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    • 1. 发明授权
    • Radiation curable coating compositions
    • 可辐射固化涂料组合物
    • US6069187A
    • 2000-05-30
    • US956233
    • 1997-10-22
    • Nubuo KusumotoKenji SekoTetsuya KoishiharaAtsushi ShiodaToru Hayase
    • Nubuo KusumotoKenji SekoTetsuya KoishiharaAtsushi ShiodaToru Hayase
    • C08F2/46C08F220/28C09D4/00C09D4/06
    • C09D4/00C08F220/28C09D4/06
    • A coating composition which comprises (A) an actinic radiation curable resin, which is the ring-opening addition reaction product of (a) a polyester resin having hydroxyl functionality and (b) a compound having both a cyclic ether group and a (meth)acryloyl group, and preferably (B) at least one compound having at least one radical-polymerizable unsaturated group in a molecule. The composition also preferably comprises (C) a photopolymerization initiator and (D) photosensitizer. A process for obtaining the composition and the coating of metal substrates are also disclosed, as well as coated metal substrates that are particularly useful as cans for beverages, soft drinks, juices, and other food products. The coating compositions and the resulting cured coatings and coated substrates exhibit improved processability, adhesivity, hardness, mar resistance, appearance and retort resistance.
    • 一种涂料组合物,其包含(A)光化射线可固化树脂,其是(a)具有羟基官能团的聚酯树脂和(b)具有环醚基和(甲基)丙烯酸酯的化合物的开环加成反应产物, 丙烯酰基,优选(B)分子中具有至少一个自由基聚合性不饱和基团的至少一种化合物。 组合物还优选包含(C)光聚合引发剂和(D)光敏剂。 还公开了用于获得金属基材的组合物和涂层的方法,以及作为饮料,软饮料,果汁和其他食品的罐特别有用的涂覆金属基材。 涂料组合物和所得的固化涂料和涂覆的基材表现出改进的加工性,粘合性,硬度,耐擦性,外观和耐蒸煮性。