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    • 9. 发明申请
    • FUNCTIONALIZED TRIPLET EMITTERS FOR ELECTRO-LUMINESCENT DEVICES
    • 用于电致发光器件的功能性三极管发射体
    • US20120326103A1
    • 2012-12-27
    • US13512111
    • 2010-11-26
    • Shuk Kwan MakWai Kin ChanTobias FischerHartmut Yersin
    • Shuk Kwan MakWai Kin ChanTobias FischerHartmut Yersin
    • C07F15/00F21V9/00C09K11/06
    • C07F15/0033C09K11/06C09K2211/185H01L51/0061H01L51/0085H01L51/0095H01L51/5016H05B33/14Y02E10/549
    • Organo-metallic complexes for opto-electronic and sensory devices and their use in such devices are provided. The organo-metallic complex (triplet emitter) consists of a metal center and chelate ligands. At least one of chelate ligands comprises an aromatic or fused aromatic ring(s). Each ligand is covalently substituted with at least one, preferably two charge transport groups (ctg). The metal center can be coordinated by a spectator ligand. Presence of two ctgs at each ligand is advantageous for applications in organic light emitting diodes (OLEDs). Charge transport units facilitate hole and/or electron transport to the molecular center and allow for efficient exciton formation directly on the complex. Presence of ctgs on each ligand provides good shielding with respect to interactions with the environment. Emission quenching is strongly reduced and materials with high emission quantum yields are obtained. Presence of ctgs on each ligand reduces undesired quenching by triplet-triplet annihilation or self-quenching effects.
    • 提供了用于光电和感官装置的有机金属配合物及其在这些装置中的应用。 有机金属络合物(三线态发射体)由金属中心和螯合配体构成。 至少一种螯合配体包括芳族或稠合芳环。 每个配体被至少一个,优选两个电荷转运基团(ctg)共价取代。 金属中心可由旁观者配体协调。 在每个配体上存在两个ctg对于在有机发光二极管(OLED)中的应用是有利的。 电荷传输单元促进空穴和/或电子传递到分子中心,并允许在复合物上直接形成有效的激子。 每个配体上的ctgs的存在在与环境的相互作用方面提供良好的屏蔽。 发射猝灭强烈降低,并获得具有高发射量子产率的材料。 每个配体上的ctgs存在通过三重态三重态湮灭或自熄效应减少不期望的猝灭。