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    • 2. 发明申请
    • OXIDATIVE DESULFURIZATION OF FUEL OIL
    • 燃油的氧化除油
    • US20090242458A1
    • 2009-10-01
    • US12055916
    • 2008-03-26
    • Grigorii Lev SoloveichikWilliam Christopher Alberts
    • Grigorii Lev SoloveichikWilliam Christopher Alberts
    • C10G45/04
    • C10G27/04C10G27/00
    • A method for purifying a sulfur-containing fuel oil comprising (a) contacting in a first reaction mixture the sulfur-containing fuel oil with a water-soluble organic acid and oxygen at a temperature in a range of from about 100° C. to about 250° C., and at a pressure in a range of from about 15 pounds per square inch to about 2500 pounds per square inch to provide a first oxidized mixture, (b) adding water to provide a biphasic mixture comprising a water-rich phase and a fuel oil-rich phase, and (c) separating the water-rich phase from the fuel oil-rich phase to provide a purified fuel oil. In one embodiment, the method may further include an oxidation catalyst. In one embodiment, the method may further include a carbonaceous promoter. In one embodiment, the sulfur-containing fuel oil may be deasphalted before contacting with the water-soluble organic acid.
    • 一种用于净化含硫燃料油的方法,包括(a)在第一反应混合物中使含硫燃料油与水溶性有机酸和氧在约100℃至约 250℃,压力范围为约15磅/平方英寸至约2500磅/平方英寸,以提供第一氧化混合物,(b)加水以提供包含富水相的两相混合物 和富燃料相,和(c)从富燃相中分离富水相以提供纯化燃料油。 在一个实施方案中,该方法还可以包括氧化催化剂。 在一个实施方案中,该方法可以进一步包括碳质促进剂。 在一个实施方案中,含硫燃料油在与水溶性有机酸接触之前可以脱沥青。