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1. 发明授权

US6063882A Long-chain dialkylmagnesium, its preparation process and applications 失效
标题翻译：长链二烷基镁，其制备方法和应用
公开(公告)号：US6063882A
公开(公告)日：2000-05-16
申请号：US106120
申请日：1998-06-29
申请人： Jean-Francois Pelletier , Karel Bujadoux , Xavier Olonde , Emmanuel Adisson , Andre Mortreux , Thomas Chenal
发明人： Jean-Francois Pelletier , Karel Bujadoux , Xavier Olonde , Emmanuel Adisson , Andre Mortreux , Thomas Chenal
IPC分类号： C07C51/15 , C07F3/02 , C08F4/44 , C08F4/60 , C08F10/00 , C08F20/06 , C08F110/02 , C08F118/02 , C08F210/00 , C08F210/02 , C08F11/02
CPC分类号： C07F3/02 , C07C51/15 , C08F10/00 , C08F110/02 , C08F210/02
摘要： This dialkylmagnesium is represented by the formula R--(CH.sub.2 --CH.sub.2).sub.n --Mg--(CH.sub.2 --CH.sub.2).sub.n' --R', (E--O--E').sub.x, where R and R' each independently represent a C.sub.1 -C.sub.20 hydrocarbon residue, branched or not, substituted or not, of the alkyl, cycloalkyl or aralkyl type; n and n', identical or substantially identical, represent an average number of --CH.sub.2 --CH.sub.2 -- linkages such that the average number of carbon atoms in each of the two chains borne by Mg is greater than 20; E and E', identical or different, each represent an alkyl radical, linear or cyclical, branched or not; and 0.ltoreq.x.ltoreq.2, x being the average value of the number of moles of E--O--E' ether complexed to the dialkylmagnesium. In order to prepare a dialkylmagnesium of this type, ethylene is polymerized in an anhydrous, de-oxygenated hydrocarbonaceous solution by means of a catalyst Cp*.sub.2 MCl.sub.2 Li(OEt.sub.2).sub.2 (Cp*=a pentamethylcyclopentadienyl ligand; M=scandium, yttrium or a metal of the lanthanide series; Et=ethyl), in the presence of a dialkylmagnesium, soluble in the solvent, of the formula R--Mg--R', (E--O--E').sub.x, where R, R', E, E' and x are as defined above, as a chain-transfer agent, and the reaction is stopped before the polydispersity of the polymer product obtained exceeds 2, preferably before it exeeds 1.5.
摘要翻译：该二烷基镁由式R-（CH 2 -CH 2）n-Mg-（CH 2 -CH 2）n'-R'，（EO-E'）x表示，其中R和R'各自独立地表示C1-C20烃烷基，环烷基或芳烷基的残基，支链或非取代的; n和n'相同或基本上相同，表示-CH2-CH2-键的平均数，使得由Mg承载的两个链中的每个链中的平均碳原子数大于20; E和E'相同或不同，各自表示直链或环状，支链或不支链的烷基; 和0≤x≤2，x是与二烷基镁络合的E-O-E'醚的摩尔数的平均值。为了制备这种二烷基镁，乙烯通过催化剂Cp * 2MCl2Li（OEt2）2（Cp * =五甲基环戊二烯基配体; M =钪，钇或金属）在无水，脱氧的含烃溶液中聚合的镧系元素; Et =乙基），在可溶于溶剂的二烷基镁存在下，式R-Mg-R'（EO-E'）x，其中R，R'，E，E' 和x如上所定义，作为链转移剂，并且在获得的聚合物产物的多分散性超过2之前优选在其超过1.5之前停止反应。

2. 发明授权

US5779942A Long-chain dialkylmagnesium, its preparation process and applications 失效
标题翻译：长链二烷基镁，其制备方法和应用
公开(公告)号：US5779942A
公开(公告)日：1998-07-14
申请号：US628373
申请日：1996-04-05
申请人： Jean-Fran.cedilla.ois Pelletier , Karel Bujadoux , Xavier Olonde , Emmanuel Adisson , Andre Mortreux , Thomas Chenal
发明人： Jean-Fran.cedilla.ois Pelletier , Karel Bujadoux , Xavier Olonde , Emmanuel Adisson , Andre Mortreux , Thomas Chenal
IPC分类号： C07C51/15 , C07F3/02 , C08F4/44 , C08F4/60 , C08F10/00 , C08F20/06 , C08F110/02 , C08F118/02 , C08F210/00 , C08F210/02
CPC分类号： C07F3/02 , C07C51/15 , C08F10/00 , C08F110/02 , C08F210/02
摘要： This dialkylmagnesium is represented by the formula R--(CH.sub.2 --CH.sub.2).sub.n --Mg--(CH.sub.2 --CH.sub.2).sub.n' --R', (E--O--E').sub.x, where R and R' each independently represent a C.sub.1 -C.sub.20 hydrocarbon residue, branched or not, substituted or not, of the alkyl, cycloalkyl or aralkyl type; n and n', identical or substantially identical, represent an average number of --CH.sub.2 --CH.sub.2 -- linkages such that the average number of carbon atoms in each of the two chains borne by Mg is greater than 20; E and E', identical or different, each represent an alkyl radical, linear or cyclical, branched or not; and 0.ltoreq.x.ltoreq.2, x being the average value of the number of moles of E--O--E' ether complexed to the dialkylmagnesium. In order to prepare a dialkylmagnesium of this type, ethylene is polymerized in an anhydrous, de-oxygenated hydrocarbonaceous solution by means of a catalyst Cp*.sub.2 MCl.sub.2 Li(OEt.sub.2).sub.2 (Cp*=a pentamethylcyclopentadienyl ligand; M=scandium, yttrium or a metal of the lanthanide series; Et=ethyl), in the presence of a dialkylmagnesium, soluble in the solvent, of the formula R--Mg--R', (E--O--E').sub.x, where R, R', E, E' and x are as defined above, as a chain-transfer agent, and the reaction is stopped before the polydispersity of the polymer product obtained exceeds 2, and preferably before it exceeds 1.5.
摘要翻译：该二烷基镁由式R-（CH 2 -CH 2）n-Mg-（CH 2 -CH 2）n'-R'，（EO-E'）x表示，其中R和R'各自独立地表示C1-C20烃烷基，环烷基或芳烷基的残基，支链或非取代的; n和n'相同或基本上相同，表示-CH2-CH2-键的平均数，使得由Mg承载的两个链中的每个链中的平均碳原子数大于20; E和E'相同或不同，各自表示直链或环状，支链或不支链的烷基; 和0≤x≤2，x是与二烷基镁络合的E-O-E'醚的摩尔数的平均值。为了制备这种二烷基镁，乙烯通过催化剂Cp * 2MCl2Li（OEt2）2（Cp * =五甲基环戊二烯基配体; M =钪，钇或金属）在无水，脱氧的含烃溶液中聚合的镧系元素; Et =乙基），在可溶于溶剂的二烷基镁存在下，式R-Mg-R'（EO-E'）x，其中R，R'，E，E' 和x如上所定义，作为链转移剂，并且在获得的聚合物产物的多分散性超过2，优选超过1.5之前停止反应。

3. 发明申请

US20140200313A1 METHOD FOR PREPARING DIALKYL MAGNESIUM COMPOUNDS BY ETHYLENE POLYMERISATION AND USES THEREOF 审中-公开
标题翻译：通过乙烯聚合制备二烷基镁化合物的方法及其用途
公开(公告)号：US20140200313A1
公开(公告)日：2014-07-17
申请号：US14234185
申请日：2012-07-20
申请人： Thomas Chenal , Andre Mortreux , Marc Visseaux
发明人： Thomas Chenal , Andre Mortreux , Marc Visseaux
IPC分类号： C08F255/02 , C08G85/00 , C08F236/08 , C08F110/02 , C08F236/06
CPC分类号： C08F255/02 , C08F10/00 , C08F110/02 , C08F236/06 , C08F236/08 , C08G85/004 , C08F4/545
摘要： A process for the preparation by ethylene polymerization of at least one dialkyl magnesium compound of formula R—(CH2—CH2)n—Mg—(CH2—CH2)m—R′ in which R and R′, identical or different, represent aryl, benzyl, allyl or alkyl groups and in which the integers n and m, identical or different, represent average —CH2—CH2— chain formation numbers greater than 1, the process including a single stage of mixing the following components: at least one ligand or one ligand precursor, at least one rare earth salt, at least one dialkyl magnesium compound of formula R—Mg—R′, and ethylene, in a medium allowing contact between the components of the above mixture.
摘要翻译：至少一种式R-（CH 2 -CH 2）n-Mg-（CH 2 -CH 2）m -R'的二烷基镁化合物的乙烯聚合制备方法，其中R和R'相同或不同，表示芳基苄基，烯丙基或烷基，其中n和m相同或不同的整数表示大于1的平均-CH 2 -CH 2 - 链形成数，所述方法包括单次混合以下组分：至少一种配体或一种配体前体，至少一种稀土盐，至少一种式R-Mg-R'的二烷基镁化合物和乙烯，在允许上述混合物组分之间接触的介质中。

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