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1. 发明授权

US4439594A Curable epoxy resin compositions 失效
标题翻译：可固化环氧树脂组合物
公开(公告)号：US4439594A
公开(公告)日：1984-03-27
申请号：US420171
申请日：1982-09-17
申请人： William A. Higgins , Alan C. Clark
发明人： William A. Higgins , Alan C. Clark
IPC分类号： C08G59/40 , C08G59/56 , C08G59/68
CPC分类号： C08G59/4071 , C08G59/56
摘要： Curable compositions of matter comprising an epoxy resin and a curing agent selected from the group consisting of polyvalent metal salts of a phosphorodithioic acid, the acid being derived from the reaction of a phosphorus sulfide with a hydroxyl containing aromatic compound, and products derived from the reaction of the polyvalent metal salt with a mono- or polyamine.
摘要翻译：包含环氧树脂和固化剂的物质的可固化组合物，所述固化剂选自由二硫代磷酸的多价金属盐，所述酸源于硫化磷与含羟基的芳族化合物的反应，以及衍生自所述反应的产物的多价金属盐与单胺或多胺。

2. 发明授权

US4161566A Aqueous disperse compositions containing clay and oleaginous film-forming materials 失效
标题翻译：含有粘土和含油成膜材料的水性分散组合物
公开(公告)号：US4161566A
公开(公告)日：1979-07-17
申请号：US918008
申请日：1978-06-22
申请人： William A. Higgins
发明人： William A. Higgins
IPC分类号： C09D5/08 , C09D191/06 , C23F11/16 , C10M7/38 , C10M7/46
CPC分类号： C09D5/08 , C09D191/06 , Y10T428/31678
摘要： Aqueous disperse compositions capable of irreversibly forming films, comprising an internal phase of at least one film-forming, non-asphaltic, oleaginous material and an external phase comprising a clay-thickened water slurry, containing, in addition to clay, a flocculating agent are disclosed. Typical film-forming materials are made by reacting a carboxylic acid with an overbased salt of an organic acid, particularly those that have been converted into non-Newtonian colloidal disperse systems such as an alkaline earth metal sulfonate gel. Typical clays are montmorillonite-type clays and usually the composition as a whole is thixotropic. These compositions are useful, for example, as coatings for preventing corrosion of metallic surfaces.
摘要翻译：能够不可逆地形成膜的水性分散组合物，其包含至少一层成膜非沥青质含油材料的内相和包含粘土增稠水浆料的外部相，该粘土增稠水浆料除粘土外还含有絮凝剂，披露典型的成膜材料通过使羧酸与有机酸的高碱性盐，特别是已经转化成非牛顿胶体分散体系如碱土金属磺酸盐凝胶的那些反应而制备。典型的粘土是蒙脱石型粘土，通常整个组合物是触变性的。这些组合物可用作例如用于防止金属表面腐蚀的涂层。

3. 发明授权

US4600742A Polycarbonate compositions 失效
标题翻译：聚碳酸酯组合物
公开(公告)号：US4600742A
公开(公告)日：1986-07-15
申请号：US641892
申请日：1984-08-17
申请人： William A. Higgins
发明人： William A. Higgins
IPC分类号： C08K5/42
CPC分类号： C08K5/42
摘要： Carbonate polymer compositions are described which comprise a mixture of(A) an organic carbonate polymer, and(B) a minor amount of at least one metal sulfonate which is compatible with the carbonate polymer and which sulfonates are characterized by the formula ##STR1## wherein R is an aliphatic group,M is an alkali or alkaline earth metal,n is at least 1, andy is equal to 1 when M is an alkali metal and1/2 when M is an alkaline earth metal.The carbonate polymer compositions of the invention have improved properties such as, for example, flame-retardancy. Processes for improving the processability and flame-retardancy characteristics of carbonate polymer compositions also are described.
摘要翻译：描述了碳酸酯聚合物组合物，其包含（A）有机碳酸酯聚合物和（B）少量与碳酸酯聚合物相容的至少一种金属磺酸盐的混合物，其中磺酸盐的特征在于式（IMAGE）（ I）其中R是脂族基团，M是碱金属或碱土金属，n是至少1，当M是碱金属时，y等于1，当M是碱土金属时，y等于1。本发明的碳酸酯聚合物组合物具有改进的性能，例如阻燃性。还描述了用于改善碳酸酯聚合物组合物的加工性和阻燃性的方法。

4. 发明授权

US4620855A Amino sulfonic acid derivatives of carboxylic acid-containing interpolymers, and fuels, lubricants and aqueous systems containing said derivatives 失效
标题翻译：含羧酸互聚物的氨基磺酸衍生物，含有所述衍生物的燃料，润滑剂和含水体系
公开(公告)号：US4620855A
公开(公告)日：1986-11-04
申请号：US669175
申请日：1984-11-07
申请人： William A. Higgins
发明人： William A. Higgins
IPC分类号： B01F17/00 , C08F8/34 , C10L1/24 , C10M145/16 , C10M151/02 , C10M173/02 , C08K5/01 , C10M151/04
CPC分类号： B01F17/0057 , C08F8/44 , C10L1/2468 , C10M145/16 , C10M151/02 , C10M173/02 , C10M2201/02 , C10M2205/04 , C10M2209/086 , C10M2221/02 , C10N2250/02 , C10N2270/02
摘要： N-acylated aminohydrocarbyl sulfonic acids or acid derivative compositions are described which are characterized by the presence with the structure of at least one acyl, acylimidoyl or acyloxy group attached to the amino nitrogen, said groups being derived from at least one of the carboxylic acid groups contained in an interpolymer of (i) at least one vinyl aromatic monomer and (ii) at least one alpha, beta-unsaturated acid or derivative thereof. Aqueous systems also are described which comprise at least about 40% of water and the N-acylated amino hydrocarbyl sulfonic acid or salt composition of the invention. The hydrocarbyl sulfonic acid or salt compositions of the present invention are useful as emulsifiers, thickeners, dispersants, etc. in the aqueous systems, and the compositions also are useful as additives in fuels and lubricants.
摘要翻译：描述了N-酰化氨基烃基磺酸或酸衍生物组合物，其特征在于存在与氨基氮连接的至少一个酰基，酰亚胺基或酰氧基的结构，所述基团衍生自至少一个羧酸基团包含在（i）至少一种乙烯基芳族单体和（ii）至少一种α，β-不饱和酸或其衍生物的互聚物中。还描述了包含至少约40％的水和本发明的N-酰化的氨基烃基磺酸或盐组合物的水系统。本发明的烃基磺酸或盐组合物可用作水性体系中的乳化剂，增稠剂，分散剂等，并且组合物也可用作燃料和润滑剂中的添加剂。

5. 发明授权

US4728578A Compositions containing basic metal salts and/or non-Newtonian colloidal disperse systems and vinyl aromatic containing polymers 失效
标题翻译：含有碱金属盐和/或非牛顿胶体分散体系和含乙烯基芳族聚合物的组合物
公开(公告)号：US4728578A
公开(公告)日：1988-03-01
申请号：US896544
申请日：1986-08-13
申请人： William A. Higgins , John Bretz
发明人： William A. Higgins , John Bretz
IPC分类号： C08K3/30 , C08K3/26 , C08K3/32 , C08K5/09 , C08K5/13 , C08K5/42 , C08K13/02 , C08L53/00 , C08L53/02 , C09D5/08 , C09D153/00 , C09D153/02 , B32B15/08 , B05D3/02 , C09K3/00
CPC分类号： C09D5/08 , C08K13/02 , C08K3/26 , C08K5/42 , Y10T428/31696
摘要： The present invention relates to modified non-Newtonian colloidal disperse systems exhibiting improved thickening power, particularly when diluted. These compositions are useful as high-solids, thermosetting caulks, molding compositions, extruding compositions and the like, but are particularly suitable for use as high solids thermosetting coating compositions. These coating compositions are heat-stable and sag-resistant.The compositions of this invention comprise a mixture of(B) at least one non-Newtonian colloidal disperse system comprising(B-1) solid metal-containing colloidal particles,(B-2) a liquid dispersing medium, and(B-3) at least one organic compound which is soluble in said dispersing medium, the molecules of said organic compound being characterized by a hydrophobic portion and at least one polar substituent; and(C) at least one hydrogenated block copolymer of a vinyl aromatic monomer and an aliphatic conjugated diene.Optionally, the compositions also contain (D) a substantially inert, normally liquid diluent.The invention also relates to methods of coating metal surfaces with the compositions of the invention described above as well as compositions comprising mixtures of neutral and/or basic metal salts of organic acidic materials and the copolymers (C) described above.
摘要翻译：本发明涉及改进的非牛顿胶体分散体系，其具有改善的增稠力，特别是当稀释时。这些组合物可用作高固体，热固性填缝料，模塑组合物，挤出组合物等，但特别适合用作高固含量的热固性涂料组合物。这些涂料组合物是热稳定的和抗起伏的。本发明的组合物包含（B）包含（B-1）含固体金属的胶体颗粒，（B-2）液体分散介质和（B-3）固体金属胶体分散体的至少一种非牛顿胶体分散体系的混合物，至少一种可溶于所述分散介质的有机化合物，所述有机化合物的分子的特征在于疏水部分和至少一个极性取代基; 和（C）至少一种乙烯基芳族单体和脂族共轭二烯的氢化嵌段共聚物。任选地，组合物还含有（D）基本惰性的通常为液体的稀释剂。本发明还涉及使用上述本发明的组合物涂覆金属表面的方法以及包含有机酸性材料的中性和/或碱性金属盐和上述共聚物（C）的混合物的组合物。

6. 发明授权

US4520155A Dye-receptive polyolefins and polyolefin fibers 失效
标题翻译：染料受体聚烯烃和聚烯烃纤维
公开(公告)号：US4520155A
公开(公告)日：1985-05-28
申请号：US603066
申请日：1984-04-23
申请人： William A. Higgins
发明人： William A. Higgins
IPC分类号： C08L23/02 , C08K20060101 , C08K5/41 , C08K5/42 , C08L20060101 , D01F6/46
CPC分类号： C08K5/42
摘要： Polyolefin compositions are described which can be dyed by conventional dyeing techniques. Such polyolefins comprise a blend of (A) a polyolefin and (B) a dye-receptive amount of at least one metal sulfonate which is soluble in the polyolefin when melted, and which sulfonates are characterized by the formulae ##STR1## wherein R is an aliphatic group,R' is an aliphatic group containing at least about 8 carbon atoms,Ar is an aromatic group,M is an alkali or alkaline earth metal,n is at least 1,y is equal to 1 when M is an alkali metal and 1/2 when M is an alkaline earth metal, andx is equal to the valence of M.The preferred sulfonates are those represented by Formula (I) and especially wherein M is sodium. In particular, it has been found that films and fibers prepared from such polyolefin composition, and more particularly polypropylene compositions, are readily dyed with common dyes to provide deep shades and fastness.
摘要翻译：描述了可以通过常规染色技术染色的聚烯烃组合物。这种聚烯烃包括（A）聚烯烃和（B）染料接受量的至少一种在熔融时可溶于聚烯烃的金属磺酸盐的共混物，并且哪些磺酸盐的特征在于式（I）（ R'ArSO 3）x M（II）其中R是脂族基团，R'是含有至少约8个碳原子的脂族基团，Ar是芳族基团，M是碱金属或碱土金属，n是至少1，当M是碱金属时，y等于1，当M是碱土金属时，y等于1，x等于M的化合价。优选的磺酸盐是由式（I）表示的那些，特别是其中M是钠。特别地，已经发现，由这种聚烯烃组合物制备的膜和纤维，特别是聚丙烯组合物，容易用普通染料染色，以提供深色调和坚牢度。

7. 发明授权

US4436855A Two-component urethane coating system 失效
标题翻译：双组分聚氨酯涂料体系
公开(公告)号：US4436855A
公开(公告)日：1984-03-13
申请号：US508992
申请日：1983-06-29
申请人： William A. Higgins , John S. Perz
发明人： William A. Higgins , John S. Perz
IPC分类号： C08G18/38 , C08G18/62 , C09D175/00 , C08K5/52
CPC分类号： C09D175/00 , C08G18/3878 , C08G18/6291
摘要： The present invention contemplates the provision of two-component urethane coating compositions comprising a first component comprising an organic polyfunctional isocyanate, and a second component comprising an acidic ester of a phosphoric acid, the alcohol portions of said acidic acid being selected from the group consisting of hydrocarbyloxy and hydroxy-substituted hydrocarbyloxy compounds, such compositions providing enhanced corrosion resistance properties as well as improved flame retardency and metal adhesion characteristics over the two-component urethane systems of the prior art. An essential ingredient in the compositions of the invention is a non-Newtonian colloidal disperse system which can be provided with either the first component and/or the second component parts of the compositions of the invention. The non-Newtonian colloidal disperse systems provided in accordance with the present invention comprise (1) solid metal-containing colloidal particles predispersed in (2) a disperse medium of at least one inert organic liquid and (3) as an essential third component at least one member selected from the class consisting of organic compounds which are substantially soluble in said disperse medium, the molecules of said organic compound being characterized by polar substituents and hydrophobic portions. The invention also relates to a method of coating a substrate comprising mixing the foregoing components and depositing the resulting composition on said substrate.
摘要翻译：本发明考虑提供双组分氨基甲酸酯涂料组合物，其包含包含有机多官能异氰酸酯的第一组分和包含磷酸的酸性酯的第二组分，所述酸性酸的醇部分选自烃氧基和羟基取代的烃氧基化合物，这些组合物在现有技术的双组分氨基甲酸酯体系中提供增强的耐腐蚀性以及改善的阻燃性和金属粘合特性。本发明组合物中的必要成分是非牛顿胶体分散体系，其可以具有本发明组合物的第一组分和/或第二组分。根据本发明提供的非牛顿胶体分散体系包括（1）预固化的（2）至少一种惰性有机液体的分散介质和（3）作为必需的第三组分的至少固体金属的胶体颗粒选自由基本上可溶于所述分散介质中的有机化合物组成的一类，所述有机化合物的分子的特征在于极性取代基和疏水部分。本发明还涉及一种涂覆基材的方法，包括混合上述组分并将所得组合物沉积在所述基材上。

8. 发明授权

US4250042A Corrosion inhibition in well-drilling operations using aqueous systems containing ammonium carboxylates 失效
标题翻译：使用含羧酸铵的含水体系进行钻井作业时的腐蚀抑制
公开(公告)号：US4250042A
公开(公告)日：1981-02-10
申请号：US30577
申请日：1979-04-16
申请人： William A. Higgins
发明人： William A. Higgins
IPC分类号： C09K8/035 , C09K8/54 , C09K7/02
CPC分类号： C09K8/54 , C09K8/035 , Y10S507/939
摘要： Certain salts of polycarboxylic acids and amino compounds are useful as corrosion inhibitors in aqueous systems used in well-drilling operations. Typical such corrosion inhibitors are made from acids such as sebacic and azelaic acid and amino compounds such as ammonia, ethanol amine, di- and tri-ethanol amines and N,N-diethyl-ethanol amine.
摘要翻译：某些多羧酸和氨基化合物的盐可用作在钻井操作中使用的水系统中的腐蚀抑制剂。典型的这种腐蚀抑制剂由诸如癸二酸和壬二酸的酸和诸如氨，乙醇胺，二 - 和三 - 乙醇胺和N，N-二乙基 - 乙醇胺的氨基化合物制成。

9. 发明授权

US5047457A Acrylate polymer modified asphalt compositions 失效
标题翻译：丙烯酸酯聚合物改性沥青组合物
公开(公告)号：US5047457A
公开(公告)日：1991-09-10
申请号：US302538
申请日：1989-01-25
申请人： William A. Higgins
发明人： William A. Higgins
IPC分类号： C08L95/00
CPC分类号： C08L95/00
摘要： Modified asphalt compositions are described which comprise(A) asphalt, and(B) a minor effective amount, sufficient to improve the durability of the asphalt in service, of at least one hydrocarbon-soluble acrylate polymer of the formula ##STR1## wherein R.sup.1 is a lower alkyl group containing from 1 to about 4 carbon atoms, R.sup.2 is a mixture of alkyl groups containing from about 4 to about 20 carbon atoms, and x is an integer providing a weight average molecular weight (Mw) to the acrylate polymer of about 5000 to about 1,000,000.Generally, the modified asphalt compositions will contain from about 0.01 to about 10% by weight, based on the weight of the asphalt, of the acrylate polymer as defined. The modified asphalt compositions of the present invention are useful in roofing and in preparing aggregate-containing asphalt concretes which can be employed as paving compositions.
摘要翻译：描述了改性沥青组合物，其包含（A）沥青和（B）少量有效量的，足以提高使用中的沥青的耐久性的至少一种下式的油溶性丙烯酸酯聚合物，其中R 1是含有1至约4个碳原子的低级烷基，R 2是含有约4至约20个碳原子的烷基的混合物，x是提供丙烯酸酯聚合物的重均分子量（Mw）为约 5000至约1,000,000。通常，改性沥青组合物将含有基于沥青重量的约0.01至约10重量％的如所定义的丙烯酸酯聚合物。本发明的改性沥青组合物可用于屋顶和制备可用作铺路组合物的含聚集体的沥青混凝土。

10. 发明授权

US4833184A Acrylate polymer modified asphalt compositions 失效
标题翻译：丙烯酸酯聚合物改性沥青组合物
公开(公告)号：US4833184A
公开(公告)日：1989-05-23
申请号：US24188
申请日：1987-03-10
申请人： William A. Higgins
发明人： William A. Higgins
IPC分类号： C08L95/00
CPC分类号： C08L95/00
摘要： Modified asphalt compositions are described which comprise(A) asphalt, and(B) a minor effective amount, sufficient to improve the durability of the asphalt in service, of at least one hydrocarbon-soluble acrylate polymer of the formula ##STR1## wherein R.sup.1 is a lower alkyl group containing from 1 to about 4 carbon atoms, R.sup.2 is a mixture of alkyl groups containing from about 4 to about 20 carbons atoms, and x is an integer providing a weight average molecular weight (Mw) to the acrylate polymer of about 5000 to about 1,000,000. Generally, the modified asphalt compositions will contain from about 0.01 to about 10% by weight, based on the weight of the asphalt, of the acrylate polymer as defined. The modified asphalt compositions of the present invention are useful in roofing and in preparing aggregate-containing asphalt concretes which can be employed as paving compositions.
摘要翻译：描述了改性沥青组合物，其包含（A）沥青和（B）少量有效量的，足以提高使用中的沥青的耐久性的至少一种下式的油溶性丙烯酸酯聚合物，其中R 1是含有1至约4个碳原子的低级烷基，R 2是含有约4至约20个碳原子的烷基的混合物，x是提供丙烯酸酯聚合物的重均分子量（Mw）为约 5000至约1,000,000。通常，改性沥青组合物将含有基于沥青重量的约0.01至约10重量％的如所定义的丙烯酸酯聚合物。本发明的改性沥青组合物可用于屋顶和制备可用作铺路组合物的含聚集体的沥青混凝土。

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