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    • 1. 发明授权
    • Recovery of sodium aluminate from high-silica aluminous materials
    • 从高硅铝质材料回收铝酸钠
    • US3998927A
    • 1976-12-21
    • US623930
    • 1975-10-20
    • Lawrence Keith HudsonThomas G. Swansiger
    • Lawrence Keith HudsonThomas G. Swansiger
    • C01F7/06
    • C01F7/06
    • An improved process is provided for the recovery of sodium aluminate crystallized from a digest of caustic and lime with high-silica aluminous materials. The digest solution is concentrated by evaporation and then seeded with Na.sub.2 Al.sub.2 O.sub.4.2.5H.sub.2 O crystals to crystallize alumina from the solution as Na.sub.2 Al.sub.2 O.sub.4.2.5H.sub.2 O. The crystals are then separated from the mother liquor solution by filtration or centrifugation. The crystals are then washed with a solution having a lower caustic content than the mother liquor and an alumina concentration of about 50 grams per liter to remove any mother liquor remaining on the crystals. The sodium aluminate crystals are used as a feed for a subsequent Bayer processing step.
    • 提供了一种改进的方法,用于回收由高硅铝质材料从苛性碱和石灰的消化物中结晶的铝酸钠。 将消化液通过蒸发浓缩,然后用Na 2 Al 2 O 4·2.5H 2 O晶体接种,以Na 2 Al 2 O 4·2.5H 2 O从溶液中结晶氧化铝。 然后通过过滤或离心将晶体与母液溶液分离。 然后用比母液低的苛性碱溶液和约50克/升的氧化铝浓度的溶液洗涤晶体以除去留在晶体上的任何母液。 铝酸钠晶体用作随后的拜耳加工步骤的进料。