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    • 1. 发明授权
    • Rare earth oxysulfide phosphor and X-ray detector using the same
    • 稀土氧硫化物荧光粉和X射线检测仪使用相同
    • US6143200A
    • 2000-11-07
    • US202235
    • 1998-12-10
    • Takeshi AkiwaYuji AokiEtsuo ShimizuHideo Suzuki
    • Takeshi AkiwaYuji AokiEtsuo ShimizuHideo Suzuki
    • C09K11/77C09K11/84G21K1/06G21K4/00G01T1/20
    • G21K4/00C09K11/7771G21K1/06
    • When each of a rare earth oxysulfide phosphor represented by the composition formula (I) of Ln.sub.2 O.sub.2 S:xRe, yM wherein Ln represents at least one rare earth element selected from Y, La and Gd; Re represents at least one rare earth element selected from Pr and Tb; M represents at least one element selected from Nb, Ta and Mn; and x and y are numbers which satisfy the conditions of 1.times.10.sup.-4 .ltoreq.x.ltoreq.0.2 and 0.01 ppm .ltoreq.y.ltoreq.1000 ppm, respectively, and a rare earth oxysulfide phosphor represented by the composition formula (II) of (Gd .sub.1-x-y-z, Pr.sub.x, Sc.sub.y, Ce.sub.z).sub.2 O.sub.2 S wherein x, y and z are numbers which satisfy the conditions of 10.sup.-4 .ltoreq.x.ltoreq.2.times.10.sup.-1, 10.sup.-4 .ltoreq.y.ltoreq.10.sup.-1 and 0.ltoreq.z.ltoreq.10.sup.-6, respectively is excited by radiation, each of them emits a scintillation at high efficiency, and decreases the afterglow. Each of the phosphors is used for an X-ray detector as a scintillator, and is useful for an X-ray CT apparatus.
    • PCT No.PCT / JP97 / 02119 Sec。 371 1998年12月10日第 102(e)日期1998年12月10日PCT提交1997年6月20日PCT公布。 公开号WO97 / 48781 日期1997年12月24日当由Ln 2 O 2 S:xRe,yM的组成式(I)表示的稀土氧硫化物荧光体中的每一种,其中Ln表示选自Y,La和Gd中的至少一种稀土元素; Re表示选自Pr和Tb中的至少一种稀土元素; M表示选自Nb,Ta和Mn中的至少一种元素; x和y分别为满足1×10 -4≤x≤0.2,0.01ppm≤y≤1000ppm的条件的数和由组成式(II)表示的稀土氧硫化物荧光体 (Gd 1-xyz,Prx,Scy,Cez)2 O 2 S,其中x,y和z是满足条件为10 -4 = 2×10-1,10-4 = y = 10-1和0