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1. 发明申请

US20080292526A1 Method for the Production of Double Metal Cyanide Complex Catalysts 审中-公开
标题翻译：双金属氰化物复合催化剂生产方法
公开(公告)号：US20080292526A1
公开(公告)日：2008-11-27
申请号：US11913484
申请日：2006-05-02
申请人： Edward Bohres , Michael Stosser , Ludwig Volkel , Raimund Ruppel , Eva Baum , Norbert Wagner , Jorg Sundermeyer , Udo Garrelts , Michael Zirnstein
发明人： Edward Bohres , Michael Stosser , Ludwig Volkel , Raimund Ruppel , Eva Baum , Norbert Wagner , Jorg Sundermeyer , Udo Garrelts , Michael Zirnstein
IPC分类号： C01C3/14 , C01C3/20 , C01B21/20 , C01G1/04
CPC分类号： B01J27/26 , B01J31/1805 , B01J31/20 , B01J2231/48 , C08G65/2663
摘要： Process for preparing double metal cyanide catalysts of the general formula (I) M2a[M1(CN)rXt]b (I) where M2 is preferably Co(III) or Fe(III), and M1 is preferably Zn(II), X is a group other than cyanide which forms a coordinate bond to M1 and is selected from the group consisting of carbonyl, cyanate, isocyanate, nitrile, thiocyanate and nitrosyl, a, b, r, t are integers which are selected so that the compound is electrically neutral, by reacting a) a cyanometallic acid of the general formula (II) Hw[M1(CN)r(X)t] where M1 and X are as defined above, r and t are as defined above and w is selected so that the compound is electrically neutral, with b) a readily protolyzable metal compound (IIIa) M2Rw and/or (IIIb) M2RuYv, where M2 is as defined above, the groups R are identical or different and are each the anion of a very weak protic acid having a pKa of ≧20, and Y is the anion of an inorganic mineral acid or a moderately strong to strong organic acid having a pKa of from −10 to +10, w corresponds to the valence of M2, u+v corresponds to the valence of M2, with u and v each being at least 1, with the reaction being carried out in a nonaqueous, aprotic solvent.
摘要翻译：制备通式（I）的双金属氰化物催化剂的方法<？in-line-formula description =“In-line formula”end =“lead”→> M2a [M1（CN）rXt] b（I）其中M2优选为Co（III）或Fe（III），M1优选为Zn（II），X为氰化物以外的基团其形成与M1的配位键，并且选自羰基，氰酸酯，异氰酸酯，腈，硫氰酸酯和亚硝酰基，a，b，r，t是选择为使化合物电中性的整数，通过使）通式（II）的卤代金属盐Hw [M1（CN）r（X）t]其中M1和X如上定义，r和t如上所定义，并且w被选择为使得化合物是电中性的，其中b）易于分解的金属化合物（IIIa）M2Rw和/或（IIIb）M2RuYv，其中M2如上所定义，基团R相同或不同，各自为非常弱的质子酸的阴离子，其具有pKa为 > = 20，和 Y是无机无机酸的阴离子或pKa为-10至+10的中等强至强有机酸的阴离子，w对应于M2的化合价，u + v对应于M2的化合价，u和v 每个至少为1，反应在非水性非质子溶剂中进行。

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