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    • 1. 发明申请
    • ZERO-VALENT IRON TWO-PHASE ANAEROBIC REACTOR
    • 零级铁两相厌氧反应器
    • US20130313172A1
    • 2013-11-28
    • US13981884
    • 2011-09-21
    • Yaobin ZhangYiwen LiuXie QuanXusheng MengShuo ChenZhiqiang Zhao
    • Yaobin ZhangYiwen LiuXie QuanXusheng MengShuo ChenZhiqiang Zhao
    • C02F3/28
    • C02F3/28C02F3/107C02F3/2826C02F3/286Y02E50/343Y02W10/15
    • The invention, belongs to the field of wastewater treatment technology, is a two-phase anaerobic reactor enhanced by addition of zero valent iron (ZVI). In the reactor, 2˜4 ZVI-filling layers are settled in the middle of the anaerobic hydrolysis-acidification tank, the effluent of which is fed into the rear anaerobic methanogenic tank. The degradation of organics is effectively enhanced in the anaerobic hydrolysis-acidification tank with dosing of ZVI, which may produce more acetic acid that is a desired substrate for the subsequent methanogenesis. Meanwhile, the acidic environment of the hydrolysis-acidification tank is helpful for the dissolution of ZVI to maintain its activity. The reactor is reasonably designed with high performance and strong shock resistance in anaerobic treatment of various wastewaters. Tests in lab-scale showed that hydrolysis-acidification and methanogenesis in this combined system were significantly improved compared with a reference reactor without addition of ZVI.
    • 本发明属于废水处理技术领域,是通过添加零价铁(ZVI)增强的两相厌氧反应器。 在反应器中,将2〜4个ZVI填充层沉淀在厌氧水解酸化槽的中间,将其流出物送入后厌氧甲烷生成槽。 在ZVI给药的厌氧水解酸化槽中有机物的降解被有效地增强,这可以产生更多的乙酸,其是用于随后的甲烷生成的期望的底物。 同时,水解酸化槽的酸性环境有助于溶解ZVI以维持其活性。 在各种废水的厌氧处理中,反应器设计合理,性能好,抗冲击性强。 实验室测试结果表明,与没有添加ZVI的参比反应器相比,该组合体系中的水解酸化和甲烷生成显着改善。
    • 2. 发明授权
    • Wastewater processing method of hydrolysis-acidification enhanced by addition of zero-valent iron (ZVI)
    • 通过添加零价铁(ZVI)增强水解酸化的污水处理方法
    • US08758617B2
    • 2014-06-24
    • US13981887
    • 2011-09-21
    • Xie QuanYaobin ZhangYiwen LiuHuimin ZhaoShuo ChenYang Yang Li
    • Xie QuanYaobin ZhangYiwen LiuHuimin ZhaoShuo ChenYang Yang Li
    • C02F3/30C02F3/28
    • C02F3/28C02F1/705C02F3/101C02F3/107C02F3/2826Y02W10/15
    • The invention discloses a wastewater processing method of hydrolysis-acidification enhanced by addition of zero-valent iron (ZVI), including the following steps: 3˜6 ZVI-filling layers are settled in the middle of an anaerobic hydrolysis-acidification reactor. Excess sludge taken from sewage treatment plant using as seed sludge is added into this anaerobic hydrolysis-acidification reactor for startup and domestication. In the present invention, ZVI are added into this anaerobic hydrolysis-acidification reactor to accelerate organic matters degradation and produce more acetic acids, accompanied with higher COD removal obtained. ZVI can be protected from rust in this anaerobic biological environment due to the air isolation. Also, ZVI can enhance anaerobic hydrolysis of wastewater through reducing refractory pollutants involved in wastewaters. This novel method made the effluent from the hydrolysis-acidification reactor present less COD concentration and simpler substrate form, benefiting for the following anaerobic methanogenesis or aerobic treatment.
    • 本发明公开了通过添加零价铁(ZVI)提高水解酸化的废水处理方法,包括以下步骤:3〜6个ZVI填充层沉淀在厌氧水解酸化反应器的中间。 将用作种子污泥的污水处理厂取得的多余污泥加入到厌氧水解酸化反应器中进行启动和驯化。 在本发明中,将ZVI加入到该厌氧水解酸化反应器中以加速有机物降​​解并产生更多的乙酸,伴随着更高的COD去除。 由于空气隔离,ZVI可以在这种厌氧生物环境中防止生锈。 此外,ZVI可以通过减少废水中的难溶性污染物来增强废水的厌氧水解。 这种新方法使得水解酸化反应器的流出物具有更少的COD浓度和更简单的底物形式,有利于以下厌氧甲烷生成或需氧处理。
    • 3. 发明授权
    • Zero-valent iron two-phase anaerobic reactor
    • 零价铁两相厌氧反应器
    • US08758616B2
    • 2014-06-24
    • US13981884
    • 2011-09-21
    • Yaobin ZhangYiwen LiuXie QuanXusheng MengShuo ChenZhiqiang Zhao
    • Yaobin ZhangYiwen LiuXie QuanXusheng MengShuo ChenZhiqiang Zhao
    • C02F3/00
    • C02F3/28C02F3/107C02F3/2826C02F3/286Y02E50/343Y02W10/15
    • The invention, belongs to the field of wastewater treatment technology, is a two-phase anaerobic reactor enhanced by addition of zero valent iron (ZVI). In the reactor, 2˜4 ZVI-filling layers are settled in the middle of the anaerobic hydrolysis-acidification tank, the effluent of which is fed into the rear anaerobic methanogenic tank. The degradation of organics is effectively enhanced in the anaerobic hydrolysis-acidification tank with dosing of ZVI, which may produce more acetic acid that is a desired substrate for the subsequent methanogenesis. Meanwhile, the acidic environment of the hydrolysis-acidification tank is helpful for the dissolution of ZVI to maintain its activity. The reactor is reasonably designed with high performance and strong shock resistance in anaerobic treatment of various wastewaters. Tests in lab-scale showed that hydrolysis-acidification and methanogenesis in this combined system were significantly improved compared with a reference reactor without addition of ZVI.
    • 本发明属于废水处理技术领域,是通过添加零价铁(ZVI)增强的两相厌氧反应器。 在反应器中,将2〜4个ZVI填充层沉淀在厌氧水解酸化槽的中间,其排出物进料到后厌氧甲烷生成槽中。 在ZVI给药的厌氧水解酸化槽中有机物的降解被有效地增强,这可以产生更多的乙酸,其是用于随后的甲烷生成的期望的底物。 同时,水解酸化槽的酸性环境有助于溶解ZVI以维持其活性。 在各种废水的厌氧处理中,反应器设计合理,性能好,抗冲击性强。 实验室测试结果表明,与没有添加ZVI的参比反应器相比,该组合体系中的水解酸化和甲烷生成显着改善。