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    • 1. 发明授权
    • Organic light-emitting devices using spin-dependent processes
    • 使用自旋依赖过程的有机发光装置
    • US07682707B2
    • 2010-03-23
    • US11110445
    • 2005-04-20
    • Z. Valy VardenyMarkus Wohlgenannt
    • Z. Valy VardenyMarkus Wohlgenannt
    • H01L51/54C09K11/06
    • B82Y10/00H01L51/5012Y10S428/917
    • The maximum luminous efficiency of organic light-emitting materials is increased through spin-dependent processing. The technique is applicable to all electro-luminescent processes in which light is produced by singlet exciton decay, and all devices which use such effects, including LEDs, super-radiant devices, amplified stimulated emission devices, lasers, other optical microcavity devices, electrically pumped optical amplifiers, and phosphorescence (Ph) based light emitting devices. In preferred embodiments, the emissive material is doped with an impurity, or otherwise modified, to increase the spin-lattice relaxation rate (i.e., decrease the spin-lattice time), and hence raise the efficiency of the device. The material may be a polymer, oligomer, small molecule, single crystal, molecular crystal, or fullerene. The impurity is preferably a magnetic or paramagnetic substance. The invention is applicable to IR, UV, and other electromagnetic radiation generation and is thus not limited to the visible region of the spectrum. The methods of the invention may also be combined with other techniques used to improve device performance.
    • 有机发光材料的最大发光效率通过自旋依赖处理增加。 该技术适用于其中由单线态激子衰变产生光的所有电致发光过程,并且使用这种效应的所有器件,包括LED,超辐射器件,放大的受激发射器件,激光器,其他光学微腔器件,电泵浦 光放大器和磷光(Ph)基发光器件。 在优选实施例中,发射材料掺杂有杂质或以其它方式修饰,以增加自旋晶格弛豫速率(即减小自旋晶格时间),从而提高器件的效率。 该材料可以是聚合物,低聚物,小分子,单晶,分子晶体或富勒烯。 杂质优选为磁性或顺磁性物质。 本发明可应用于IR,UV等电磁辐射产生,因此不限于光谱的可见光区域。 本发明的方法还可以与用于提高设备性能的其他技术组合。