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1. 发明授权

US4859745A Stratified fibrous fluoropolymer compositions and process for forming such fluoropolymers 失效
标题翻译：分层纤维状含氟聚合物组合物和形成这种含氟聚合物的方法
公开(公告)号：US4859745A
公开(公告)日：1989-08-22
申请号：US136690
申请日：1987-12-22
申请人： William P. Carl , Emmett L. Tasset , Robert E. Aikman, Jr.
发明人： William P. Carl , Emmett L. Tasset , Robert E. Aikman, Jr.
IPC分类号： C08F259/08
CPC分类号： C08F259/08 , Y10S525/902
摘要： The invention is a process for producing a modified polytetrafluoroethylene which comprises polymerizing tetrafluoroethylene in an aqueous medium containing a dispersing agent with a polymerization initiator source and then, copolymerizing tetrafluoroethylene one or more fluorinated modifiers having an acid functional group or a functional group which is convertible to the acid group as a copolymerizable modifier in the presence of the resulting polytetrafluoroethylene to a polymerization point past the Kraft point to produce highly porous, fibrous, stratified fluoropolymers having cores made of homopolymer of poly-tetrafluoroethylene coated with sheath layers which are made of a copolymer of polytetrafluoroethylene and one or more modifiers.The invention also includes a highly porous, fibrous, stratified fluoropolymer having a plurality of interconnected, fibrous-like projections wherein the stratified fluoropolymer has a core layer of polytetrafluoroethylene substantially completely covered by a copolymer of polytetrafluoroethylene and a fluorocarbon modifier.
摘要翻译：本发明是一种改性聚四氟乙烯的制造方法，其特征在于，在含有聚合引发剂源的分散剂的水性介质中聚合四氟乙烯，然后使四氟乙烯与一种或多种具有酸官能团或官能团的氟化改性剂共聚，该酸基团作为可共聚改性剂，在所得聚四氟乙烯存在下，聚合点经过牛皮纸点，以产生具有由涂覆有鞘层的聚四氟乙烯均聚物制成的芯的高度多孔，纤维状分层的含氟聚合物，的聚四氟乙烯和一种或多种改性剂。本发明还包括具有多个相互连接的纤维状突起的高度多孔，纤维状分层的氟聚合物，其中分层含氟聚合物具有基本上被聚四氟乙烯和氟碳改性剂的共聚物完全覆盖的聚四氟乙烯核心层。

2. 发明授权

US4804727A Process to produce novel fluorocarbon vinyl ethers and resulting polymers 失效
标题翻译：生产新型氟碳乙烯醚和所得聚合物的方法
公开(公告)号：US4804727A
公开(公告)日：1989-02-14
申请号：US46954
申请日：1987-05-05
申请人： Bobby R. Ezzell , William P. Carl , William A. Mod
发明人： Bobby R. Ezzell , William P. Carl , William A. Mod
IPC分类号： C07C41/24 , C07C43/17 , C07F9/40 , C08F16/14 , C08F16/24 , C08F216/14
CPC分类号： C08F216/14 , C07C309/00 , C07F9/4006 , C08F16/14
摘要： Novel vinyl ethers are prepared in decarboxylation reactions of novel acid fluoride compounds according to the following reaction: ##STR1## wherein a is 0 or an integer greater than 0;b is 0 or an integer greater than 0;n=1 or an integer greater than 1;R.sub.f and R.sub.f ' are independently selected from the group consisting of F, Cl, perfluoroalkyl or fluorochloroalkyl;X=F, Cl, Br or mixtures thereof when n>1X'=Cl or Br;D is an acid group or an acid derivative easily convertible to an acid group;Z=F, Cl, Br, OH, NRR' or OA;R and R' are independently selected from the group consisting of hydrogen, an alkyl having one or more than one carbon atoms, and aryl; andA=alkali metal, quaternary nitrogen, or R.These vinyl ethers may be homopolymerized with themselves or copolymerized with other vinyl ethers.
摘要翻译：新型乙烯基醚在新的酰氟化合物的脱羧反应中根据以下反应制备：其中a为0或大于0的整数; b为0或大于0的整数; n = 1或大于1的整数; Rf和Rf'独立地选自F，Cl，全氟烷基或氟氯烷基; 当n> 1 X'= Cl或Br时，X = F，Cl，Br或其混合物; D是易于转化为酸基的酸基或酸衍生物; Z = F，Cl，Br，OH，NRR'或OA; R和R'独立地选自氢，具有一个或多于一个碳原子的烷基和芳基; 并且A =碱金属，季氮或R.这些乙烯基醚可以与其自身均聚或与其它乙烯基醚共聚。

3. 发明授权

US4784882A Method for forming composite polymer films 失效
标题翻译：复合聚合物膜的形成方法
公开(公告)号：US4784882A
公开(公告)日：1988-11-15
申请号：US739734
申请日：1985-05-31
申请人： Jeffrey D. Birdwell , William P. Carl
发明人： Jeffrey D. Birdwell , William P. Carl
IPC分类号： C08J3/02 , B01D67/00 , B01D69/10 , B01D71/32 , B01J41/14 , C08F14/18 , C08F16/14 , C08F214/18 , C08F216/14 , C08J3/09 , C08J5/18 , C08J5/22 , C08L27/06 , C08L27/12 , C08L29/10 , H01M8/02 , H01M8/10 , B05D3/02 , B32B27/00 , C25B13/00
CPC分类号： C08J5/18 , B01D67/0011 , B01D67/0044 , B01D69/10 , B01D71/32 , C08J3/093 , H01M8/0289 , B01D2323/08 , B01D2323/12 , C08J2327/18 , H01M8/1004 , Y10T428/31544
摘要： The invention is a method for forming composite polymer films comprising:(a) forming a dispersion of a first perfluorinated polymer containing sites convertible to ion exchange groups and a dispersant having: a boiling point less than about 110.degree. C.; a density of from about 1.55 to about 2.97 grams per cubic centimeter; and a solubility parameter of from greater than about 7.1 to about 8.2 hildebrands;(b) forming a first film of the perfluorinated polymer by depositing the dispersion onto a second polymer film containing ion exchange groups or sites convertible to ion exchange groups; and(c) heating the two films for a time and at a temperature sufficient to fuse the two films to each other.Particularly preferred as a dispersant is a compound represented by the general formula:XCF.sub.2 --CYZX'wherein:X is selected from the group consisting of F, Cl. Br, and I;X' is selected from the group consisting of Cl, Br, and I;Y and Z are independently selected from the group consisting of H, F, Cl, Br, I, and R';R' is selected from the group of perfluoroalkyl radicals and chloroperfluoroalkyl radicals having from 1 to 6 carbon atoms.The most preferred dispersant is 1,2-dibromotetrafluoroethane.
摘要翻译：本发明是形成复合聚合物膜的方法，其包括：（a）形成含有可转化为离子交换基团的位点的第一全氟化聚合物的分散体和具有小于约110℃的沸点的分散剂。约1.55至约2.97克/立方厘米的密度; 并且溶解度参数为大于约7.1至约8.2扁平线; （b）通过将分散体沉积到含有离子交换基团或可转换成离子交换基团的位点的第二聚合物膜上，形成全氟化聚合物的第一膜; 和（c）将两个膜加热一段时间并在足以将两个膜彼此熔合的温度下加热。特别优选的分散剂是由以下通式表示的化合物：XCF2-CYZX'其中：X选自F，Cl。 Br和I X'选自Cl，Br和I; Y和Z独立地选自H，F，Cl，Br，I和R'; R'选自具有1至6个碳原子的全氟烷基和氯全氟烷基。最优选的分散剂是1,2-二溴四氟乙烷。

4. 发明授权

US4748190A Process for forming a shaped porous fluorinated polymer catalyst and the resultant product 失效
标题翻译：用于形成成形的多孔氟化聚合物催化剂和所得产物的方法
公开(公告)号：US4748190A
公开(公告)日：1988-05-31
申请号：US813130
申请日：1985-12-24
申请人： William P. Carl
发明人： William P. Carl
IPC分类号： B01J31/06 , B01J31/08 , C08F4/02 , C08J9/06 , B29C67/22 , C08J9/12
CPC分类号： C08F4/027 , B01J31/08 , B01J2231/323 , B01J2231/326 , B01J2231/52 , B01J2231/64 , Y10S264/09
摘要： The invention is a process for making a high surface area, self-supporting catalyst suitable for use as an acid catalyst comprising:(a) at least partially polymerizing a perfluorinated monomer containing ion exchange groups convertible to an acid or salt form in a medium containing a gas-forming ingredient(s) which is present during polymerization and serves a polymerization enhancement purpose during polymerization; wherein the said gas-forming ingredient(s) is a material that will convert into a gaseous state and expand when heated; and(b) heating the polymer to a temperature sufficient to soften the polymer and sufficient to convert at least a portion of the gas-forming ingredient(s) into a gaseous state while the polymer is still in contact with at least a portion of the gas-forming ingredient(s), thereby converting the gas-forming ingredient(s) into a gas which expands the polymer and causes the formation of open and closed pores within the polymer.
摘要翻译：本发明是一种制备适合用作酸催化剂的高表面积自支撑催化剂的方法，其包括：（a）至少部分地将含有可转化为酸或盐形式的离子交换基团的全氟化单体在含有在聚合期间存在的气体形成成分，并且在聚合期间用作聚合增强目的; 其中所述气体形成成分是将被转化成气态并在加热时膨胀的材料; 和（b）将聚合物加热到足以软化聚合物的温度，并且足以将至少一部分气体形成成分转化为气态，同时聚合物仍然与至少一部分气体形成成分，从而将气体形成成分转化为膨胀聚合物并使聚合物内形成开放和闭孔的气体。

5. 发明授权

US4650711A Method for sizing polytetrafluoroethylene fabrics 失效
标题翻译：聚四氟乙烯织物尺寸的方法
公开(公告)号：US4650711A
公开(公告)日：1987-03-17
申请号：US739956
申请日：1985-05-31
申请人： William P. Carl , Jeffrey D. Birdwell
发明人： William P. Carl , Jeffrey D. Birdwell
IPC分类号： B01D67/00 , B01D69/10 , B01D71/32 , C08J3/09 , C08J5/18 , H01M8/02 , H01M8/10 , B32B7/00 , D03D3/00 , D06M15/00
CPC分类号： C08J5/18 , B01D67/0011 , B01D69/10 , B01D71/32 , C08J3/093 , H01M8/0289 , B01D2323/08 , B01D2323/12 , C08J2327/18 , H01M8/1004 , Y10T428/3154 , Y10T428/31544 , Y10T442/2402
摘要： The invention is a method for sizing polytetrafluoroethylene fabrics comprising:(a) forming a sizing composition of a perfluorinated polymer containing sites convertible to ion exchange groups and a treating agent having: a boiling point less than about 110.degree. C.; a density of from about 1.55 to about 2.2; and a solubility parameter of from greater than about 7.1 to about 8.2 hildebrands;(b) contacting the sizing composition with the fibers of a polytetrafluoroethylene fabric; and(c) removing the treating agent from the sizing composition.Particularly preferred as a treating agent is a compound represented by the general formula:XCF.sub.2 --CYZX'wherein:X is selected from the group consisting of F, Cl, Br, and I;X' is selected from the group consisting of Cl, Br, and I;Y and Z are independently selected from the group consisting of H, F, Cl, Br, I and R';R' is selected from the group of perfluoroalkyl radicals and chloroperfluoroalkyl radicals having from 1 to 6 carbon atoms.The most preferred treating agent is 1,2-dibromotetrafluoroethane.
摘要翻译：本发明是一种聚四氟乙烯织物尺寸的方法，包括：（a）形成含有可转化为离子交换基团的位点的全氟化聚合物的施胶组合物和沸点低于约110℃的处理剂; 约1.55至约2.2的密度; 并且溶解度参数为大于约7.1至约8.2扁平线; （b）使上胶组合物与聚四氟乙烯织物的纤维接触; 和（c）从施胶组合物中除去处理剂。作为处理剂特别优选的是由下列通式表示的化合物：XCF2-CYZX'其中：X选自F，Cl，Br和I; X'选自Cl，Br和I; Y和Z独立地选自H，F，Cl，Br，I和R'; R'选自具有1至6个碳原子的全氟烷基和氯全氟烷基。最优选的处理剂是1,2-二溴四氟乙烷。

6. 发明授权

US4650551A Supported ion exchange membrane films 失效
标题翻译：负离子交换薄膜
公开(公告)号：US4650551A
公开(公告)日：1987-03-17
申请号：US739934
申请日：1985-05-31
申请人： William P. Carl , Jeffrey D. Birdwell
发明人： William P. Carl , Jeffrey D. Birdwell
IPC分类号： B01D67/00 , B01D69/10 , B01D71/32 , C08J3/09 , C08J5/18 , H01M8/02 , H01M8/10 , C25B1/00 , C25B13/02 , C09J5/02
CPC分类号： C08J5/18 , B01D67/0011 , B01D69/10 , B01D71/32 , C08J3/093 , H01M8/0289 , B01D2323/08 , B01D2323/10 , B01D2323/12 , B01D2325/18 , C08J2327/18 , H01M8/1004
摘要： The invention is a method for forming a supported membrane film comprising:(a) at least partially coating a polytetrafluoroethylene fabric with a sizing composition;(b) contacting the coated polytetrafluoroethylene fabric with a membrane film having sites convertible to ion exchange groups; and(c) heating the polytetrafluoroethylene fabric and the membrane film while maintaining the fabric and the film in contact.
摘要翻译：本发明是一种形成支撑膜膜的方法，其包括：（a）至少部分地用施胶组合物涂覆聚四氟乙烯织物; （b）使涂覆的聚四氟乙烯织物与具有可转换成离子交换基团的位点的膜膜接触; 和（c）在保持织物和膜接触的同时加热聚四氟乙烯织物和膜膜。

7. 发明授权

US4470889A Electrolytic cell having an improved ion exchange membrane and process for operating 失效
标题翻译：电解槽具有改进的离子交换膜和操作过程
公开(公告)号：US4470889A
公开(公告)日：1984-09-11
申请号：US158429
申请日：1980-06-11
申请人： Bobby R. Ezzell , William P. Carl , William A. Mod
发明人： Bobby R. Ezzell , William P. Carl , William A. Mod
IPC分类号： C25B13/08 , B01J47/12 , C08J5/22 , C25B1/46 , C25B1/34
CPC分类号： C25B1/46 , C08J5/2237 , C08J2327/18
摘要： An electrolytic cell and a process for electrolysis using the cell are provided. The electrolytic cell is separated into an anode chamber and a cathode chamber by a fluorinated polymer membrane; wherein the membrane comprises:(a) at least 60 mole percent [CFX--CF.sub.2 ] where X=F or Cl;(b) an ion exchange equivalent weight of at least 600;(c) pendant sulfonyl ion exchange groups; and(d) pendant substantially fluorinated carbon groups which have no ion exchange functionality.These cells are particularly useful for the electrolysis of aqueous, alkali metal halides.
摘要翻译：提供电解池和使用电池的电解方法。电解池通过氟化聚合物膜分离成阳极室和阴极室; 其中所述膜包含：（a）至少60摩尔％的[CFX-CF 2]，其中X = F或Cl; （b）至少600的离子交换当量; （c）磺酰离子交换基团; 和（d）不具有离子交换官能团的侧基基本上氟化的碳基团。这些电池特别可用于电解碱金属卤化物水溶液。

8. 发明授权

US4417969A Sulfonic acid electrolytic cell membranes 失效
标题翻译：磺酸电解池
公开(公告)号：US4417969A
公开(公告)日：1983-11-29
申请号：US341431
申请日：1982-01-21
申请人： Bobby R. Ezzell , William P. Carl , William A. Mod
发明人： Bobby R. Ezzell , William P. Carl , William A. Mod
IPC分类号： C08J5/22 , C25B1/46 , C25B9/00 , C25B1/14
CPC分类号： C08J5/225 , C25B1/46 , C08J2327/18
摘要： An improved polymer for use as an ion exchange membrane in an electrolytic cell wherein the polymer has pendant chains containing sulfonic acid ion exchange groups and has an equivalent weight of between about 800 and about 1500. The polymers have a hydration product of less than about 22,000.The electrolytic cell and its method of operation are described when these polymers are used as ion exchange membranes.
摘要翻译：一种用于电解池中离子交换膜的改进的聚合物，其中该聚合物具有含磺酸离子交换基团的侧链，其当量重量约为800至约1500.聚合物具有小于约22,000的水合产物。当这些聚合物用作离子交换膜时，描述了电解槽及其操作方法。

9. 发明授权

US4358412A Preparation of vinyl ethers 失效
标题翻译：乙烯基醚的制备
公开(公告)号：US4358412A
公开(公告)日：1982-11-09
申请号：US158427
申请日：1980-06-11
申请人： Bobby R. Ezzell , William P. Carl , William A. Mod
发明人： Bobby R. Ezzell , William P. Carl , William A. Mod
IPC分类号： C07C69/708 , B01J27/232 , C07B61/00 , C07C41/24 , C07C43/17 , C07C51/00 , C07C51/38 , C07C59/135 , C07C67/00 , C07C67/32 , C07C69/734 , C07C309/10 , C07C309/65 , C07C309/68 , C07C309/80 , C07C309/82 , C07F9/40 , C07F9/113 , C07C69/73 , C07C143/70
CPC分类号： C07C309/00 , C07F9/4006
摘要： The invention relates to a process to produce compounds represented by the general formulaY--(CFR.sub.f).sub.a --(CFR.sub.f ').sub.b --O--CF.dbd.CF.sub.2by decarboxylation of compounds represented by the general formula ##STR1## where a=0-3; b=0-3;provided a+b=2 or 3;Y.dbd.an acid derivative;X.dbd.Cl, I, or Br;M.dbd.OR, F, Cl, Br, I, OA;A.dbd.alkali metal, alkali earth metal, a quaternary nitrogen and hydrogen;R.sub.f ' and R.sub.f are independently selected from the group consisting of F, Cl, perfluoroalkyls and fluorochloroalkylsR.dbd.an alkyl having one or more carbon atoms or an aryl.
摘要翻译：本发明涉及通过通式（I）= 0-3表示的化合物的脱羧反应生成由通式Y-（CFRf）a-（CFRf'）b-O-CF = CF2表示的化合物的方法。 b = 0-3; 提供+ b = 2或3; Y =酸衍生物; X = Cl，I或Br; M = OR，F，Cl，Br，I，OA; A =碱金属，碱土金属，季氮和氢; Rf'和Rf独立地选自F，Cl，全氟烷基和氟氯烷基R =具有一个或多个碳原子的烷基或芳基。

10. 发明授权

US5654109A Composite fuel cell membranes 失效
标题翻译：复合燃料电池膜
公开(公告)号：US5654109A
公开(公告)日：1997-08-05
申请号：US497438
申请日：1995-06-30
申请人： Keith R. Plowman , Timothy J. Rehg , Larry W. Davis , William P. Carl , Alan J. Cisar , Charles S. Eastland
发明人： Keith R. Plowman , Timothy J. Rehg , Larry W. Davis , William P. Carl , Alan J. Cisar , Charles S. Eastland
IPC分类号： C08J5/22 , H01M4/92 , H01M8/10 , H01M8/00
CPC分类号： H01M4/928 , C08J5/225 , H01M8/1025 , H01M8/1039 , H01M8/1053 , H01M8/1067 , C08J2327/12 , H01M2300/0082 , H01M8/1004
摘要： A bilayer or trilayer composite ion exchange membrane suitable for use in a fuel cell. The composite membrane has a high equivalent weight thick layer in order to provide sufficient strength and low equivalent weight surface layers for improved electrical performance in a fuel cell. In use, the composite membrane is provided with electrode surface layers. The composite membrane can be composed of a sulfonic fluoropolymer in both core and surface layers.
摘要翻译：适用于燃料电池的双层或三层复合离子交换膜。复合膜具有高当量重的厚层，以提供足够的强度和低当量的表面层，以改善燃料电池中的电性能。在使用中，复合膜具有电极表面层。复合膜可以由核和表层中的磺基含氟聚合物组成。

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