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    • 1. 发明授权
    • Method of producing treated silica filler for silicone rubber
    • 硅橡胶处理二氧化硅填料的生产方法
    • US4985477A
    • 1991-01-15
    • US401607
    • 1989-08-30
    • Warde T. CollinsKenneth R. CottrellJohn C. Saam
    • Warde T. CollinsKenneth R. CottrellJohn C. Saam
    • C08K9/06C09C1/30
    • C09C1/3081C08K9/06C01P2006/12C01P2006/80Y10T428/2995
    • An improved method of producing treated silica filler for use with silicone rubber operates at ambient temperature in a short period of time. The method consists essentially of mixing reinforcing silica with a volatile treating agent of the formula R.sub.x Si(OR').sub.4 -.sub.x, wherein R is a substituted or unsubstituted, saturated or unsaturated, alkyl or aryl radical having from 1 to 6 carbon atoms, R' is an alkyl radical having from 1 to 3 carbon atoms, x is 1 or 2, and R and R' are chosed so that the vapor pressure of the alkoxysilane exceeds 10 Pa (0.0001) atmosphere) at treatment temperature, in combination with a volatile catalyst selected from the group consisting of acid A, base B, and mixtures thereof; wherein acid A is a volatile acid or acid progenitor, and base B is a silylamine or silazane, acid A and base B being chosen so that the vapor pressure of either acid A or base B exceeds 500 Pa (0.005 atmosphere) at treatment temperature, for a period of time sufficient to allow the desired amount of treating agent to be absorbed onto the surface of the particulate filler.
    • 用于硅橡胶的经处理的二氧化硅填料的改进方法在环境温度下在短时间内进行。 该方法基本上包括将增强二氧化硅与式RxSi(OR')4-x的挥发性处理剂混合,其中R是具有1至6个碳原子的取代或未取代的饱和或不饱和的烷基或芳基,R '是具有1至3个碳原子的烷基,x是1或2,选择R和R',使得烷氧基硅烷的蒸气压在处理温度下超过10Pa(0.0001)气氛),与 选自酸A,碱B及其混合物的挥发性催化剂; 其中酸A是挥发性酸或酸性祖细胞,碱B是甲硅烷基胺或硅氮烷,选择酸A和碱B使得在处理温度下,任一种酸A或碱B的蒸气压都超过500Pa(0.005气氛) 一段时间足以使所需量的处理剂吸收到颗粒填料的表面上。