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    • 4. 发明授权
    • Method of treating nickel-containing etching waste fluid
    • 处理含镍蚀刻废液的方法
    • US5328670A
    • 1994-07-12
    • US854565
    • 1992-03-20
    • Teruhiko HirabayashiYoshiyuki ImagireToshiaki KuriharaEiichi AkiyoshiRyoichi Maekawa
    • Teruhiko HirabayashiYoshiyuki ImagireToshiaki KuriharaEiichi AkiyoshiRyoichi Maekawa
    • C01G49/00C01G53/00C23F1/28C23F1/46C01G49/10C01G53/09
    • C23F1/46Y10S423/01
    • A method of regenerating an etching waste fluid, includes the steps of dissolving HCl gas in an etching waste fluid at a temperature falling within a range of 20.degree. C. to 50.degree. C. and crystallizing NiCl.sub.2 and FeCl.sub.2 crystals, the etching waste fluid containing NiCl.sub.2, FeCl.sub.3, and FeCl.sub.2 and being obtained by etching Ni or an Ni alloy with an etching solution consisting of an aqueous solution containing FeCl.sub.3, distilling a mother liquor at the atmospheric pressure after crystallization and separation thereof to reduce the HCl concentration in the mother liquor, and distilling, at a reduced pressure, a concentrate obtained upon distillation at the atmospheric pressure to further reduce the HCl concentration, thereby obtaining an aqueous solution containing FeCl.sub.3, or bringing the concentrate obtained by distillation at the atmospheric pressure into contact with an iron oxide to cause HCl in the concentrate to react with the iron oxide to further reduce the HCl concentration in the concentrate thereby obtaining the aqueous solution containing FeCl.sub.3 with little HCl.
    • 一种再生蚀刻废液的方法包括以下步骤:将HCl气体溶解在蚀刻废液中,温度范围为20℃至50℃,并结晶NiCl 2和FeCl 2晶体,蚀刻废液含有 NiCl 2,FeCl 3和FeCl 2,并且通过用含有FeCl 3的水溶液的蚀刻溶液蚀刻Ni或Ni合金,在结晶并分离后蒸馏出大气压下的母液,从而降低母液中的HCl浓度 并且在减压下蒸馏在大气压下获得的浓缩物以进一步降低HCl浓度,从而获得含有FeCl 3的水溶液,或将通过蒸馏在大气压下获得的浓缩物与氧化铁接触 使浓缩物中的HCl与氧化铁反应,以进一步降低浓缩物中的HCl浓度 从而获得含少量HCl的FeCl 3水溶液。