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1. 发明申请

US20110245414A1 Copolymerizable (Meth)Acrylic Acid Esters 失效
标题翻译：可共聚（甲基）丙烯酸酯
公开(公告)号：US20110245414A1
公开(公告)日：2011-10-06
申请号：US13132638
申请日：2009-11-26
申请人： Ronald Klagge , Thomas Schliwka , Uwe Held , Thomas Mausberg , Katharina Hömberg , Stefan Busch , Shailesh C. Shah
发明人： Ronald Klagge , Thomas Schliwka , Uwe Held , Thomas Mausberg , Katharina Hömberg , Stefan Busch , Shailesh C. Shah
IPC分类号： C08F2/30 , C08F120/18 , C07C69/54
CPC分类号： C08F2/24 , C07F9/091 , C08F220/38 , C08F230/02 , C08G65/2615 , C08G65/2648 , C08G65/327
摘要： The invention relates to a copolymerizable emulsifier comprising (meth)acrylic acid esters, selected from compounds of the general formula (1) and (II), where: A is an acrylic group having 3 to 40 carbon atoms, x and y independently of each other are a hydrogen group or a methyl group, B is hydrogen or a sulfate or phosphate group, and n a number in the range of 0 to 40. The invention further relates to methods of using said copolymerizable emulsifier in the emulsion polymerization of olefinically unsaturated monomers to prepare polymers.
摘要翻译：本发明涉及包含（甲基）丙烯酸酯的可共聚的乳化剂，其选自通式（1）和（II）的化合物，其中：A为具有3-40个碳原子的丙烯酸基，x和y各自独立地为另一个是氢基或甲基，B是氢或硫酸根或磷酸基，na数在0至40的范围内。本发明还涉及在烯属不饱和单体的乳液聚合中使用所述可共聚的乳化剂的方法以制备聚合物。

2. 发明申请

US20080262132A1 NONIONIC SURFACTANTS 审中-公开
标题翻译：非离子表面活性剂
公开(公告)号：US20080262132A1
公开(公告)日：2008-10-23
申请号：US12048287
申请日：2008-03-14
申请人： Thorsten Roloff , Katharina Hoemberg , Thomas Schliwka , Thomas Mausberg , Wolfgang H. Breuer , Doug Rhubright , Mike Wiggins
发明人： Thorsten Roloff , Katharina Hoemberg , Thomas Schliwka , Thomas Mausberg , Wolfgang H. Breuer , Doug Rhubright , Mike Wiggins
IPC分类号： C08K5/1515
CPC分类号： C08F2/30 , C08K5/06
摘要： A nonionic surfactant for emulsion polymerization is provided, and includes products from the addition of 3 to 20 mols of ethylene and/or propylene oxide onto 1 mol of one or more diterpene alcohols selected from the group consisting of abietyl alcohol, dihydroabietyl alcohol, tetrahydroabietyl alcohol and dehydroabietyl alcohol, wherein the surfactant is included as an emulsifier in a polymer emulsion. A method for stabilizing an emulsion polymer or polymer dispersion is also provided, including the steps of adding an emulsifier, to an emulsion polylmer or polymer dispersion comprising monomers, in an amount of from about 0.5 to about 10% by weight, based on the total quantity of monomers present, the emulsifier including products from the addition of 3 to 20 mols of ethylene and/or propylene oxide onto 1 mol of one or more diterpene alcohols selected from the group consisting of abietyl alcohol, dihydroabietyl alcohol, tetrahydroabietyl alcohol and dehydroabietyl alcohol.
摘要翻译：提供了用于乳液聚合的非离子表面活性剂，并且包括在1摩尔一种或多种选自以下的二萜烯醇中加入3至20摩尔的乙烯和/或环氧丙烷的产物：选自二醇，二氢枞醇，四氢枞醇和脱氢松香醇，其中表面活性剂作为乳化剂包含在聚合物乳液中。还提供了一种用于稳定乳液聚合物或聚合物分散体的方法，包括以下步骤：将乳化剂加入到包含单体的乳液聚合物或聚合物分散体中，其量为约0.5至约10重量％存在的单体的量，乳化剂包括从1至1摩尔选自下列的一种或多种二萜醇中加入3-20摩尔的乙烯和/或环氧丙烷的产物：二醇，二氢枞醇，四氢松香醇和脱氢枞醇。

3. 发明授权

US08183320B2 Copolymerizable surfactants (1) 有权
标题翻译：可共聚表面活性剂（1）
公开(公告)号：US08183320B2
公开(公告)日：2012-05-22
申请号：US12824394
申请日：2010-06-28
申请人： Ronald Klagge , Uwe Held , Thomas Mausberg , Katharina Hömberg , Thomas Schliwka
发明人： Ronald Klagge , Uwe Held , Thomas Mausberg , Katharina Hömberg , Thomas Schliwka
IPC分类号： C08L31/06
CPC分类号： C08F2/24 , C08F222/20
摘要： The invention is directed to the use of maleic esters selected from compounds of formulae (I), (II) and (III), as copolymerizable emulsifiers in the emulsion polymerization of olefinically unsaturated monomers, in which A is a C3-C40 alkyl group; X, Y and Z independently are hydrogen or methyl; B and D independently are sulfate, phosphate or hydrogen; n and p independently are numbers in the range from 0 to 40; and m is a number in the range from 2 to 40.
摘要翻译：本发明涉及在烯属不饱和单体的乳液聚合中使用选自式（I），（II）和（III）的化合物的马来酸酯作为可共聚的乳化剂，其中A为C 3 -C 40烷基; X，Y和Z独立地是氢或甲基; B和D独立地是硫酸根，磷酸根或氢原子; n和p独立地为0至40的数字; m为2〜40的数。

4. 发明申请

US20120029131A1 Use Of Nonionic Surfactants As Emulsifiers For Emulsion Polymerization (III) 失效
标题翻译：用作乳液聚合乳化剂的非离子表面活性剂（III）
公开(公告)号：US20120029131A1
公开(公告)日：2012-02-02
申请号：US13259846
申请日：2010-03-13
申请人： Markus Scherer , Thomas Schliwka , Katharina Hömberg , Uwe Held , Thomas Mausberg , Ronald Klagge
发明人： Markus Scherer , Thomas Schliwka , Katharina Hömberg , Uwe Held , Thomas Mausberg , Ronald Klagge
IPC分类号： C08K9/04 , C08L9/10 , C08L13/02 , C08L19/02
CPC分类号： C08F2/30
摘要： The invention relates to the use of aqueous solutions of nonionic surfactants as gel phase free emulator systems for the emulsion polymerization, wherein said nonionic surfactants are chosen from the group (a) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, and (b) of the addition products from 1 to 40 mol ethylene and/or propylene oxide per mol of allyl alcohol, wherein the OH-group of said addition products is end-capped in the sense that it is substituted by a group OR, wherein R is an alkyl group with 1 to 20 C-atoms, which can be saturated or unsaturated, straight chained or branched.
摘要翻译：本发明涉及非离子表面活性剂的水溶液用作乳液聚合的无凝胶相模拟器系统，其中所述非离子表面活性剂选自1-40mol乙烯和/或环氧丙烷加成产物（a）组每摩尔烯丙醇，和（b）每摩尔烯丙醇1至40摩尔乙烯和/或环氧丙烷的加成产物，其中所述加成产物的OH-基是在上述意义上被封端被OR取代，其中R是具有1-20个碳原子的烷基，其可以是饱和或不饱和的，直链或支链的。

5. 发明授权

US08642698B2 Copolymerizable (meth)acrylic acid esters 失效
标题翻译：可共聚（甲基）丙烯酸酯
公开(公告)号：US08642698B2
公开(公告)日：2014-02-04
申请号：US13132638
申请日：2009-11-26
申请人： Ronald Klagge , Thomas Schliwka , Uwe Held , Thomas Mausberg , Katharina Hömberg , Stefan Busch , Shailesh C. Shah
发明人： Ronald Klagge , Thomas Schliwka , Uwe Held , Thomas Mausberg , Katharina Hömberg , Stefan Busch , Shailesh C. Shah
IPC分类号： C08F2/30 , C08F120/18 , C07C69/54
CPC分类号： C08F2/24 , C07F9/091 , C08F220/38 , C08F230/02 , C08G65/2615 , C08G65/2648 , C08G65/327
摘要： The invention relates to a copolymerizable emulsifier comprising (meth)acrylic acid esters, selected from compounds of the general formula (1) and (II), where: A is an acrylic group having 3 to 40 carbon atoms, x and y independently of each other are a hydrogen group or a methyl group, B is hydrogen or a sulfate or phosphate group, and n a number in the range of 0 to 40. The invention further relates to methods of using said copolymerizable emulsifier in the emulsion polymerization of olefinically unsaturated monomers to prepare polymers.
摘要翻译：本发明涉及包含（甲基）丙烯酸酯的可共聚的乳化剂，其选自通式（1）和（II）的化合物，其中：A为具有3-40个碳原子的丙烯酸基，x和y各自独立地为另一个是氢基或甲基，B是氢或硫酸根或磷酸基，na数在0至40的范围内。本发明还涉及在烯属不饱和单体的乳液聚合中使用所述可共聚的乳化剂的方法以制备聚合物。

6. 发明授权

US08519071B2 Low-viscosity aqueous compositions 失效
标题翻译：低粘度水性组合物
公开(公告)号：US08519071B2
公开(公告)日：2013-08-27
申请号：US13298468
申请日：2011-11-17
申请人： Thomas Schliwka , Ronald Klagge , Uwe Held , Thomas Mausberg
发明人： Thomas Schliwka , Ronald Klagge , Uwe Held , Thomas Mausberg
IPC分类号： C08F2/00 , C08F210/00 , C08F20/06 , C08F118/02 , B01F3/08
CPC分类号： C08F2/26 , C08F212/08 , C08F218/08 , C08F218/10 , C08F220/06 , C08F2220/1825 , C08F220/14
摘要： Provided are low-viscosity aqueous compositions comprising compounds of Formula (III) and (IV). These compositions are prepared by jointly ethoxylating a mixture of the compounds of the Formula (I) and (II) to give an intermediate which represents a mixture of compounds of Formulas (I*) and (II*). The intermediate is then converted by sulfation or phosphation and subsequent neutralization, into an aqueous composition comprising the compounds of Formula (III) and (IV). The aqueous compositions are notable for having, at 20° C., a Brookfield viscosity of 3000 mPas or less (measured at 20° C. with spindle 2 and 20 rpm), and are suitable as emulsifiers for emulsion polymerization.
摘要翻译：提供包含式（III）和（IV）的化合物的低粘度水性组合物。这些组合物通过将式（I）和（II）的化合物的混合物共聚乙氧基化以得到表示式（I *）和（II *）的化合物的混合物的中间体来制备。然后通过硫酸化或磷酸化并随后中和将中间体转化成包含式（III）和（IV）的化合物的水性组合物。含水组合物在20℃下的Brookfield粘度为3000mPa·s以下（在20℃下用纺锤2和20rpm测量）是显着的，并且适用于乳液聚合的乳化剂。

7. 发明申请

US20090292072A1 Use of nonionic surfactants as emulsifiers for emulsion polymerization 审中-公开
标题翻译：使用非离子表面活性剂作乳液聚合乳化剂
公开(公告)号：US20090292072A1
公开(公告)日：2009-11-26
申请号：US12469226
申请日：2009-05-20
申请人： Ronald Klagge , Markus Scherer , Thomas Schliwka , Katharina Homberg , Uwe Held , Thomas Mausberg
发明人： Ronald Klagge , Markus Scherer , Thomas Schliwka , Katharina Homberg , Uwe Held , Thomas Mausberg
IPC分类号： C08F2/22
CPC分类号： B01F17/0021 , B01F17/0028 , C08F2/26
摘要： Disclosed is the use of nonionic surfactants as emulsifiers for emulsion polymerization, one or more nonionic surfactants being selected from the group consisting of (a) addition products of from 1 to 40 mol of ethylene oxide and/or propylene oxide per mole onto allyl alcohol, and (b) addition products of from 1 to 40 mol of ethylene oxide and/or propylene oxide per mole onto allyl alcohol, where the OH group of these addition products is terminally capped in the sense that it is replaced by a group OR, where R is an alkyl group having 1 to 20 carbon atoms which may be saturated or unsaturated, straight-chain or branched.
摘要翻译：公开了使用非离子表面活性剂作为乳液聚合的乳化剂，一种或多种非离子表面活性剂选自（a）每摩尔1至40摩尔环氧乙烷和/或环氧丙烷加成产物至烯丙醇，和（b）每摩尔1至40摩尔环氧乙烷和/或环氧丙烷加成的烯丙醇，其中这些加成产物的OH基团被末端封端，其被替换为OR，其中 R是具有1至20个碳原子的烷基，其可以是饱和或不饱和的，直链或支链的。

8. 发明申请

US20130317190A1 COPOLYMERIZABLE SURFACTANTS 审中-公开
标题翻译：可共聚表面活性剂
公开(公告)号：US20130317190A1
公开(公告)日：2013-11-28
申请号：US13979770
申请日：2011-10-08
申请人： Thomas Schliwka , Thomas Mausberg , Uwe Held , Ronald Klagge , Stefan Busch , Markus Scherer
发明人： Thomas Schliwka , Thomas Mausberg , Uwe Held , Ronald Klagge , Stefan Busch , Markus Scherer
IPC分类号： C07D303/48 , C08F224/00 , C07F9/655
CPC分类号： C07D303/48 , C07F9/65502 , C08F2/24 , C08F2/26 , C08F224/00
摘要： The invention relates to the use of compounds of the formula (I), R—CH(O—(AO)mX)—CH2—O—(AO)—CH2—CH═CH2, where: R denotes an alkyl radical which has 8 to 18 carbon atoms and can be saturated or unsaturated, straight-chain or branched; X denotes a sulfate or phosphate group or hydrogen; (AO) denotes an alkylene oxide unit, selected from the group consisting of ethylene oxide, propylene oxide or butylene oxide; n denotes a number in the range of 0 to 50; and m denotes zero or a number in the range of 1 to 30; as copolymerizable emulsifiers in the emulsion polymerization of olefinically unsaturated monomers.
摘要翻译：本发明涉及式（I），R-CH（O-（AO）m X）-CH 2 -O-（AO）-CH 2 -CH = CH 2的化合物的用途，其中：R表示具有 8至18个碳原子，可以是饱和或不饱和的，直链或支链的; X表示硫酸根或磷酸基或氢; （AO）表示选自环氧乙烷，环氧丙烷或环氧丁烷的环氧烷单元; n表示0〜50的范围的数; m表示0或1〜30的数; 作为烯属不饱和单体的乳液聚合中的可共聚的乳化剂。

9. 发明申请

US20120227626A1 Preparations Of Solid Material 审中-公开
标题翻译：固体材料的制备
公开(公告)号：US20120227626A1
公开(公告)日：2012-09-13
申请号：US13508601
申请日：2010-11-02
申请人： Sascha Oestreich , Ronald Klagge , Shailesh C. Shah , Harald Frommelius , Thomas Schliwka
发明人： Sascha Oestreich , Ronald Klagge , Shailesh C. Shah , Harald Frommelius , Thomas Schliwka
IPC分类号： C09D5/00
CPC分类号： C09D17/001 , C09B67/0089 , C09D5/027 , C09D7/45
摘要： Nonionic surfactants selected from the group consisting of (a) the addition products of 1 to 40 mol of alkylene oxide per mol of allyl alcohol wherein the alkylene oxide is selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide and styrene oxide and (b) the addition products of 1 to 40 mol of alkylene oxide per mol of allyl alcohol wherein the alkylene oxide is selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide and styrene oxide, wherein the OH group of these addition products is end group capped in the sense that it is replaced by an OR group, wherein R is an alkyl radical having 1 to 20 carbon atoms, which may be saturated or unsaturated, straight chain or branched, are useful as dispersants in the production of preparations wherein one or more solid materials are dispersed in a liquid medium.
摘要翻译：选自以下的非离子表面活性剂：（a）每摩尔烯丙醇中1至40摩尔环氧烷烃的加成产物，其中烯化氧选自环氧乙烷，环氧丙烷，环氧丁烷和氧化苯乙烯，以及（b）每摩尔烯丙醇中1至40摩尔烯化氧的加成产物，其中环氧烷选自环氧乙烷，环氧丙烷，环氧丁烷和氧化苯乙烯，其中这些加成产物的OH基团是由OR基团取代的意义上的末端基团，其中R是具有1至20个碳原子的烷基，其可以是饱和或不饱和的，直链或支链的，可用作生产制剂中的分散剂其中一种或多种固体材料分散在液体介质中。

10. 发明申请

US20100331486A1 COPOLYMERIZABLE SURFACTANTS (1) 有权
标题翻译：可共聚表面活性剂（1）
公开(公告)号：US20100331486A1
公开(公告)日：2010-12-30
申请号：US12824394
申请日：2010-06-28
申请人： Ronald Klagge , Uwe Held , Thomas Mausberg , Katharina Hömberg , Thomas Schliwka
发明人： Ronald Klagge , Uwe Held , Thomas Mausberg , Katharina Hömberg , Thomas Schliwka
IPC分类号： C08L33/14
CPC分类号： C08F2/24 , C08F222/20
摘要： The invention is directed to the use of maleic esters selected from compounds of formulae (I), (II) and (III), as copolymerizable emulsifiers in the emulsion polymerization of olefinically unsaturated monomers, in which A is a C3-C40 alkyl group; X, Y and Z independently are hydrogen or methyl; B and D independently are sulfate, phosphate or hydrogen; n and p independently are numbers in the range from 0 to 40; and m is a number in the range from 2 to 40.
摘要翻译：本发明涉及在烯属不饱和单体的乳液聚合中使用选自式（I），（II）和（III）的化合物的马来酸酯作为可共聚的乳化剂，其中A为C 3 -C 40烷基; X，Y和Z独立地是氢或甲基; B和D独立地是硫酸根，磷酸根或氢原子; n和p独立地为0至40的数字; m为2〜40的数。

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