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    • 1. 发明授权
    • Unsaturated ketones and their use in perfumery
    • 不饱和酮及其在香料中的用途
    • US06177400B1
    • 2001-01-23
    • US09306797
    • 1999-05-07
    • Hubert MimounWolfgang Klaus Giersch
    • Hubert MimounWolfgang Klaus Giersch
    • A61K746
    • C07C403/16C07C31/1355C07C33/14C07C45/62C07C47/32C07C47/42C07C69/007C07C2601/14C07C2601/16C07D317/12C11B9/0034
    • The compounds according to the general formula in which formula the dotted lines indicate a single or a double bond, n and m are 0 or 1, R1 is hydrogen or an acyl group —C(O)R3, R3 being a linear or branched alkyl or alkylene group from C1 to C8, the oxygen atom being bound to the adjacent &agr;-carbon atom by a double bond in the case where n is 0 and by a single bond in the case where n is 1, R2 is hydrogen or a linear or branched alkyl, alkenyl or alkoxy group from C1 to C8, or R2 is an alkenoxy group which is linked to the group R1 to form a 1,3-dioxolane cycle having 5 to 7 ring members, are useful perfuming ingredients. The most preferred compounds according to the invention are those which have a damascone- or damascenone-like structure, with the methyl substituent being in 4-position of the ring instead of the 2-position, as is the case in damascones and damascenones.
    • 根据一般配方的化合物,其虚线表示单键或双键,n和m为0或1,R 1为氢或酰基-C(O)R 3,R 3为直链或支链烷基或 在C1至C8的亚烷基中,在n为0的情况下,氧原子通过双键与相邻的α-碳原子结合,在n为1的情况下通过单键结合,R2为氢或直链或 支链烷基,烯基或烷氧基,或R2是与基团R1连接形成具有5至7个环成员的1,3-二氧戊环循环的链烯氧基,是有用的加香成分。 根据本发明最优选的化合物是具有大马酮酮或大马士革类结构的那些化合物,甲基取代基位于环的4-位而不是2-位,如在damascones和大马士革中的情况。