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    • 1. 发明申请
    • METHODS OF TREATING TEXTILE FIBRES
    • 处理纺织纤维的方法
    • US20140315022A1
    • 2014-10-23
    • US13814177
    • 2011-08-02
    • Warrick James David AllenAndrea DuffyNicholas Horrocks
    • Warrick James David AllenJames Leonard RolfeAndrea DuffyNicholas Horrocks
    • D06P1/52D06M15/59
    • D06P1/52C09D139/02D06M15/3562D06M15/3566D06M15/59D06P1/39D06P1/41D06P1/5242D06P1/525D06P3/241D06P3/242D06P3/521D06P3/522Y10T428/2969
    • According to the invention there is provided a method of treating textile fibres including the steps of: providing a polymeric precursor which includes a group of sub-formula (I) where R2 and R3 are independently selected from (CR7R8)n, or a group CR9R10, CR7R8CR9R10 or CR9R10CR7R8 where n is 0, 1 or 2, R7 and R8 are independently selected from hydrogen, halo or hydrocarbyl, and either one of R9 or R10 is hydrogen and the other is an electron withdrawing group, or R9 and R10 together form an electron withdrawing group, and R4 and R5 are independently selected from CH or CR11 where R11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X1 is a group CX2X3 where the dotted line bond to which it is attached is absent and a group CX2 where the dotted line bond to which it is attached is present, Y1 is a group CY2Y3 where the dotted line bond to which it is attached is absent and a group CY2 where the dotted line bond to which it is attached is present, and X2, X3, Y2 and Y3 are independently selected from hydrogen, fluorine or other substituents, R1 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or —R3-R5≡Y1, and R13 is C(O) or S(0)2; coating the textile fibres with the polymeric precursor; and polymerising the polymeric precursor so as to produce a polymeric coating on the textile fibres.
    • 根据本发明,提供了一种处理纺织纤维的方法,包括以下步骤:提供聚合物前体,其包含其中R2和R3独立地选自(CR7R8)n,或CR9R10基团的一个子式(I) ,CR 7 R 8 CR 9 R 10或CR 9 R 10 CR 7 R 8,其中n为0,1或2,R 7和R 8独立地选自氢,卤素或烃基,R 9或R 10中的任一个为氢,另一个为吸电子​​基团,或者R 9和R 10一起形成 吸电子基团,R4和R5独立地选自CH或CR11,其中R11是吸电子基团,虚线表示存在或不存在键,X1是基团的虚线键 不存在,并且存在与其连接的虚线键的基团CX2,Y1是不存在与其连接的虚线键的基团CY2Y3,并且其中虚线键合的基团CY2 附属的是 并且X 2,X 3,Y 2和Y 3独立地选自氢,氟或其它取代基,R 1选自氢,卤素,硝基,烃基,任选取代或插入有官能团,或-R 3 -R 5 = Y 1,以及 R 13为C(O)或S(O)2; 用聚合物前体涂覆纺织纤维; 并聚合聚合物前体以便在纺织纤维上产生聚合物涂层。
    • 5. 发明申请
    • METHODS OF COATING A LOW SURFACE ENERGY SUBSTRATE
    • US20140370279A1
    • 2014-12-18
    • US13814167
    • 2011-08-02
    • Warrick James David AllenAndrea Duffy
    • Warrick James David AllenJames Leonard RolfeAndrea Duffy
    • C09J147/00B05D3/00C09J133/24B05D7/24
    • C09J147/00B05D3/007B05D7/24C09D139/02C09J133/24Y10T428/2848Y10T428/31931Y10T428/31938
    • According to the invention there is provided a method of coating a low surface energy substrate including the steps of: a) providing a polymeric precursor which includes a group of sub-formula (I) where R1 is i) CRa, where Ra is hydrogen or alkyl, ii) a group S(0)pR13, or SiR14 where R13 and R14 are independently selected from hydrogen or hydrocarbyl, p is 0, 1 or 2 and q is 1 or 2, iii) C(0)N, S(0)2N, C(0)ON, CH2ON, or CH═CHRCN where Rc is an electron withdrawing group, or iv) OC(0)CH, C(0)OCH or S(0)2CH; in which R12 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or formula (II) R2 and R3 are independently selected from (CR7R8)n, or a group CR9R10, CR7R8CR9R10 or CR9R10CR7R8 where n is 0, 1 or 2, R7 and R8 are independently selected from hydrogen or alkyl, and either one of R9 or R10 is hydrogen and the other is an electron withdrawing group, or R9 and R10 together form an electron withdrawing group; R4 and R5 are independently selected from CH or CR11 where CR11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X1 is a group CX2X3 where the dotted line bond to which it is attached is absent and a group CX2 where the dotted line to which it is attached is present, Y1 is a group CY2Y3 where the dotted line to which it is attached is absent and a group CY2 where the dotted line to which it is attached is present, and X2, X3, Y2 and Y3 are independently selected from hydrogen, fluorine or other substituents; and b) either (i) coating the low surface energy substrate with the polymeric precursor and polymerising the polymeric precursor to form a polymeric coating, or (ii) polymerising the polymeric precursor and contacting the polymerised polymeric precursor with a low surface energy substrate to form a polymeric coating on the low surface energy substrate.
    • 7. 发明申请
    • COMPOSITE ARTICLES AND METHODS OF PRODUCING SAME
    • 复合制品及其生产方法
    • US20150283784A1
    • 2015-10-08
    • US13814183
    • 2011-08-02
    • Warrick James David AllenJames Leonard RolfeNicholas HorrocksPaul Milne
    • Warrick James David AllenJames Leonard RolfeNicholas HorrocksPaul Milne
    • B32B1/08B32B7/12B32B27/12F16L11/04B32B25/10B32B37/12B32B37/14F16L11/02B32B5/08B32B27/38
    • B32B1/08B32B5/08B32B7/12B32B25/10B32B25/20B32B27/12B32B27/38B32B37/1207B32B37/142B32B2255/02B32B2255/26B32B2262/0269B32B2262/0276B32B2262/103B32B2262/14B32B2310/0831B32B2383/00B32B2398/00B32B2597/00C09D139/02D06M10/10D06M15/3562F16L11/02F16L11/04Y10T428/249921
    • According to the invention there is provided a composite article including: a textile layer having a first and a second face, each of the first and second faces having a polymeric coating thereon; a first polymeric layer adhered to the polymeric coating on the first face of the textile layer; and a second polymeric layer adhered to the polymeric coating on the second face of the textile layer; in which the polymeric coatings on the first and second faces of the textile layer are each formed by polymerising a polymeric precursor which includes a group of sub-formula (I) where R2 and R3 are independently selected from (CR7R8)n, or a group CR9R10, CR7R8CR9R10 or CR9R10CR7R8 where n is 0, 1 or 2, R7 and R8 are independently selected from hydrogen, halo or hydrocarbyl, and either One of R9 or R10 is hydrogen and the other is an electron withdrawing group, or R9 and R10 together form an electron withdrawing group, and R4 and R5 are independently selected from CH or CR11 where R11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X1 is a group CX2X3 where the dotted line bond to which it is attached is absent and a group CX2 where the dotted line bond to which it is attached is present, Y1 is a group CY2Y3 where the dotted line bond to which it is attached is absent and a group CY2 where the dotted line bond to which it is attached is present, and X2, X3, Y2 and Y3 are independently selected from hydrogen, fluorine or other substituents, R1 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or formula (II), and R13 is C(0) or S(0)2.
    • 根据本发明,提供一种复合制品,其包括:具有第一和第二表面的织物层,所述第一和第二表面中的每一个在其上具有聚合物涂层; 第一聚合物层,粘合到纺织层的第一面上的聚合物涂层; 以及第二聚合物层,粘附到纺织物层的第二面上的聚合物涂层; 其中织物层的第一和第二表面上的聚合物涂层各自通过聚合聚合物前体形成,该聚合物前体包括其中R 2和R 3独立地选自(CR 7 R 8)n的一个子式(I) CR9R10,CR7R8CR9R10或CR9R10CR7R8,其中n为0,1或2,R7和R8独立地选自氢,卤素或烃基,R9或R10中的一个为氢,另一个为吸电子​​基团,或R 9和R 10为一体 形成吸电子基团,并且R 4和R 5独立地选自CH或CR 11,其中R 11是吸电子基团,虚线表示存在或不存在键,X 1是基团X 2 X 3,其中虚线键合到其上 不存在,并且存在与其连接的虚线键的基团CX2,Y1为不存在与其连接的虚线键的基团CY2Y3,并且其中虚线键合的基团CY2 是附属的 并且X 2,X 3,Y 2和Y 3独立地选自氢,氟或其它取代基,R 1选自氢,卤素,硝基,烃基,任选取代或插入有官能团或式(II),R 13是 C(0)或S(0)2。