/44
CPC分类号： C08L19/006 , C08J3/248 , C08L63/10 , C09D5/443 , C09D5/4488 , Y10S525/902
摘要： The present invention provides a micro gel particle having a cationic charge, prepared by a radical polymerization. The micro gel particle is obtained in the form of an aqueous dispersion. The micro gel particle dispersion is prepared by dispersing or emulsifying in an aqueous medium (A) a cationic aqueous resin and (B) a resin having at least two polymerizable vinyl groups and a number average molecular weight of 400 to 20,000, followed by radical-polymerizing.

4. 发明授权

US4692483A Water-based paint composition 失效
标题翻译：水性油漆组成
公开(公告)号：US4692483A
公开(公告)日：1987-09-08
申请号：US855644
申请日：1986-04-25
申请人： Yasuyuki Tsuchiya , Hiroyuki Sakamoto
发明人： Yasuyuki Tsuchiya , Hiroyuki Sakamoto
IPC分类号： C09D151/04 , C09D191/00 , C08K3/20 , C08L37/00 , C08L83/00
CPC分类号： C09D191/005 , C09D151/04
摘要： A water-based paint composition comprising:(A) a reaction product prepared by reacting a butadiene-based polymer and/or a drying oil with an .alpha.,.beta.-unsaturated dicarboxylic acid anhydride followed by reacting with water, a primary monoalcohol or a dialkylamine; and(B) a modified epoxy resin with acrylic acid, methacrylic acid or unsaturated fatty acid, or a modified phenol resin with glycidyl acrylate or methacrylate, components (A) and(B) being dispersed in an aqueous medium containing a base.
摘要翻译：一种水性涂料组合物，其包含：（A）通过使丁二烯基聚合物和/或干性油与α，β-不饱和二羧酸酐反应而制备的反应产物，随后与水，一级一元醇或二烷基胺 ; 和（B）具有丙烯酸，甲基丙烯酸或不饱和脂肪酸的改性环氧树脂或具有丙烯酸酯或甲基丙烯酸缩水甘油酯的改性酚醛树脂，组分（A）和（B）分散在含有碱的水性介质中。

5. 发明授权

US4543406A Cathode-depositing electrodeposition coating composition 失效
标题翻译：阴极沉积电沉积涂料组合物
公开(公告)号：US4543406A
公开(公告)日：1985-09-24
申请号：US661177
申请日：1984-10-15
申请人： Yutaka Otsuki , Hiroyoshi Omika , Akio Oshima , Yoshihiko Araki , Yasuyuki Tsuchiya
发明人： Yutaka Otsuki , Hiroyoshi Omika , Akio Oshima , Yoshihiko Araki , Yasuyuki Tsuchiya
IPC分类号： C08G59/16 , C08G59/42 , C08G59/68 , C09D5/44 , C09D163/10 , C08L63/10 , C08L63/08
CPC分类号： C09D5/4473 , C08G59/1455 , C08G59/4292 , C08G59/68 , C09D163/10
摘要： A cathode-precipitating electrodeposition coating having excellent low-temperature curability, said composition consisting essentially of(A) 100 parts by weight of a high molecular compound having a molecular weight of 500 to 10,000 and containing carbon-carbon double bonds with an iodine value of 50 to 500 and 30 to 300 millimoles of amino groups per 100 g,(B) 10 to 200 parts by weight of a product of reaction of a diglycidyl compound represented by the general formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 represent a hydrogen atom or a methyl group and n represents an integer of from 0 to 20, with at least one organic acid component selected from the group consisting of(a) both an alpha,beta-unsaturated dicarboxylic acid and an alpha,beta-unsaturated monocarboxylic acid, (b) an unsaturated fatty acid containing at least 10% by weight of carbon-carbon conjugated double bonds and having a molecular weight of 100 to 350, and (c) an alpha,beta-unsaturated monocarboxylic acid, a 1,2-dicarboxylic acid anhydride, and a monoepoxy compound in this sequence, and(C) 0.005 to 1.0 part by weight as metal of a manganese salt of an organic acid or manganese dioxide.
摘要翻译：一种具有优异的低温固化性的阴极沉淀电沉积涂料，所述组合物基本上由（A）100重量份的分子量为500至10,000的高分子化合物组成，并且含有碳 - 碳双键，碘值为 50至500和30至300毫摩尔氨基/ 100g，（B）10至200重量份由通式（IMAGE）+ TR＆lt; IMAGE＆gt;表示的二缩水甘油基化合物的反应产物，其中R1，R2 并且R 3表示氢原子或甲基，n表示0至20的整数，其中至少一种有机酸组分选自（a）α，β-不饱和二羧酸和α， β-不饱和单羧酸，（b）含有至少10重量％碳 - 碳共轭双键且分子量为100至350的不饱和脂肪酸，和（c）α，β-不饱和一元羧酸， a 1， 2-二羧酸酐和单环氧化合物，（C）0.005〜1.0重量份的有机酸或二氧化锰的锰盐金属。

6. 发明授权

US4253930A Process for electrodepositing cationic compositions 失效
标题翻译：电沉积阳离子组合物的方法
公开(公告)号：US4253930A
公开(公告)日：1981-03-03
申请号：US57672
申请日：1979-07-16
申请人： Yasuyuki Tsuchiya , Akio Ichikawa , Kastuyoshi Yamasoe
发明人： Yasuyuki Tsuchiya , Akio Ichikawa , Kastuyoshi Yamasoe
IPC分类号： C09D5/44 , C25D13/06
CPC分类号： C09D5/4465 , C09D5/4403 , Y10T428/31605 , Y10T428/31678
摘要： A resin useful for electrocoating is obtained by reacting a reaction product of an epoxy group-containing compound with a carboxyl group-containing butadiene/acrylonitrile copolymer with simultaneously or separately an amino group-containing compound and a fully or a partially blocked isocyanato group-containing compound, and a composition comprising said resin or a composition comprising a reaction product obtained by reacting a reaction product of an epoxy group-containing compound and a carboxyl group-containing butadiene/acrylonitrile copolymer with an amino group-containing compound and a fully or partially blocked isocyanato group-containing compound is used for a cathodical electrodeposition.
摘要翻译：可用于电泳的树脂通过使含环氧基的化合物与含羧基的丁二烯/丙烯腈共聚物的反应产物同时或单独地含有氨基化合物和完全或部分封闭的含异氰酸酯基的化合物化合物和包含所述树脂的组合物或包含通过使含环氧基的化合物和含羧基的丁二烯/丙烯腈共聚物的反应产物与含氨基化合物反应而获得的反应产物的组合物，以及完全或部分封闭的含异氰酸酯基的化合物用于阴极电沉积。

7. 发明授权

US5705559A Crosslinked resin particles and production thereof 失效
标题翻译：交联树脂颗粒及其生产
公开(公告)号：US5705559A
公开(公告)日：1998-01-06
申请号：US391091
申请日：1995-02-21
申请人： Hiroyuki Sakamoto , Kenshiro Tobinaga , Yasuyuki Tsuchiya , Hisaichi Muramoto , Yusuke Ninomiya , Keizou Ishii , Shinichi Ishikura
发明人： Hiroyuki Sakamoto , Kenshiro Tobinaga , Yasuyuki Tsuchiya , Hisaichi Muramoto , Yusuke Ninomiya , Keizou Ishii , Shinichi Ishikura
IPC分类号： C08J3/12 , C08C19/36 , C08F8/46 , C08F20/32 , C08F220/32 , C08F290/00 , C08F299/00 , C08J3/24 , C08J3/26 , C09D5/44 , C08F8/00
CPC分类号： C08C19/36 , C08J3/26 , C09D5/4492
摘要： Disclosed is a process for preparing crosslinked resin particles which comprises dispersing a resin having both a water-dispersible function and a self-crosslinkable function in one molecule in an aqueous medium and then three-dimensionally crosslinking.
摘要翻译：公开了一种制备交联树脂颗粒的方法，其包括将具有水分散性功能和自交联功能的树脂分散在水性介质中，然后进行三维交联。

8. 发明授权

US5179184A Polymerizable cyclic urea derivatives and polymers having a pendant urea 失效
标题翻译：可聚合的环脲衍生物和具有侧链脲的聚合物
公开(公告)号：US5179184A
公开(公告)日：1993-01-12
申请号：US683543
申请日：1991-04-10
申请人： Noriyuki Tsuboniwa , Satoshi Urano , Hirotoshi Umemoto , Noriyuki Sakamoto , Kenshiro Tobinaga , Yasuyuki Tsuchiya
发明人： Noriyuki Tsuboniwa , Satoshi Urano , Hirotoshi Umemoto , Noriyuki Sakamoto , Kenshiro Tobinaga , Yasuyuki Tsuchiya
IPC分类号： C07D229/00 , C07D233/38 , C07D239/10 , C07D243/04 , C08F20/36 , C08F20/60
CPC分类号： C07D239/10 , C07D229/00 , C07D233/38 , C07D243/04 , C08F20/36 , C08F20/60
摘要： The present invention relates to polymerizable cyclic urea derivatives which can be thermally split to give rise to an isocyanate group; and to a polymer having cyclic urea pendant groups, which can be cured by heating without any additional curing agent such as an isocyanate blocked with a volatile lower molecular weight material, so that volatile material is not released in a thermal curing process.
摘要翻译：本发明涉及可热分解以产生异氰酸酯基团的聚合性环状脲衍生物; 以及具有环状脲侧基的聚合物，其可以通过加热而固化，而不需要任何额外的固化剂，例如用挥发性低分子量材料封端的异氰酸酯，使得挥发性物质在热固化过程中不释放。

9. 发明授权

US4642325A Cathode-depositing electrodeposition coating composition 失效
标题翻译：阴极沉积电沉积涂料组合物
公开(公告)号：US4642325A
公开(公告)日：1987-02-10
申请号：US720602
申请日：1985-04-05
申请人： Yutaka Otsuki , Hiroyoshi Omika , Akio Oshima , Yoshihiko Araki , Yasuyuki Tsuchiya
发明人： Yutaka Otsuki , Hiroyoshi Omika , Akio Oshima , Yoshihiko Araki , Yasuyuki Tsuchiya
IPC分类号： C09D5/44 , C08L63/10
CPC分类号： C09D5/4488
摘要： A cathode-depositing electrodeposition coating composition having excellent low-temperature curability comprising as essential ingredients(A) 100 parts by weight of a reaction product of (1) a high molecular compound having a molecular weight of 500 to 5,000 and containing carbon-carbon double bonds with an iodine number of 50 to 500 and 3 to 12% by weight of oxirane oxygen, and (2) 30 to 300 millimoles, per 100 g of the high molecular compound (1), of a specified amine compound,(B) 10 to 200 parts by weight of a reaction product of a specified diglycidyl compound with 1.9 to 2.1 moles, per molecule of the diglycidyl compound, of an alpha, beta-unsaturated carboxylic acid or an unsaturated fatty acid having a molecular weight of 100 to 350 and containing at least 10% by weight of a carbon-carbon double bond, or a mixture of both,(C) 0.5 to 10 parts by weight of a reaction product of a high molecular compound having a molecular weight of 500 to 5,000 and containing a carbon-carbon double bond with an iodine number of 50 to 500 and 40 to 400 millimoles, per 100 g of the high molecular compound, of a specified alpha, beta-unsaturated dicarboxylic acid and(D) 0.005 to 1.0 part by weight, as metal, of a water-soluble salt of an organic acid with a metal selected from manganese, cobalt, and copper.
摘要翻译：一种阴极沉积电沉积涂料组合物，其具有优异的低温固化性，其包含作为必要成分的（A）100重量份的（1）分子量为500-5000的高分子化合物和含有碳 - 碳双键的反应产物（A）的碘值为50〜500，3〜12重量％的环氧乙烷的氧键，（2）30〜300毫摩尔的高分子化合物（1），（B）每分子二缩水甘油基化合物，分子量为100〜350的α，β-不饱和羧酸或不饱和脂肪酸，10〜200重量份指定的二缩水甘油基化合物与1.9〜2.1摩尔的反应产物并且含有至少10重量％的碳 - 碳双键或两者的混合物，（C）0.5至10重量份的分子量为500至5000的高分子化合物的反应产物并含有碳碳做每100克高分子化合物，指定的α，β-不饱和二羧酸和（D）0.005至1.0重量份的作为金属的碘值为50至500和40至400毫摩尔的碘值，具有选自锰，钴和铜的金属的有机酸的水溶性盐。

10. 发明授权

US4975475A Electrodeposition coating composition 失效
标题翻译：电沉积涂料组合物
公开(公告)号：US4975475A
公开(公告)日：1990-12-04
申请号：US301096
申请日：1989-01-25
申请人： Yasuyuki Tsuchiya , Shigeo Nishikawa , Kenshiro Tobinaga , Keizou Ishii , Koichi Saito
发明人： Yasuyuki Tsuchiya , Shigeo Nishikawa , Kenshiro Tobinaga , Keizou Ishii , Koichi Saito
IPC分类号： C09D5/44
CPC分类号： C09D5/448
摘要： An electrodeposition coating composition containing polymer microparticles of 0.01 to 20 microns size is disclosed. The polymer microparticles have a predetermined range of softening point, solubility parameter, refractive index or crosslinking density.
摘要翻译：公开了含有0.01至20微米尺寸的聚合物微粒的电沉积涂料组合物。聚合物微粒具有预定的软化点范围，溶解度参数，折射率或交联密度。

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