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1. 发明授权

US4007435A Sensor device and method of manufacturing same 失效
标题翻译：传感器装置及其制造方法
公开(公告)号：US4007435A
公开(公告)日：1977-02-08
申请号：US464019
申请日：1974-04-25
申请人： Tseng-Ying Tien
发明人： Tseng-Ying Tien
IPC分类号： G01N27/12
CPC分类号： G01N27/12
摘要： An oxygen sensing device particularly suited as a sensor for the exhaust gases of internal combustion engines, the sensing device comprising an electrically insulative ceramic element having bonded on the surface thereof a layer of an oxygen sensing metal oxide, preferably titania, and a pair of electrical leads for the oxygen sensing metal oxide, the device also having a layer of electrical resistance heating material adjacent to the layer of oxygen sensing metal oxide but separated therefrom by a layer of the electrically insulative ceramic, a pair of electrical leads for the electrical resistance heating material, and a layer of ceramic covering the layer of electrical resistance heating material.
摘要翻译：一种特别适合作为内燃机废气传感器的氧气感测装置，该感测装置包括一个电绝缘陶瓷元件，该电绝缘陶瓷元件在其表面上粘合一层氧传感金属氧化物，优选二氧化钛，以及一对电气用于氧传感金属氧化物的引线，该器件还具有与氧感测金属氧化物层相邻的电阻加热材料层，但是由电绝缘陶瓷层分离，一对用于电阻加热的电引线材料和一层覆盖电阻加热材料的陶瓷层。

2. 发明授权

US06124225A Cutting tools and wear resistant articles and material for same 失效
标题翻译：切削刀具和耐磨制品和材料相同
公开(公告)号：US06124225A
公开(公告)日：2000-09-26
申请号：US124658
申请日：1998-07-29
申请人： Tseng-Ying Tien , Zhen-Kun Huang
发明人： Tseng-Ying Tien , Zhen-Kun Huang
IPC分类号： C04B35/597 , C04B35/599
CPC分类号： C04B35/6261 , C04B35/597 , C04B35/64 , C04B35/645 , C04B35/6455 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/36 , C04B2235/3865 , C04B2235/3869 , C04B2235/3878 , C04B2235/3882 , C04B2235/5445 , C04B2235/608 , C04B2235/6587 , C04B2235/766 , C04B2235/767 , C04B2235/77 , C04B2235/785 , C04B2235/786 , C04B2235/788 , C04B2235/79 , C04B2235/80 , C04B2235/96
摘要： A ceramic having a relatively high proportion of an alpha prime SiAlON phase and exhibiting high hardness and toughness. In a particularly preferred embodiment, a cation of Gd is used as a modifying cation.
摘要翻译：具有较高比例的α原子SiAlON相并具有高硬度和韧性的陶瓷。在特别优选的实施方案中，使用Gd的阳离子作为改性阳离子。

3. 发明授权

US4387359A Titania oxygen sensor with chrome oxide compensator 失效
标题翻译：二氧化钛氧传感器与氧化铬补偿器
公开(公告)号：US4387359A
公开(公告)日：1983-06-07
申请号：US226652
申请日：1981-01-21
申请人： Tseng-Ying Tien , David C. Weber , Philip R. Woodruff
发明人： Tseng-Ying Tien , David C. Weber , Philip R. Woodruff
IPC分类号： G01N27/12 , H01L7/00
CPC分类号： G01N27/12
摘要： An oxygen sensor utilizes a chrome oxide compensating resistor (5) in series with a titania sensing resistor (3). The chrome oxide resistor (5) not only compensates for the effects of temperature on the titania sensing (3) resistor, but since it exhibits (p) type behavior while the titania exhibits (n) type behavior in the presence of gaseous oxygen, the sensitivity of the sensor is increased. The resistors (3, 5) can be applied as a film to a substrate (7) or they can be formed as discrete chips. Substantial quantities of alumina and glass can be added to the chrome oxide without affecting oxygen sensitivity although the electrical resistance rises substantially.
摘要翻译：氧传感器利用与二氧化钛感测电阻器（3）串联的氧化铬补偿电阻器（5）。氧化铬电阻器（5）不仅补偿了二氧化钛感测（3）电阻器的温度影响，而且由于它呈现（p）型行为，而二氧化钛在气态氧气存在下表现出（n）型的行为，传感器的灵敏度提高。电阻器（3,5）可以作为薄膜施加到基板（7）上，或者它们可以形成为分立的芯片。可以将大量的氧化铝和玻璃添加到氧化铬中，而不影响氧气的敏感性，尽管电阻显着上升。

4. 发明授权

US3932246A Gas sensor and method of manufacture 失效
标题翻译：气体传感器及其制造方法
公开(公告)号：US3932246A
公开(公告)日：1976-01-13
申请号：US503590
申请日：1974-09-05
申请人： Henry L. Stadler , Tseng-Ying Tien , Michael J. Esper , Donald J. Romine
发明人： Henry L. Stadler , Tseng-Ying Tien , Michael J. Esper , Donald J. Romine
IPC分类号： C04B35/46 , C04B35/632 , F02D41/14 , G01N27/12 , C04B39/12
CPC分类号： F02D41/1455 , C04B35/46 , C04B35/632 , G01N27/12
摘要： A gas sensor, and its method of manufacture, particularly useful as an exhaust gas sensor for an internal combustion engine air/fuel ratio system, is disclosed. The sensor is comprised of a sintered ceramic body of transition metal oxide, such as titania, and includes a pair of spacedapart electrodes. As the partial pressure of oxygen in the gas being sensed varies in response to variations in the inlet air/fuel mixture ratio, the resistance of the ceramic material varies. The active portion of the sensor body is a substantially uniform body of porous ceramic material having a density of less than about 85% of theoretical density and a modulus of rupture in excess of 11,000 psi. The sensor is fabricated from a very pure transition metal oxide powder having a very fine and highly uniform particle size. The transitional metal oxide is selected so that the operating temperature of the resulting device is less than about 75% and preferably less than about 50% of the melting temperature of the metal oxide.
摘要翻译：公开了一种气体传感器及其制造方法，特别可用作内燃机空燃比系统的废气传感器。该传感器由二氧化钛等过渡金属氧化物的烧结陶瓷体组成，并且包括一对间隔开的电极。当被检测气体中的氧的分压响应于入口空气/燃料混合比的变化而变化时，陶瓷材料的电阻变化。传感器主体的主动部分是基本均匀的多孔陶瓷材料体，其密度小于理论密度的约85％，断裂模量超过11,000psi。传感器由非常纯的过渡金属氧化物粉末制成，其具有非常精细和高度均匀的粒度。选择过渡金属氧化物使得所得器件的工作温度小于金属氧化物的熔融温度的约75％，优选小于约50％。

5. 发明授权

US4886768A Toughened ceramics 失效
标题翻译：增韧陶瓷
公开(公告)号：US4886768A
公开(公告)日：1989-12-12
申请号：US120600
申请日：1987-11-13
申请人： Tseng-Ying Tien
发明人： Tseng-Ying Tien
IPC分类号： C04B35/486
CPC分类号： C04B35/486
摘要： Novel partially stabilized zirconia ceramic compositions exhibiting improved toughness comprising: a major component consisting of ZrO.sub.2, a minor stabilizing component Y.sub.2 O.sub.3 and an effective amount of a toughening agent (e.g., Ta.sub.2 O.sub.5). The toughness of the tetragonal zirconia polycrystal (e.g., 96% ZrO.sub.2, 3 mole % Y.sub.2 O.sub.3) can be increased nearly three-fold by replacing 1% of the ZrO.sub.2 with Ta.sub.2 O.sub.5. Empirical equations based on ratios of fundamental lattice parameters (e.g. c/a) quantitatively relating to the stability/instability of tetragonal zirconia oxide are disclosed and used in a novel method for improving the toughness of the ceramic compositions.
摘要翻译：表现出改进韧性的新型部分稳定化的氧化锆陶瓷组合物，包括：由ZrO 2，少量稳定组分Y 2 O 3和有效量的增韧剂（例如Ta 2 O 5）组成的主要组分。通过用Ta 2 O 5代替1％的ZrO 2，四方晶氧化锆多晶体（例如，96％ZrO 2，3摩尔％Y 2 O 3）的韧性可以增加近三倍。基于与四方氧化锆氧化物的稳定性/不稳定性有关的基本晶格参数（例如c / a）的比例的经验方程被公开并用于提高陶瓷组合物的韧性的新方法中。

6. 发明授权

US4533647A Ceramic compositions 失效
标题翻译：陶瓷组合物
公开(公告)号：US4533647A
公开(公告)日：1985-08-06
申请号：US546119
申请日：1983-10-27
申请人： Tseng-Ying Tien
发明人： Tseng-Ying Tien
IPC分类号： C04B35/42 , C04B35/10 , C04B35/119 , C04B35/185 , C04B35/48 , F02B3/06 , C04B35/12
CPC分类号： C04B35/645 , C04B35/10 , C04B35/119 , C04B35/185 , F02B3/06
摘要： Novel transformation toughened ceramic compositions comprising finely divided ZrO.sub.2 -HfO.sub.2 solid solution particles dispersed in a Al.sub.2 O.sub.3 -Cr.sub.2 O.sub.3 (alumina) or 3Al.sub.2 O.sub.3.2SiO.sub.2 -3Cr.sub.2 O.sub.3.2SiO.sub.2 (mullite) solid solution matrix phase. It is found that increased hardness and modulus associated with higher relative Cr.sub.2 O.sub.3 content (e.g. 20 mole %) in the matrix phase and increased fracture toughness associated with higher relative HfO.sub.2 content (e.g. 10 to 20 mole %) in the disperse phase represent viable and improved ceramic compositions. Such transformation toughened ceramic compositions are considered useful in superhot light diesel engine applications, high temperature gas turbines and ultrahigh temperature ceramic heat exchangers.
摘要翻译：包含分散在Al2O3-Cr2O3（氧化铝）或3Al2O3.2SiO2-3Cr2O3.2SiO2（莫来石））固溶体基体相中的细分散的ZrO 2-HfO 2固溶体颗粒的新型转化增韧陶瓷组合物。发现与分散相中较高的相对HfO 2含量（例如10至20摩尔％）相关的基体相中较高的相对Cr 2 O 3含量（例如20摩尔％）和增加的断裂韧性相关的增加的硬度和模量表示可行和改进陶瓷组合物。这种转化增韧的陶瓷组合物被认为在超轻型柴油发动机应用，高温燃气轮机和超高温陶瓷热交换器中是有用的。

7. 发明授权

US3989614A Gas sensor 失效
标题翻译：气体传感器
公开(公告)号：US3989614A
公开(公告)日：1976-11-02
申请号：US539270
申请日：1975-01-08
申请人： Tseng Ying Tien
发明人： Tseng Ying Tien
IPC分类号： G01N27/407 , G01N27/46
CPC分类号： G01N27/4075 , G01N27/4077
摘要： A transducer operative to generate an electrical signal proportional to the partial oxygen pressure in a gas consists of a tube, closed at one end, of zirconia stabilized with yttria. The outer surface of the tube is coated with a porous electronic conductor and a porous platinum layer is coated over the porous conductor so that the platinum contacts the zirconia tubes at the voids in the conductor coating. Electrodes attached to the inner and outer surfaces of the tube sense the potential difference generated across the tube as a result of galvanic action. The open end of the tube is encased within a ceramic cylinder having an outer metal threaded sleeve. Electrodes attached to the inner and outer surfaces of the tube are joined to a connector fixed at the far end of the ceramic tubes. A second embodiment employs a sensor consisting of a transition metal oxide pad and a thermistor pad on a ceramic substrate bonded to a second substrate containing a deposited resistance element so as to hermetically seal the element. The sensor is encased in a ceramic cylinder having an outer metal threaded sleeve.
摘要翻译：用于产生与气体中的部分氧气压力成比例的电信号的换能器由在一端闭合的用氧化钇稳定的氧化锆的管构成。管的外表面涂覆有多孔电子导体，并且多孔铂层涂覆在多孔导体上，使得铂在导体涂层中的空隙处与氧化锆管接触。连接到管的内表面和外表面的电极感测由于电流作用而在管上产生的电位差。管的开口端封装在具有外金属螺纹套筒的陶瓷圆筒内。连接到管的内表面和外表面的电极连接到固定在陶瓷管的远端的连接器。第二实施例使用由过渡金属氧化物焊盘和热敏电阻焊盘构成的传感器，陶瓷衬底上粘合到含有沉积的电阻元件的第二衬底上，以便气密地密封元件。传感器被封装在具有外金属螺纹套筒的陶瓷圆筒中。

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