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    • 1. 发明申请
    • DIENE-BASED CARBOXYLATE ANION AND SALT THEREOF, AND POLYMERIZABLE OR CURABLE COMPOSITION THEREOF
    • 基于二苯醚的羧酸盐及其盐及其可聚合或可固化的组合物
    • US20130197123A1
    • 2013-08-01
    • US13877751
    • 2011-10-05
    • Tomomasa Kaneko
    • Tomomasa Kaneko
    • C07C57/13C08F136/20
    • C07C57/13C07C59/60C07C69/734C07F5/00C07F7/003C07F7/2224C07F9/005C07F9/94C07F15/025C07F15/045C08F136/20
    • The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.
    • 要求保护的发明提供了一种未经过研究的新化合物,即含有特定结构的二烯羧酸盐阴离子及其盐。 要求保护的发明还可以提供一种易于溶于一般有机溶剂,反应性稀释剂和树脂的二烯羧酸盐阴离子及其盐,特别是其金属盐,在常温下可根据结构处于液态, 具有高聚合性。 这些聚合/固化产生了引入许多离子键和金属的树脂,提供了各种性能,例如硬度,耐擦伤性,抗指纹性,阻气性,水蒸气阻隔性,氧吸收性,紫外线防护 红外线保护,显色和着色,高折射率,附着力,各种催化能力,荧光能力和发光能力,光学放大,分散性和抗静电性能。 此外,阴离子和盐可用于功能性细颗粒和金属纳米颗粒复合材料的原料,也可用于MOD材料。 所要求保护的发明还提供了制备二烯羧酸根阴离子及其盐的有利方法。
    • 5. 发明授权
    • Diene-based carboxylate anion and salt thereof, and polymerizable or curable composition thereof
    • 二烯系羧酸根阴离子及其盐及其可聚合或可固化的组合物
    • US09499466B2
    • 2016-11-22
    • US13877751
    • 2011-10-05
    • Tomomasa Kaneko
    • Tomomasa Kaneko
    • C07C57/13C07C59/60C07F5/00C07F7/00C07F7/22C08F136/20C07C69/734C07F9/00C07F9/94C07F15/02C07F15/04
    • C07C57/13C07C59/60C07C69/734C07F5/00C07F7/003C07F7/2224C07F9/005C07F9/94C07F15/025C07F15/045C08F136/20
    • The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.
    • 要求保护的发明提供了一种未经过研究的新化合物,即含有特定结构的二烯羧酸盐阴离子及其盐。 要求保护的发明还可以提供一种易于溶于一般有机溶剂,反应性稀释剂和树脂的二烯羧酸盐阴离子及其盐,特别是其金属盐,在常温下可根据结构处于液态, 具有高聚合性。 这些聚合/固化产生了引入许多离子键和金属的树脂,提供了各种性能,例如硬度,耐擦伤性,抗指纹性,阻气性,水蒸气阻隔性,氧吸收性,紫外线防护 红外线保护,显色和着色,高折射率,附着力,各种催化能力,荧光能力和发光能力,光学放大,分散性和抗静电性能。 此外,阴离子和盐可用于功能性细颗粒和金属纳米颗粒复合材料的原料,也可用于MOD材料。 所要求保护的发明还提供了制备二烯羧酸根阴离子及其盐的有利方法。
    • 9. 发明申请
    • Alkali-soluble maleimide copolymer and liquid crystal display comprising the same
    • 碱溶性马来酰亚胺共聚物和包含其的液晶显示器
    • US20050074563A1
    • 2005-04-07
    • US10490658
    • 2002-09-24
    • Masahiro TatsuzawaKiyoshi ItoShinji HayashiShunsuke SegaTomonobu SuminoMinoru YamaguchiTomomasa KanekoKenichi Ueda
    • Masahiro TatsuzawaKiyoshi ItoShinji HayashiShunsuke SegaTomonobu SuminoMinoru YamaguchiTomomasa KanekoKenichi Ueda
    • C08F222/40G02F1/1335G03F7/00G03F7/037G03F7/038G03F7/004G02B5/20
    • C08F222/40G02F1/133514G03F7/0007G03F7/037G03F7/0387Y10T428/10
    • It is an object of the present invention to provide an alkali-soluble maleimide-based copolymer excellent in resistance for thermally yellowing, high in hardness, excellent in solubility in solvents and capable of readily forming uniform coat films and, in addition, capable of being satisfactorily dissolved in alkali water when remaining uncured, as well as a pigment dispersion composition comprising such copolymer and an ionizing radiation-curable resin composition comprising such copolymer. Another object of the present invention is to provide a color filter and a liquid crystal display which are formed by using the ionizing radiation-curable resin composition. The present invention is related to an alkali-soluble maleimide-based copolymer which comprises, as essential constituents, 5 to 50% by mass of a maleimide monomer unit which is at least one unit selected from the group consisting of a N-cyclohexylmaleimide monomer unit, a N-benzylmaleimide monomer unit and a substituted N-benzylmaleimide monomer unit, 8 to 30% by mass of the (meth)acrylic acid monomer unit and 30 to 87% by mass of a (meth)acrylic acid ester monomer unit and which satisfies the condition represented by the formula: 0.4×X≦Y≦0.5×X+10  where X is the content, in % by mass, of the N-cyclohexylmaleimide monomer unit, the N-benzylmaleimide monomer unit and the substituted N-benzylmaleimide monomer unit and Y is the content, in % by mass, of the (meth)acrylic acid monomer unit.
    • 本发明的目的是提供一种耐热黄变性,硬度高,在溶剂中溶解性优异并且能够容易地形成均匀涂膜的碱溶性马来酰亚胺基共聚物,并且还能够 保留未固化时,令人满意地溶解在碱水中,以及包含这种共聚物的颜料分散体组合物和包含这种共聚物的电离辐射固化树脂组合物。 本发明的另一个目的是提供一种通过使用电离辐射固化树脂组合物形成的滤色器和液晶显示器。 本发明涉及一种碱溶性马来酰亚胺类共聚物,其中,作为必要成分,含有5〜50质量%的马来酰亚胺单体单元,该单体单元为选自N-环己基马来酰亚胺单体单元 ,N-苄基马来酰亚胺单体单元和取代的N-苄基马来酰亚胺单体单元,8〜30质量%的(甲基)丙烯酸单体单元和30〜87质量%的(甲基)丙烯酸酯单体单元, 满足由下式表示的条件:0.4xX <= Y <= 0.5×X + 10其中X是N-环己基马来酰亚胺单体单元,N-苄基马来酰亚胺单体单元和取代的N-苄基马来酰亚胺的含量(以质量%计) 单体单元,Y为(甲基)丙烯酸单体单元的质量%。