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    • 1. 发明授权
    • Fluorine-based magnetic fluid
    • 氟基磁性液体
    • US5718833A
    • 1998-02-17
    • US784693
    • 1997-01-15
    • Yasushi YamamotoYoshiyuki TakeishiYutaka KoudaTomoko MinagawaTakao Kanno
    • Yasushi YamamotoYoshiyuki TakeishiYutaka KoudaTomoko MinagawaTakao Kanno
    • C07C59/135C08G65/22H01F1/44
    • H01F1/44C07C59/135C08G65/226
    • A fluorine-based magnetic fluid, which comprises (A) fine magnetic particles as dispersed in (D) a perfluoropolyether base oil represented by the following general formula: F�CF(CF.sub.3)CF.sub.2 O!mRf where Rf is a perfluoroalkyl group, by means of (B) a salt of perfluoroether carboxylic acid represented by the following general formula: F�CF(CF.sub.3)CF.sub.2 O!nCF(CF.sub.3)COOM where M is an alkali metal or an ammonium group, and (C) amide compounds of perfluoroether carboxylic acid represented by the following general formula: F�CF(CF.sub.3)CF.sub.2 O!pCF(CF.sub.3)CONH(CH.sub.2)qNH.sub.2, F�CF(CF.sub.3)CF.sub.2 O!pCF(CF.sub.3)CONH(CH.sub.2 CH.sub.2 NH)rH or F�CF(CF.sub.3)CF.sub.2 O!pCF(CF.sub.3)CONH(CH.sub.2 CH.sub.2 NH)rCOCF(CF.sub.3)�OCF.sub.2 CF(CF.sub.3)!pF has a high affinity of the fine magnetic particles toward the perfluoropolyether base oil and is effectively used as a sealing material for vacuum apparatus.
    • 氟系磁性流体,其包含(A)分散在(D)由以下通式表示的全氟聚醚基油中的微细磁性颗粒:F [CF(CF 3)CF 2 O] m R f其中R f为全氟烷基 (B)由以下通式表示的全氟醚羧酸盐:F [CF(CF 3)CF 2 O] n CF(CF 3)COOM,其中M是碱金属或铵基,和(C)全氟醚羧酸的酰胺化合物 由CF(CF 3)CF 2 O] pCF(CF 3)CONH(CH 2)q NH 2,F [CF(CF 3)CF 2 O] p CF(CF 3)CONH(CH 2 CH 2 NH)r H或F [CF(CF 3) CF 2 O] p CF(CF 3)CONH(CH 2 CH 2 NH)rCOCF(CF 3)[OCF 2 CF(CF 3)] pF具有高精细磁性颗粒对全氟聚醚基油的亲和力,并被有效地用作真空装置的密封材料。
    • 2. 发明授权
    • Fluorine-based magnetic fluid
    • 氟基磁性液体
    • US5785882A
    • 1998-07-28
    • US901359
    • 1997-07-28
    • Yasushi YamamotoYoshiyuki TakeishiYutaka KoudaTomoko MinagawaTakao Kanno
    • Yasushi YamamotoYoshiyuki TakeishiYutaka KoudaTomoko MinagawaTakao Kanno
    • H01F1/44
    • H01F1/44H01F1/445
    • A fluorine-based magnetic fluid, which comprises (A) fine magnetic particles as dispersed in (D) a perfluoropolyether base oil represented by the following general formula: F�CF(CF.sub.3)CF.sub.2 O!mRf where Rf is a perfluoroalkyl group by means of general formulae: (B.sub.1){F�CF(CF.sub.3)CF.sub.2 O!nCF(CF.sub.2) (Y)v(R)wO}tPO(OM)u, (B.sub.2)F�CF(CF.sub.3)CF.sub.2 O!nCF(CF.sub.3)YRSO.sub.2 M or (B.sub.3)F�CF(CF.sub.3)CF.sub.2 O!nCF(CF.sub.3)X(RO)sCH.sub.2 COOM where R is a divalent organic group; Y is a COO group or CONH group; X is a COO group or CH.sub.2 O group; and M is a hydrogen group, an alkali metal, an alkaline earth metal or an ammonium group and perfluoroether carboxylic acid amide compounds represented by the following general formulae: (C.sub.1)F�CF(CF.sub.3)CF.sub.2 O!pCF(CF.sub.3)CONH(CH.sub.2)qNH.sub.2, (C.sub.2)F�CF(CF.sub.3)CF.sub.2 O!pCF(CF.sub.3)CONH(CH.sub.2 CH.sub.2 NH)rHor (C.sub.3)F�CF(CF.sub.3)CF.sub.2 O!pCF(CF.sub.3)CONH(CH.sub.2 CH.sub.2 NH)rCOCF(CF.sub.3)�OCF.sub.2 CF(CF.sub.2 )!pF has an increased affinity of the fine magnetic particles toward the perfluoropolyether base oil and is effectively used as a sealing material for vacuum apparatus.
    • 氟系磁性流体,其包含(A)分散在(D)由以下通式表示的全氟聚醚基油中的细磁性颗粒:F [CF(CF 3)CF 2 O] m R f其中R f是全氟烷基,通过 通式(B1){F [CF(CF3)CF2O] nCF(CF2)(Y)v(R)wO} tPO(OM)u,(B2)F [CF(CF3)CF2O] nCF(CF3) 或(B3)F [CF(CF 3)CF 2 O] n CF(CF 3)X(RO)s CH 2 COOM,其中R是二价有机基团; Y是COO组或CONH组; X是COO基团或CH 2 O基团; (C1)F [CF(CF3)CF2O] pCF(CF3)CONH(CH2)的化合物,M为氢基,碱金属,碱土金属或铵基,全氟醚羧酸酰胺化合物 )CF(CF 3)CONH(CH 2 CH 2 NH)r COCF(CF 3)[OCF 2 CF(CF 3)CF 2 CF 2 CF 2 CF 2) CF2)] pF具有增加的细磁粒子对全氟聚醚基油的亲和性,并且有效地用作真空装置的密封材料。
    • 3. 发明授权
    • Fluorine-based magnetic fluid
    • 氟基磁性液体
    • US5738802A
    • 1998-04-14
    • US800784
    • 1997-02-14
    • Yasushi YamamotoYoshiyuki TakeishiYutaka KoudaTomoko MinagawaTakao Kanno
    • Yasushi YamamotoYoshiyuki TakeishiYutaka KoudaTomoko MinagawaTakao Kanno
    • C07C59/135C08G65/22C08G65/337C09K3/10H01F1/44
    • C08G65/337C07C59/135C08G65/226C09K3/1009H01F1/44H01F1/445
    • A fluorine-based magnetic fluid, which comprises (A) fine magnetic particles dispersed in (D) a perfluoropolyether base oil represented by the following general formula: F(CF(CF.sub.3)CF.sub.2 O).sub.m Rf where Rf is a perfluoroalkyl group, by means of (B) a perfluoroether carboxylic acid or salt thereof represented by the following general formula: F(CF(CF.sub.3)CF.sub.2 O).sub.n CF(CF.sub.3)COOM where M is a hydrogen atom, an alkali metal or an ammonium group, and (C) a perfluoroether compound represented by the following general formula: F(CF(CF.sub.3)CF.sub.2 O).sub.p CF(CF.sub.3)X(RO).sub.q CH.sub.2 COOM', F(CF(CF.sub.3)CF.sub.2 O).sub.p CF(CF.sub.3)(Y).sub.r R'OSO.sub.3 M' or (F(CF(CF.sub.3)CF.sub.2 O).sub.p CF(CF.sub.3)(Y).sub.v (R).sub.w O).sub.t PO(OM').sub.u. Fluorine-based magnetic fluid has a high affinity of the fine magnetic particles toward the perfluoropolyether base oil and is effectively used as a sealing material for vacuum apparatus.
    • 氟系磁性流体,其包含(A)分散在(D)由以下通式表示的全氟聚醚基油中的细磁性颗粒:F(CF(CF 3)CF 2 O)m R f其中Rf是全氟烷基,通过( B)由以下通式表示的全氟醚羧酸或其盐:F(CF(CF 3)CF 2 O)n CF(CF 3)COOM其中M是氢原子,碱金属或铵基,和(C)全氟醚化合物 由(CF(CF 3)CF 2 O)p CF(CF 3)X(RO)q CH 2 COOM',F(CF(CF 3)CF 2 O)p CF(CF 3)(Y)r R'OSO 3 M'或(F (CF 3)CF 2 O)pCF(CF 3)(Y)v(R)w O)t PO(OM')u。基于氟的磁性流体具有高的细磁粒子对全氟聚醚基油的亲和力, 真空设备用密封材料。